Packaging Materials and Properties Quiz

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Questions and Answers

Which of the following levels is responsible for the physical properties of materials?

  • Intermolecular forces (correct)
  • Spatial arrangement (correct)
  • Chemical bonding
  • Chemical constituents

The chemical changes in packaging materials do not involve breaking of chemical bonds.

False (B)

What is the major type of atom commonly found in plastics?

Carbon

In the aseptic carton for milk, layers consist of ______, aluminum, and polyethylene.

<p>paper</p>
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Which material is known to provide gas and light barriers in packaging?

<p>Aluminum (A)</p>
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Match the following packaging materials with their characteristics:

<p>Plastics = Carbon-based, lighter, chemical reactions Glass = Inorganic, rigid, impermeable Paper = Organic, recyclable, used for strength Metals = Inorganic, heat-resistant, for packaging stability</p>
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The bond type primarily found in plastics is ______ backbone.

<p>C-C</p>
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Intermolecular forces do not influence the behavior of materials under heat or pressure.

<p>False (B)</p>
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Which material has the highest surface tension at 25°C?

<p>Iron (D)</p>
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Surface tension increases with temperature.

<p>False (B)</p>
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What is tacticity in relation to molecular arrangement?

<p>The atomic arrangement in three-dimensional molecular configuration.</p>
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Polyethylene terephthalate has a surface tension of _____ dyne/cm at 25°C.

<p>43</p>
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Match the following materials with their respective surface tensions at 25°C:

<p>Polytetrafluoroethylene = 20 dyne/cm Polyethylene = 31 dyne/cm Cellophane = 44 dyne/cm Water = 73 dyne/cm</p>
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Which process is needed to improve the surface tension of plastics for operations like printing?

<p>Surface treatments (D)</p>
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The methyl groups in isotactic polypropylene are arranged alternately on both sides of the chain.

<p>False (B)</p>
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Name one additive used to lower the surface tension of liquids in plastic applications.

<p>Surfactant</p>
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Which type of bond has the highest bond energy?

<p>Covalent bonds (C)</p>
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Intermolecular forces are stronger than intramolecular forces.

<p>False (B)</p>
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What is the bond dissociation energy?

<p>The amount of energy required to break a covalent bond between two linked atoms.</p>
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What is one consequence of too fast oxidation in food packaging materials?

<p>Endanger its function as food packaging (B)</p>
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Covalent bonds are _____ times stronger than intermolecular forces.

<p>10-100</p>
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All types of polyethylene have the same density and gas permeability.

<p>False (B)</p>
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What type of forces hold molecules together loosely?

<p>Intermolecular forces (A)</p>
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Name one main material that can be affected by oxidation.

<p>Plastics</p>
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Match the types of intermolecular forces with their bond energy range:

<p>Hydrogen bonds = 4-40 kJ/mol Dipole-dipole forces = 0.15-15 kJ/mol Ion-dipole forces = 5-60 kJ/mol Dispersion forces = 0.4-4 kJ/mol</p>
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Packaging materials are primarily degraded by __________ when exposed to atmospheric oxygen.

<p>oxidation</p>
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What happens to the covalent bonds in a punctured PE film?

<p>The intermolecular forces holding the PE molecules break, while the covalent bonds remain strong and unaffected.</p>
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Metals are composed of individual molecules held together by covalent bonds.

<p>False (B)</p>
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Match the types of behavior with their respective materials:

<p>Oxidation = Plastics, some cellulosic Corrosion = Metals Biodegradation = Cellulosic, plastics Biodeterioration = Cellulosic, plastics, metals</p>
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Which property is important for food packaging materials to prevent degradation?

<p>Resistance to oxidation (C)</p>
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Cellulosic materials are not susceptible to chemical reactions during food contact.

<p>False (B)</p>
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Identify one factor that affects the chemical properties of food packaging.

<p>Atomic and molecular levels</p>
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What happens during a redox reaction?

<p>Electrons are lost by an atom. (C)</p>
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Combustion reactions are endothermic processes.

<p>False (B)</p>
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What is one example of a bleaching agent?

<p>Sodium hypochlorite (NaOCl)</p>
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The burning behavior of polyethylene produces a _____ flame with weak smoke.

<p>mostly yellow</p>
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Match the following polymers with their burning characteristics:

<p>Polypropylene = Weak smoke, paraffin odor Polyvinyl chloride = Soot (black), HCl odor Polyamide = White smoke, horn odor Polystyrene = Weak odor of plastic</p>
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What is a notable characteristic of bleaching agents?

<p>They typically function as oxidizing agents. (A)</p>
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All bleaching processes are environmentally safe.

<p>False (B)</p>
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What can the flame color of a burning polymer help identify?

