Analytical Chemistry: Titration Methods for Metal Ions
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Questions and Answers

What is the characteristic of the endpoint in Fajan's method?

  • Reddish-brown color
  • Colorless chloroform layer
  • White precipitate with AgCl (correct)
  • Red precipitate of ferric thiocyanate
  • What is the name of the method that involves the formation of a white precipitate with AgCl at the start of the reaction?

  • Fajan's method (correct)
  • Volhard method
  • Direct Titration
  • Mohr's method
  • Who is the scientist after whom Fajan's method is named?

  • Jacob Volhard
  • Kazimiers Ferric
  • Kazimiers Mohr
  • Kazimiers Fajans (correct)
  • What is the type of reaction that occurs in Fajan's method?

    <p>Precipitation reaction</p> Signup and view all the answers

    What is the purpose of Fajan's method?

    <p>To determine the purity of NaCl</p> Signup and view all the answers

    What is the indicator used in Fajan's method?

    <p>Dichlorofluorescein (DCF)</p> Signup and view all the answers

    What is the purpose of adding 20g of NaCl in the sodium fluoride determination?

    <p>To repress ionization of NaF</p> Signup and view all the answers

    What is the indicator used in the titration of sodium fluoride with ferric chloride?

    <p>Potassium thiocyanate</p> Signup and view all the answers

    What is the reaction that occurs between NaF and FeCl3?

    <p>NaF + FeCl3 → FeF63-</p> Signup and view all the answers

    What is the purpose of using ascorbic acid, citrates, and tartrates in the determination of zinc?

    <p>To mask the interference of Co, Ni, and Cu</p> Signup and view all the answers

    What is the advantage of using EDTA in the determination of zinc?

    <p>It forms a stable complex with zinc ions</p> Signup and view all the answers

    What is the name of the titration method used to determine the iodine content in iodine-containing radiocontrast medium?

    <p>Fajans Titration</p> Signup and view all the answers

    What is the purpose of adding nitrobenzene in the Fajans titration method?

    <p>To form a film over precipitated AgCl particles</p> Signup and view all the answers

    What is the USP requirement for the iodine content in iodine-containing radiocontrast medium?

    <p>99.0% - 100.5%</p> Signup and view all the answers

    What is the reaction between 0.1N silver nitrate and iodine in the Fajans titration method?

    <p>Precipitation reaction</p> Signup and view all the answers

    What is the purpose of adding ferric ammonium nitrate in the Fajans titration method?

    <p>To prevent the precipitation of silver sulfate</p> Signup and view all the answers

    What is the endpoint of the Fajans titration method?

    <p>Until the color of the yellow precipitate just changes to green</p> Signup and view all the answers

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