Organic Chemistry Basics Quiz
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Questions and Answers

What name corresponds to the hydrocarbon radical indicated as $C_4H_9$?

  • Isopropyl
  • Sec-butyl
  • Isobutyl (correct)
  • Tert-butyl
  • Which hydrocarbon radical is represented by the structure $C_3H_7$?

  • Phenyl
  • Benzyl
  • Vinyl
  • Propyl (correct)
  • Which class of organic compounds does a compound with the functional group $-COOH$ belong to?

  • Ester
  • Acid (correct)
  • Ketone
  • Aldehyde
  • What functional group of the ethanolamine molecule is designated as a prefix in IUPAC naming?

    <p>Hydroxy-group (D)</p> Signup and view all the answers

    Which functional group of the serine molecule serves as a suffix according to IUPAC rules?

    <p>Carboxy-group (D)</p> Signup and view all the answers

    Which alkane serves as the parent structure in a compound having the formula $C_5H_{12}$?

    <p>Pentane (A)</p> Signup and view all the answers

    How many primary carbon atoms are typically found in a branched hydrocarbon chain?

    <p>Only carbons bonded to one other carbon (B)</p> Signup and view all the answers

    How many secondary carbon atoms are typically present in a simple hydrocarbon?

    <p>Carbons bonded to two other carbons (B)</p> Signup and view all the answers

    Which pair of compounds are interclass isomers?

    <p>ethers and alcohols (A), alcohols and acids (B)</p> Signup and view all the answers

    What is the name of the compound with the IUPAC name 2,3-dimethylpentane?

    <p>2-ethyl-4-methylhexane (B)</p> Signup and view all the answers

    What is the type of reaction represented by CH₃C₃NH₂ + CH₃I →?

    <p>alkylation (B)</p> Signup and view all the answers

    What is the type of the following reaction CH₃CH₂NH + (CH₃CO)₂O →?

    <p>acylation (D)</p> Signup and view all the answers

    Which of the following is a polyatomic alcohol?

    <p>glycerol (C)</p> Signup and view all the answers

    What type of alcohol is represented by the formula C₃H₈O?

    <p>primary monoatomic alcohol (B)</p> Signup and view all the answers

    What is the functional group of aldehydes and ketones?

    <p>-C(O)- (D)</p> Signup and view all the answers

    Which of the Bronsted acids is the strongest according to Bronsted-Lowry theory?

    <p>sulfuric acid (D)</p> Signup and view all the answers

    What is the correct amino alcohol that is part of phosphatidylcholine?

    <p>Choline (C)</p> Signup and view all the answers

    Which bond will hydrolyze in phosphatidylethanolamine?

    <p>Amide bond (D)</p> Signup and view all the answers

    What reaction is needed to obtain phosphatidylethanolamine from phosphatidylserine?

    <p>Deamination (B)</p> Signup and view all the answers

    What bond can hydrolyze in glycocholic acid?

    <p>Amide bond (A)</p> Signup and view all the answers

    Which product results from the reaction of cholic acid with taurine?

    <p>Amide (C)</p> Signup and view all the answers

    How many moles of hydrogen are required for the complete hydrogenation of 1 mole of fat?

    <p>4 (A)</p> Signup and view all the answers

    Which of these substances contains sodium oleate?

    <p>Sodium stearate (C)</p> Signup and view all the answers

    What is a common byproduct of the hydrogenation of fatty acids?

    <p>Fat (B)</p> Signup and view all the answers

    What are the salts of malonic acid called?

    <p>malonates (B)</p> Signup and view all the answers

    Which of the following acids is the weakest?

    <p>acetic acid (A)</p> Signup and view all the answers

    Which acid decarboxylates most easily when heated to form monocarboxylic acids?

    <p>succinic (butanedioic acid) (A)</p> Signup and view all the answers

    What is the product of the reaction when an alcohol reacts with an acid to form an ester?

    <p>ether (D)</p> Signup and view all the answers

    Which acid is formed by hydrolysis of butyric acid?

    <p>acetic acid (B)</p> Signup and view all the answers

    What compound forms an anhydride when reacted with acetic acid?

    <p>acetaldehyde (B)</p> Signup and view all the answers

    Which product is formed from the hydrolysis of propylacetate?

