Organic Chemistry Isomerism and Functional Groups
15 Questions
1 Views

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

What is the total maximum marks allotted for the examination?

  • 50
  • 150
  • 75 (correct)
  • 100

    • Which of these is NOT a part of the examination?

  • Part C
  • Part D (correct)
  • Part B
  • Part A

    • How many questions in Part C must be answered?

  • All
  • 7 (correct)
  • 5
  • 10

    • What is the subject of the examination?

    <p>Pharmaceutical Organic Chemistry-IV (C)</p> Signup and view all the answers

    What is the total time allotted for the examination?

    <p>Three hours (B)</p> Signup and view all the answers

    Which of the following compounds would be expected to exhibit geometric isomerism (cis-trans isomerism)?

    <p>2-Butene (B)</p> Signup and view all the answers

    Which of the following statements correctly describes the functional group present in the molecule represented by -C-O-C- ?

    <p>The functional group is an ether, characterized by an oxygen atom bonded to two carbon atoms. (C)</p> Signup and view all the answers

    Which of the following is the most basic among the given compounds?

    <p>Trimethylamine ((CH<sub>3</sub>)<sub>3</sub>N) (D)</p> Signup and view all the answers

    Which of the following reactions is NOT a characteristic reaction of alkyl halides?

    <p>Electrophilic addition reaction (D)</p> Signup and view all the answers

    Which of the following would be considered a primary (1°) aliphatic amine?

    <p>Ethylamine (CH<sub>3</sub>CH<sub>2</sub>NH<sub>2</sub>) (C)</p> Signup and view all the answers

    Which of the following is NOT a characteristic of a ketone?

    <p>Ketones are typically more reactive than aldehydes. (C)</p> Signup and view all the answers

    Which of the following compounds would undergo a nucleophilic substitution reaction with a strong nucleophile like hydroxide ion (OH-)?

    <p>Bromoethane (CH<sub>3</sub>CH<sub>2</sub>Br) (A)</p> Signup and view all the answers

    Which of the following compounds would be expected to produce a positive Tollens' test, indicating the presence of an aldehyde functional group?

    <p>Formaldehyde (HCHO) (B)</p> Signup and view all the answers

    Which of the following statements is TRUE regarding the reactivity of acyl halides?

    <p>Acyl halides are more reactive than esters and amides due to the presence of a good leaving group (halide ion). (C)</p> Signup and view all the answers

    Which of the following pairs of molecules represents functional isomers?

    <p>Ethanol (CH<sub>3</sub>CH<sub>2</sub>OH) and Dimethyl ether (CH<sub>3</sub>OCH<sub>3</sub>) (C)</p> Signup and view all the answers

    Flashcards

    Pharmaceutical Organic Chemistry-IV

    A course focusing on organic chemistry principles relevant to pharmacy.

    Examination Format

    The structure of the exam with three parts: A, B, and C.

    Part A Questions

    All questions must be answered, each worth 1 mark.

    Part B Questions

    Students choose 2 questions to answer, each worth 10 marks.

    Signup and view all the flashcards

    Part C Questions

    Answer any 7 questions from this section, each worth 5 marks.

    Signup and view all the flashcards

    Isomers

    Molecules with the same molecular formula but different structures.

    Signup and view all the flashcards

    LPG Composition

    LPG mainly consists of Butane and Isobutane.

    Signup and view all the flashcards

    Carbon Hybridization

    Carbon in alkenes is sp² hybridized due to double bonds.

    Signup and view all the flashcards

    Lucas Test

    A test that determines the type of alcohol present.

    Signup and view all the flashcards

    Acetaldehyde Reaction

    Reacts with Fehling's solution to form Cu₂O.

    Signup and view all the flashcards

    Ketone Example

    Acetone is a common example of a ketone.

    Signup and view all the flashcards

    Gabriel Phthalimide Reaction

    Used for synthesizing primary aliphatic amines.

    Signup and view all the flashcards

    Alkane Substitution

    Alkyl halides undergo nucleophilic substitution reactions.

    Signup and view all the flashcards

    Carbylamine Test

    Indicates the presence of primary amines.

    Signup and view all the flashcards

    Saponification

    Basic hydrolysis of esters to form soap.

    Signup and view all the flashcards

    Study Notes

    Multiple Choice Questions (Part A)

    • Isomers with the same molecular formula but different functional groups are called functional isomers.
    • LPG (liquefied petroleum gas) is primarily a mix of butane and isobutane.
    • Carbon atoms in a double bond are sp² hybridized.
    • Lucas test identifies alcohols.
    • Acetaldehyde reacts with Fehling's solution to produce CuO.
    • Acetone is an example of a ketone.
    • Chloroform, exposed to light and air, produces phosgene.
    • Gabriel phthalimide reaction synthesizes primary aliphatic amines.
    • Trimethylamine is the most basic among the given options.
    • 2-Butene exhibits geometric isomerism.
    • The functional group -C-O-C- represents an ether.
    • Primary amines give a positive carbylamine test.
    • C=O is a bond present in the carboxylic acid functional group.
    • Alkyl halides undergo nucleophilic substitution reactions.
    • N,N-dimethylthanamide is a structure; the provided format does not specify the formula for this compound.
    • Methanol has the lowest solubility in water, compared to the other given alcohols.
    • Saponification is the basic hydrolysis of esters.
    • The most stable acid derivatives are amides.
    • Benzaldehyde among the given aldehydes can undergo aldol reactions.

    Part B (Short Answer Questions)

    • SN1 and SN2 reactions are nucleophilic substitution reactions with different mechanisms and reaction rates. Factors affecting these reactions are discussed.
    • Several name reactions are mentioned; however, just the names are provided.
    • Halogenation of alkanes, Cannizzaro reaction, nucleophilic addition reactions, and Diels-Alder reactions are a few.

    Part C (Essay Questions)

    • Markownikoff's and Anti-Markownikoff's rules describe the addition of reagents to alkenes.
    • E1 and E2 reactions relate to elimination reactions.
    • Ethyl chloride and chloroform are discussed in terms of structure and applications.
    • The basicity of aliphatic amines is influenced by substituents.
    • The acid-catalyzed and base-catalyzed hydrolysis of amides are explained.
    • Methods to distinguish between primary, secondary, and tertiary amines.
    • Aldehydes and ketones are collectively called carbonyl compounds and Perkin condensation is discussed.
    • Acetic acid is detailed. Key comparisons between formic and acetic acid are provided..
    • Qualitative tests for alcohols are summarized.
    • Markownikoff's and anti-Markownikoff's rules are explained.

    Studying That Suits You

    Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

    Quiz Team

    Related Documents

    B. Pharmacy 2nd Semester Pharmaceutical Organic Chemistry Past Paper April-May 2021 PDF

    Description

    This quiz covers essential concepts in organic chemistry, focusing on isomerism, functional groups, and chemical reactions involving various organic compounds. Test your knowledge on functional isomers, hybridization, and important tests used in organic analysis.

    More Like This

    Use Quizgecko on...
    Browser
    Open
    Browser
    Browser