Polyatomic Ions and Valence Numbers

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6 Questions

What is the net electric charge of a polyatomic ion?

A group of atoms bonded together with a net electric charge

What is the valence number of an atom in its elemental form?

0

Which of the following polyatomic ions has a charge of -2?

Carbonate (CO32-)

What is the valence number of nitrogen in ammonia (NH3)?

-3

What is the sum of the valence numbers of the individual atoms in a neutral compound?

0

What is the valence number of carbon in methane (CH4)?

+4

Study Notes

Polyatomic Ions

  • A polyatomic ion is a group of atoms bonded together that has a net electric charge.
  • They are also known as complex ions.
  • Polyatomic ions are typically formed from a combination of nonmetal atoms.

Common Polyatomic Ions

  • Ammonium (NH4+)
  • Carbonate (CO32-)
  • Hydroxide (OH-)
  • Nitrate (NO3-)
  • Phosphate (PO43-)
  • Sulfate (SO42-)

Valence Numbers (Oxidation States)

  • A valence number, also known as an oxidation state, is a number that represents the number of electrons an atom gains or loses to form a bond.
  • Valence numbers can be positive or negative.
  • The sum of the valence numbers in a neutral compound is zero.

Rules for Assigning Valence Numbers

  1. Atoms in their elemental form: Valence number of zero.
  2. Monatomic ions: Equal to the charge of the ion (e.g., Na+ = +1, Cl- = -1).
  3. Polyatomic ions: The sum of the valence numbers of the individual atoms in the ion.
  4. Compounds: The sum of the valence numbers of the individual atoms in the compound is zero.

Examples of Valence Numbers

  • Sodium (Na): +1
  • Chlorine (Cl): -1
  • Oxygen (O): -2
  • Nitrogen (N): -3 in ammonia (NH3), +5 in nitrate (NO3-)
  • Carbon (C): +4 in methane (CH4), -4 in methide (CH3-)

Polyatomic Ions

  • A polyatomic ion is a group of atoms bonded together with a net electric charge, also known as a complex ion.
  • Polyatomic ions are typically formed from a combination of nonmetal atoms.

Examples of Polyatomic Ions

  • Ammonium (NH4+)
  • Carbonate (CO32-)
  • Hydroxide (OH-)
  • Nitrate (NO3-)
  • Phosphate (PO43-)
  • Sulfate (SO42-)

Valence Numbers (Oxidation States)

  • A valence number, also known as an oxidation state, represents the number of electrons an atom gains or loses to form a bond.
  • Valence numbers can be positive or negative.
  • In a neutral compound, the sum of the valence numbers is zero.

Rules for Assigning Valence Numbers

  • Atoms in their elemental form have a valence number of zero.
  • Monatomic ions have a valence number equal to the charge of the ion.
  • Polyatomic ions have a valence number equal to the sum of the valence numbers of the individual atoms in the ion.
  • In a compound, the sum of the valence numbers of the individual atoms is zero.

Examples of Valence Numbers

  • Sodium (Na): +1
  • Chlorine (Cl): -1
  • Oxygen (O): -2
  • Nitrogen (N): -3 in ammonia (NH3), +5 in nitrate (NO3-)
  • Carbon (C): +4 in methane (CH4), -4 in methide (CH3-)

Learn about polyatomic ions, also known as complex ions, and valence numbers or oxidation states in chemistry. Understand how polyatomic ions are formed and review common examples.

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