Qualitative Analysis: Identifying Cations
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Questions and Answers

Which of the following cations forms a blue precipitate when reacted with aqueous sodium hydroxide?

  • Cu2+ (correct)
  • Ca2+
  • Fe2+
  • Zn2+
  • Which of the following cations forms a precipitate that dissolves in excess aqueous sodium hydroxide?

  • Cu2+
  • Pb2+ (correct)
  • Fe3+
  • Ca2+
  • The reaction of which of the following cations with aqueous sodium hydroxide produces a green precipitate?

  • Fe3+
  • Al3+
  • Fe2+ (correct)
  • Zn2+
  • Aqueous sodium hydroxide solution is added dropwise to a solution containing an unknown cation. A white precipitate forms that dissolves when the solution is warmed. Which of the following is the most likely identity of the unknown cation?

    <p>Al3+ (C)</p> Signup and view all the answers

    Which of the following cations forms a white precipitate with aqueous sodium hydroxide that remains insoluble in excess sodium hydroxide solution?

    <p>Ca2+ (D)</p> Signup and view all the answers

    When an unknown cation is reacted with aqueous sodium hydroxide, a white precipitate forms and then dissolves upon the addition of excess sodium hydroxide. The precipitate also dissolves when the solution is warmed. Which of the following cations could be present?

    <p>Al3+ (A)</p> Signup and view all the answers

    A colorless solution is warmed with aqueous sodium hydroxide. A colorless gas is released, and moist red litmus paper turns blue. What is the identity of the unknown cation?

    <p>NH4+ (A)</p> Signup and view all the answers

    What is the balanced chemical equation for the reaction of iron(III) ions with aqueous sodium hydroxide to form iron(III) hydroxide?

    <p>Fe3+(aq) + 3OH-(aq) → Fe(OH)3(s) (D)</p> Signup and view all the answers

    Flashcards

    Qualitative Analysis

    The process of identifying components in a substance or mixture, like cations or anions.

    Cation

    A positively charged ion that is attracted to the cathode in electrolysis.

    Aqueous Sodium Hydroxide

    A chemical solution used to test for metal cations through precipitation reactions.

    Precipitate

    An insoluble solid formed from a chemical reaction in a liquid solution.

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    Calcium Hydroxide

    A white precipitate formed from Ca2+ reacting with sodium hydroxide.

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    Ammonia Test

    A method to identify NH4+ when no precipitate forms, detected by gas evolution.

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    Copper(II) Hydroxide

    A blue precipitate indicating the presence of Cu2+ when sodium hydroxide is added.

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    Aluminium Hydroxide

    A white precipitate that dissolves in excess sodium hydroxide to form a colorless solution.

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    Study Notes

    Qualitative Analysis: Identifying Cations

    • Qualitative analysis identifies components of a substance (e.g., cations and anions in an ionic compound).
    • Identifying Cations using Sodium Hydroxide: Metal cations form insoluble metal hydroxides when reacting with sodium hydroxide solution.
    • To identify a metal /ammonium ion, create a solution of the unknown solid in water.
    • Add sodium hydroxide dropwise, note any precipitate color.
    • Add excess sodium hydroxide to see if precipitate dissolves . If no precipitate forms, gently warm and test for ammonia gas.

    Cation Reactions with Sodium Hydroxide

    • Calcium (Ca²⁺): White precipitate, insoluble in excess sodium hydroxide.
    • Aluminum (Al³⁺): White precipitate, dissolves in excess sodium hydroxide solution, forming a colorless solution which is soluble in excess sodium hydroxide.
    • Lead (II) (Pb²⁺): White precipitate, dissolves in excess sodium hydroxide, forming a colorless solution, soluble in excess sodium hydroxide.
    • Zinc (Zn²⁺): White precipitate, dissolves in excess sodium hydroxide, forming a colorless solution, soluble in excess sodium hydroxide.
    • Copper (II) (Cu²⁺): Blue precipitate, insoluble in excess sodium hydroxide.
    • Iron (II) (Fe²⁺): Green precipitate, insoluble in excess sodium hydroxide
    • Iron (III) (Fe³⁺): Red-brown precipitate, insoluble in excess sodium hydroxide.
    • Ammonium (NH₄⁺): No precipitate, ammonia gas is evolved when warmed causing changes in moist red litmus paper, changing it to blue.

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    Description

    Test your knowledge on qualitative analysis focusing on the identification of cations using sodium hydroxide. This quiz will cover the reactions of various metal cations, their precipitate colors, and solubility in excess sodium hydroxide. Perfect for chemistry students looking to reinforce their understanding of ionic compounds.

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