Reactions of Alkanes
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Questions and Answers

What is the term used to describe the decomposition of a compound by the action of heat alone?

  • Pyrolysis (correct)
  • Combustion
  • Cracking
  • Hydrolysis

Which reaction of alkanes is known to be extremely exothermic and requires a very high temperature for initiation?

  • Combustion (correct)
  • Polymerization
  • Cracking
  • Hydrolysis

What is the distinguishing feature of the alkene structure?

  • π bond
  • Triple bond
  • Double bond (correct)
  • σ bond

Which process yields predominantly ethylene (C2H4) along with other small molecules?

<p>Cracking (C)</p> Signup and view all the answers

What is the general formula for the family of alkenes?

<p>CnH2n (C)</p> Signup and view all the answers

In which type of cracking are large alkanes converted into smaller alkanes, alkenes, and some hydrogen?

<p>Thermal cracking (D)</p> Signup and view all the answers

Which type of carbon-carbon bond has a shorter distance, according to the text?

<p>Carbon-carbon double bond (A)</p> Signup and view all the answers

Which is NOT one of the three simple alkenes commonly referred to by their common names?

<p>Butylene (D)</p> Signup and view all the answers

According to the IUPAC system, what suffix replaces -ane in the names of alkenes?

<p>-ene (C)</p> Signup and view all the answers

In naming alkenes, how is the position of the double bond indicated?

<p>By a number (D)</p> Signup and view all the answers

What takes precedence in determining the main carbon chain and numbering direction over alkyl groups and halogens?

<p>Carbon–carbon double bonds (D)</p> Signup and view all the answers

How do the physical properties of alkenes compare to those of alkanes?

<p>They are essentially the same (B)</p> Signup and view all the answers

What is the reactivity order observed for halogenation?

<p>$Cl_{2} &gt; Br_{2}$ (B)</p> Signup and view all the answers

In halogenation, why does an alkane yield a mixture of all possible isomeric products?

<p>Because all hydrogen atoms are susceptible to replacement. (B)</p> Signup and view all the answers

How do the relative amounts of isomers differ in chlorination and bromination?

<p>No isomer greatly predominates in chlorination; one isomer may predominate in bromination. (C)</p> Signup and view all the answers

What does the high degree of selectivity in bromination refer to?

<p>Selective replacement of hydrogen atoms in bromination. (B)</p> Signup and view all the answers

How does halogenation of alkanes proceed?

<p>A halogen atom abstracts a hydrogen from the alkane to form an alkyl radical. (A)</p> Signup and view all the answers

What determines how fast an alkyl halide is formed in halogenation?

<p>The rate at which alkyl radicals are formed. (D)</p> Signup and view all the answers

Which step in the chain propagating process is more difficult than the other?

<p>Step (2) (B)</p> Signup and view all the answers

Why is the chlorination of propane considered an important problem?

<p>To determine the product obtained based on radical formation rates (C)</p> Signup and view all the answers

Why is little control possible over the combustion process?

<p>High temperatures prevent control (B)</p> Signup and view all the answers

Which type of radicals are formed by abstraction of secondary hydrogens?

<p>Isopropyl radicals (D)</p> Signup and view all the answers

In the chlorination of alkanes, if isopropyl radicals are formed faster, what product is obtained more quickly?

<p>Isopropyl chloride (B)</p> Signup and view all the answers

What sequence is followed in the rate of abstraction of hydrogen atoms during alkane reactions?

<p>3o &gt; 1o &gt; 2o (B)</p> Signup and view all the answers

The C─C distance in ethylene is greater than the C─C distance in ethane.

<p>False (B)</p> Signup and view all the answers

Common names are frequently used for naming alkenes.

<p>False (B)</p> Signup and view all the answers

Alkenes are named based on the rules of the IUPAC system.

<p>True (A)</p> Signup and view all the answers

The parent structure for naming alkenes is selected as the shortest continuous chain.

<p>False (B)</p> Signup and view all the answers

The suffix -ene is added to the alkane name to name alkenes.

<p>True (A)</p> Signup and view all the answers

The position of the double bond in the parent chain is indicated by a letter in naming alkenes.

<p>False (B)</p> Signup and view all the answers

Alkyl groups and halogens take precedence over carbon-carbon double bonds in naming alkenes.

<p>False (B)</p> Signup and view all the answers

Physical properties of alkenes differ significantly from those of alkanes.

<p>False (B)</p> Signup and view all the answers

The IUPAC system is rarely used for naming alkenes.

<p>False (B)</p> Signup and view all the answers

Alkenes possess unique physical properties that are distinct from alkanes.

<p>False (B)</p> Signup and view all the answers

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