Organic Chemistry: Organic Reagents Overview
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Questions and Answers

What is the reagent used to convert alcohols into alkyl halides?

PCl5, PBr5, PI3

What reagents are used to convert alcohols into alkyl chlorides and carboxylic acids into acid chlorides?

SOCl2, PCl5

What reagent is utilized for the conversion of alcohols into alkyl halides?

HCl/ZnCl2, HBr, HI

What is the reagent that introduces a Cl group substituting on benzene?

<p>Cl<sub>2</sub>/Fe or FeCl<sub>3</sub></p> Signup and view all the answers

What reagent is used in the diazotization process?

<p>NaNO<sub>2</sub>, HCl (0-5<sup>o</sup>C)</p> Signup and view all the answers

Study Notes

Organic Reagents

  • Alcohols to Alkyl Halides: PCI3, PBr3, PCl5
  • Alcohols to Alkyl Chlorides & Carboxylic Acids to Acid Chlorides: SOCl2, PCl5
  • Alcohols to Alkyl Halides: HCl/ZnCl2, HBr, HI
  • Chlorine Substitution on Benzene: Cl2/FeCl3
  • Diazotisation: NaNO2/HCl (0-5°C)
  • Diazonium Salts to Chlorobenzene, Bromobenzene, Benzonitrile, Iodobenzene, Phenol, Benzene: CuCl, CuBr, CuCN, KI, H2O, H2PO2
  • Diazonium Chloride to Fluoro Benzene: HBF4 or NaBF4; AgF or HgF2 or SbF3 or CoF
  • Alkyl Halides to Alkanes: Na/dry ether
  • Alkyl Halides to Alkyl Chlorides: NaOH(623/443/368K)
  • Bromination of Benzene: Br2/FeBr3
  • Chlorination of Benzene: Cl2/FeCl3
  • Alkylation of Benzene: CH3Cl/AlCl3
  • Acylation of Benzene: CH3COCl/AlCl3
  • Nitration of Benzene: H2SO4/HNO3
  • O-Acylation of Phenol: (CH3CO)2O/AICl3
  • Sulphonation of Benzene: H2SO4
  • Alkenes to Alcohols: H2O/H2SO4
  • Alkyl Halides to Alcohols: H2O/H2SO4; AgOH
  • Alkyl Halides to Alcohols (Anti Markovnikov Product): BH3/H2O/OH-
  • Aldehydes, Ketones, Carboxylic Acids to Alcohols: NaBH4 / LiAlH4 (LAH)
  • Nitriles, Isocyanides to Amines: H2/Ni or H2/Pd reduction of aldehydes, Ketones, Cynides

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Description

This quiz focuses on various organic reagents and their transformations, including the conversion of alcohols to alkyl halides and the diazotization process. Participants will explore reactions involving halogenation and substitution on benzene rings, as well as the use of specific reagents for these transformations. Test your knowledge of organic reagents and their applications in synthesis.

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