    <p>acetic acid + propanol (B)</p> Signup and view all the answers

    What product is formed by the following reaction: propanoic acid + ethanol → ?

    <p>ethyl acetate (B)</p> Signup and view all the answers

    Which statement accurately describes ergosterol?

    <p>Isomerizes to vitamin (C), Can form an ester (D)</p> Signup and view all the answers

    What characteristic best describes saturated fatty acids?

    <p>They take part in addition reactions (C), They are liquid substances at room temperature (D)</p> Signup and view all the answers

    Which statement characterizes linolenic acid?

    <p>Has two double bonds in the hydrocarbon radical (C)</p> Signup and view all the answers

    What best describes 1-oleoyl-2-palmitoyl-3-stearoylglycerol?

    <p>Refers to complex saponifiable lipids (A)</p> Signup and view all the answers

    Which product results from the reaction that includes nitrogen-containing compounds like pyridine?

    <p>Pyrimidine (B), Pyrroline (C)</p> Signup and view all the answers

    Identify the fused ring heterocycle among the following options.

    <p>Purine (D)</p> Signup and view all the answers

    In which of the following compounds is there an N-H acidic reaction center?

    <p>Pyrrol (A)</p> Signup and view all the answers

    What property distinguishes the carbon chain of linolenic acid?

    <p>Contains three double bonds (A)</p> Signup and view all the answers

    Which type of bond forms during the interaction of uridine with phosphoric acid?

    <p>O-glycosidic (C)</p> Signup and view all the answers

    What type of bond forms when uracil interacts with D-ribose?

    <p>O-glycosidic (B)</p> Signup and view all the answers

    Which of the following compounds corresponds to the structure of uridine?

    <p>Uridine (A)</p> Signup and view all the answers

    What products are formed by the complete hydrolysis of thymidine-5'-phosphate in acid?

    <p>Thymine, 2-deoxy-D-ribofuranose, phosphoric acid (D)</p> Signup and view all the answers

    What are the products formed from the hydrolysis of uridine under acidic conditions?

    <p>Uracil, ribose (A)</p> Signup and view all the answers

    Which of the following bases is classified as a pyrimidine?

    <p>Cytosine (A), Uracil (B)</p> Signup and view all the answers

    Which of the following is a deoxyribonucleotide?

    <p>Thymidine-5'-phosphate (A), Deoxycytidine (B)</p> Signup and view all the answers

    Which compound can form a complementary pair with cytosine?

    <p>Thymine (D)</p> Signup and view all the answers

    Flashcards

    Isobutyl Radical

    A branched alkyl group with four carbon atoms, where the branching occurs on the second carbon atom from the end.

    Isopropyl Radical

    A branched alkyl group with three carbon atoms, where the branching occurs on the middle carbon atom.

    sec-Butyl Radical

    A branched alkyl group with four carbon atoms, where the branching occurs on the third carbon atom from the end.

    tert-Butyl Radical

    A branched alkyl group with four carbon atoms, where the branching occurs on the second carbon atom from the end.

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    Propyl Radical

    A straight chain alkyl group with three carbon atoms.

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    Amino Group

    The functional group containing a nitrogen atom directly bound to two alkyl groups, and one hydrogen atom.

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    Primary Carbon Atom

    A carbon atom in an organic compound that is directly connected to only one other carbon atom.

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    Secondary Carbon Atom

    A carbon atom in an organic compound that is directly connected to two other carbon atoms.

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    Chain Isomers

    Isomers that have the same molecular formula but differ in the arrangement of their atoms within the carbon chain. They are molecules that have the same number and type of atoms but differ in the way these atoms are arranged in space.

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    Geometric (or Dimensional) Isomers

    Isomers that have the same molecular formula and the same arrangement of atoms, but differ in the spatial arrangement of their atoms. They have atoms in the same order, but the molecule's three-dimensional shape is different.

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    Functional Group Isomers

    Isomers that have the same molecular formula, but different functional groups.

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    Structural Isomers

    Compounds that have the same molecular formula but different structural formulas. They differ in the arrangement of their atoms and bonds.

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    Alkylation

    A reaction that involves the addition of an alkyl group to a molecule. It's like adding a new building block to a structure.

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    Decarboxylation

    The removal of a carboxyl group (-COOH) from a molecule. It's like removing a functional group from a molecule.