<p>Type and nature of the material</p>
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What is one consequence of microbial biofilms on material surfaces?

<p>They can lead to deep corrosion. (A)</p>
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Biodeterioration applies mainly to fragile and easily damaged materials.

<p>False (B)</p>
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What term describes the ability of a material to resist changes when exposed to chemically aggressive substances?

<p>Chemical resistance</p>
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The process of removal of matter from the surface of packaging materials by dissolution or scraping is known as __________.

<p>etching</p>
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Which factor does NOT influence the adhesion of microbial cells on surfaces?

<p>Color of the material (D)</p>
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What is microbiologically-triggered corrosion?

<p>Corrosion induced by microbial activity.</p>
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Match the following terms with their definitions:

<p>Biodeterioration = Microbial damage to durable materials Weathering = Decomposition due to atmospheric conditions Leaching = Removal of matter by dissolution Etching = Surface material removal by scraping</p>
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Controlled exposure tests are used to objectively measure changes in properties after weathering.

<p>True (A)</p>
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Flashcards

Chemical Bonding

The arrangement of atoms within a molecule, determining its chemical properties.

Intermolecular Forces

The forces that attract molecules to each other, influencing the material's physical properties.

Spatial Arrangement

The three-dimensional arrangement of molecules in a material impacting its physical properties.

Chemical Changes

Changes that involve breaking and forming new chemical bonds, resulting in new substances.

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Physical Changes

Changes that do not involve breaking or forming new chemical bonds, only altering physical properties.

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Carbon-Based Materials

Organic materials like plastics and paper, known for their lightweight and susceptibility to chemical reactions.

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Inorganic Materials

Inorganic materials like glass and metal, known for their durability and resistance to chemical reactions.

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Composite Materials

A combination of different materials to achieve specific functionalities, like the layers in an aseptic carton.

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Bond dissociation energy

The amount of energy needed to break a covalent bond between two atoms.

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Hydrogen bond

A type of intermolecular force that occurs when a hydrogen atom is bonded to a highly electronegative atom like oxygen or nitrogen.

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Plastic or paper materials

They have weak intermolecular forces, making them breakable and meltable. Examples are paper and plastic.

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Metals and glass

They consist of giant molecules with strong bonds, making them rigid and strong. Examples are metals and glass.

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Breaking intermolecular bonds

Breaking a bond, especially intermolecular bonds, can lead to changes in the material's state, such as melting or breaking apart.

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Covalent bonds vs. other bonds

Covalent bonds are generally stronger than other bond types, requiring more energy to break.

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Surface tension

The force per unit length acting along the surface of a liquid, which arises from intermolecular interactions between molecules at the gas-liquid or liquid-liquid interface.

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Why do plastic materials pose challenges for surface treatments?

Surface tension is reduced compared to other materials, making it difficult to perform operations like printing, laminating, and coating.

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Surface active agents

Substances that lower the surface tension of liquids, allowing for better wetting and spreading on surfaces.

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Tacticity

The arrangement of atoms within a molecule, specifically referring to the spatial orientation of groups along a chain, e.g., in polypropylene the methyl groups can be on the same side, alternate sides, or random.

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Isotactic

All methyl groups are on the same side of the polymer chain, leading to a more ordered and crystalline structure.

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Syndiotactic

Methyl groups alternate above and below the polymer chain, resulting in a crystallizable structure.

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Atactic

Methyl groups are randomly positioned along the polymer chain, leading to a less ordered, amorphous structure.

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Morphology

The internal arrangement of a material's molecules, influencing its overall properties. This can be highly ordered (crystalline) or less structured (amorphous).

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What is oxidation?

A chemical reaction where an atom or molecule loses electrons creating a more positive charge. It is always coupled with reduction.

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What is reduction?

The gaining of electrons by an atom or molecule, leading to a more negative charge. It is always coupled with oxidation.

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Define redox reactions.

Chemical reactions involving both oxidation and reduction, where electrons are transferred between atoms or molecules.

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What is combustion?

A chemical process that releases energy as heat and light. Often used to dispose of organic packaging materials after use.

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How does bleaching work?

Using bleaching agents like sodium hypochlorite (NaOCl) or hydrogen peroxide (H2O2) to remove color from packaging materials.

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Explain the concept of 'corrosion'.

The weakening of the packaging material over time due to oxidation reactions, leading to deterioration. Examples include rusting of metal and the fading of color on packaging.

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What is ECF (Elemental Chlorine Free) or TCF (Totally Chlorine Free) bleaching?

A method for bleaching pulp with chlorine-free processes, minimizing environmental harm.

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What is 'chemical reactivity and susceptibility' of packaging?

