Pharmaceutical Analytical Chemistry II - Complexometric Titrations

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Questions and Answers

Based on the information provided, what is the coordination number of Ni2+ in the complex Ni(CN)4-?

  • 6
  • 8
  • 4 (correct)
  • 2

Which of the following statements about chelating agents is true?

  • Chelates do not form coordinate bonds.
  • Chelates are less stable than linear complexes.
  • Chelates have 2 donor sites.
  • Chelates are more stable than linear complexes. (correct)

What is the term used to describe the number of donor sites in a chelating agent?

  • Ligand
  • Coordination number
  • Dentate (correct)
  • Complexation

In complexometric titrations, what type of curve is observed when a stable chelate is formed in one step?

<p>A curve with a single steep inflection region (C)</p> Signup and view all the answers

Which of the following complexes has a coordination number of 2?

<p>Ag(NH3)2+ (C)</p> Signup and view all the answers

What type of bond is formed between a metal and a ligand in a complex?

<p>Coordinate bond (A)</p> Signup and view all the answers

Which of the following statements accurately describes the formation of a metal-ligand complex?

<p>The ligand donates both shared electrons in the coordinate bond. (D)</p> Signup and view all the answers

What is the primary advantage of using a chelating agent in complexometric titrations?

<p>Chelates form multiple coordinate bonds, increasing complex stability. (B)</p> Signup and view all the answers

In the complex Fe(CN)6³⁻, what is the coordination number of the iron(III) ion?

<p>6 (C)</p> Signup and view all the answers

Which of the following statements best describes the shape of the titration curve in a complexometric titration involving a stable chelate formation?

<p>The curve has a single, steep inflection region, indicating a one-step complex formation. (D)</p> Signup and view all the answers

What is the term used to describe chelating agents with four donor sites?

<p>Tetradentate (C)</p> Signup and view all the answers

In the complex Zn(NH₃)₄²⁺, what is the coordination number of the zinc(II) ion?

<p>4 (C)</p> Signup and view all the answers

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