The tendency of a packaging material to react with other substances (like oxygen), causing changes in its properties. This can involve oxidation reactions.

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Oxidation

The process where materials react with oxygen, often leading to degradation or weakening. This is particularly relevant for plastics and some types of paper.

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Stability to Oxidation

This refers to how well packaging materials withstand changes caused by exposure to oxygen, heat, or light, affecting their longevity and usefulness.

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Stability to Combustion

The ability of a material to resist being burned or decomposing due to heat. This is vital for safety and waste disposal.

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Stability to Degradation

How well packaging materials hold up against changes caused by chemical reactions, environmental factors, or prolonged contact with specific substances.

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Resistance to Corrosion

The ability of metals to withstand damage from corrosive agents, such as chemicals and moisture. This is important for items like aluminum cans and tin-plated food containers.

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Chemical Resistance

How well a material can resist being dissolved, broken down, or affected by contact with specific chemicals.

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Etching

A process where the surface of a material becomes worn down or altered due to chemical reactions. This can happen due to exposure to acids or other reactive substances.

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Leaching

When components from a material are transferred into food or another substance through contact. This can sometimes happen when packaging materials are exposed to acidic foods or intense heat.

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Biodeterioration

The deterioration of materials caused by the destructive activity of microbes.

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Microbial biofilm

A thin layer of microorganisms attached to a surface, often embedded in a sticky substance.

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Weathering

The breakdown of a material due to exposure to weather conditions, such as sunlight, rain, and wind.

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Abuse test

A test that exposes a material to controlled conditions to measure its resistance to chemicals, weathering, etc., by observing changes in weight, shape, or appearance.

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Bacteria proliferation

The capacity of bacteria to multiply on a surface, especially within biofilms.

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Microbiologically-triggered corrosion

Corrosion caused by the activity of microbes, often within biofilms.

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Study Notes

Chemical Structure & Properties of Packaging Materials

  • Packaging material properties depend on four levels of atomic and molecular structures.

  • Level 1: Chemical Constituents identifies the atoms composing the materials. -Four basic material types for food packaging: plastics, paper, glass, and metals. -Examples: plastics and paper are carbon-based organic materials, which can be lighter and weaker and may interact with food; glass and metal materials are inorganic and more resistant to chemical reactions. -Various complex materials are combinations of two or more materials to improve functions. -Example: an aseptic carton for milk and juices is made from layers of 70% paper, 6% aluminum and 24% polyethylene (PE).

  • Level 2: Chemical Bonding describes the forces holding atoms together to form molecules. -Transferring electrons creates ionic bonds. -Sharing electrons forms covalent or metallic bonds, which are stronger bonds called primary bonds. -Examples: -Ionomers (packaging polymers) consist of covalent and ionic bonds, which leads to unique properties like heat seal strength. -Covalent bonds are the most common type in plastics, paper, and glass, frequently using atoms like C, O, N, and Cl.

  • Level 3: Intermolecular Forces explains the forces attracting molecules together to form materials. -Weaker than primary bonds, these forces create loosely-associated groups. -Types include dispersion forces (weakest), dipole-dipole interactions, ion-dipole interactions, and hydrogen bonding (strongest). -Examples: -These forces explain properties like surface tension, which may be useful in coating, printing, and adhesion (lamination, wetting). -Typical values of the bonds' strengths are given (dispersion forces, 0.04-4 kJ/mol; Dipole-dipole forces, 0.15-15 kJ/mol; hydrogen bonds, 4-40 kJ/mol). -Covalent bonds have much greater strength than intermolecular bonds (10-100 times stronger).

  • Level 4: Spatial Arrangement (Tacticity) describes the ordering of molecules in three dimensions within a material. -Tacticity or stereochemistry defines the placement of groups in molecules, influencing properties. -Structures can be crystalline (orderly, predictable units) or amorphous (random molecular arrangement). -Crystalline structures are stronger and stiffer than amorphous structures. -Degree of crystallinity is a measure of crystalline organization within a material, including plastics and ceramics. A higher percentage of crystallinity results in greater strengths and reduced transparency. -Examples: -Different types of polymers can exhibit different levels of crystallinity based on the processing and composition.

Chemical Reactivity & Susceptibility of Packaging

  • Chemical properties are crucial for packaging's protective function.
  • Packaging materials' reactivity depends on atomic and molecular level interactions . -Examples: -The structure of polyethylene, for example, strongly affects its gas permeability.
  • Chemical properties important for food packaging: -Oxidation (e.g., through combustion, corrosion or bleaching). -Resistance to corrosion and chemical substances (e.g., acids or solvents). -Biodegradation/Biodeterioration (e.g., through microbial action). -Specific standards (e.g., ASTM standards) are used to measure the chemical resistance.

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