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    Dehydration

    A reaction where an alcohol loses a molecule of water (H2O). It's like removing water from a structure, leaving a double bond behind.

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    Acylation

    A reaction that involves the introduction of an acyl group (R-CO-) into a molecule. It's like adding a carbonyl group to a structure.

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    What is the formula of oxalic acid?

    Oxalic acid is a dicarboxylic acid with the formula HOOC-COOH. It is the simplest dicarboxylic acid, consisting of two carboxyl groups connected to each other.

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    What are the salts of malonic acid called?

    The salts of malonic acid are known as malonates. Malonic acid is a dicarboxylic acid with the formula CH2(COOH)2.

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    Which of the following acids is the weakest?

    Oxalic acid (ethanedioic acid) is the weakest among the listed acids. The strength of a carboxylic acid depends on factors like electron-withdrawing groups. Oxalic acid has two carboxyl groups that can interact, weakening the acidity compared to other options.

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    Which of the following acids decarboxylates most easily when heated to form monocarboxylic acids?

    Succinic acid (butanedioic acid) decarboxylates (loses a CO2 molecule) most easily upon heating. This is due to the stability of the resulting cyclic anhydride (succinic anhydride).

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    What is the product of the following reaction → ?

    The reaction of a carboxylic acid with an alcohol forms an ester. This reaction is called esterification.

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    Which acid is formed by hydrolysis of ( ) ?

    Hydrolysis of the given compound ( ) produces acetic acid (CH3COOH). Hydrolysis is the process of breaking down a compound by reacting it with water.

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    Which acid is formed by hydrolysis of

                    ?
    

    The given compound, ( ) is hydrolyzed to produce propionic acid (CH3CH2COOH). Hydrolysis is the process of breaking down a compound with water.

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    What compound forms an anhydride when reacted with acetic acid?

    Acetic acid (CH3COOH) forms an anhydride when reacted with itself (another molecule of acetic acid). An anhydride is formed by removing a water molecule from two carboxylic acid molecules.

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    N-glycosidic bond

    A type of bond formed between a nitrogenous base and a sugar molecule in a nucleotide.

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    O-glycosidic bond

    A type of bond formed between a sugar molecule and a phosphate group in a nucleotide.

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    Ester bond

    A type of bond formed when the hydroxyl group of a sugar molecule reacts with the phosphate group of phosphoric acid.

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    Uridine

    A nucleoside composed of uracil attached to a ribose sugar.

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    Thymidine

    A nucleoside composed of thymine attached to a deoxyribose sugar.

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    Deoxyribonucleotide

    A nucleotide consisting of a nitrogenous base linked to a sugar, with a single phosphate group attached to the sugar's 5' carbon.

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    Pyrimidine

    A nitrogenous base that is a derivative of pyrimidine, having a single ring structure.

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    Guanine

    A nitrogenous base that forms a complementary pair with cytosine in DNA.

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    Phospholipid

    A type of lipid that is composed of glycerol, fatty acids, and a phosphate group. Phosphatidylcholine, also known as lecithin, is a common example.

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    Phosphatidylethanolamine

    A type of lipid that is a major component of cell membranes. Phosphatidylethanolamine is a major component of cell membrane structures.

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    Colamine

    An amino alcohol that is a component of phosphatidylethanolamine. It's similar to choline but lacks the methyl groups.

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    Glycocholic Acid

    A molecule that is the product of the reaction of cholic acid with glycine. It aids in the digestion of fats.

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    Taurocholic Acid

    A molecule that is the product of the reaction of cholic acid with taurine. It assists in the digestion of fats.

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    Amide Bond

    The bond that connects the amino acid (glycine or taurine) to cholic acid in glycocholic and taurocholic acids.

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    Hydrogenation

    A chemical reaction that involves the addition of hydrogen atoms across the double bond of a molecule.

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    Properties of Ergosterol

    Ergosterol is a sterol naturally found in fungi, plants, and yeast. It's important because it can isomerize into Vitamin D2 when exposed to UV light. Ergosterol also has structural features like an alcohol group and the ability to form esters.

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    Saturated Fatty Acid Characteristics

    Saturated fatty acids are long chains of carbon atoms linked by single bonds. These straight chains make them solid at room temperature. They have even numbers of carbon atoms and lack double bonds, preventing them from participating in addition reactions.

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    Linolenic Acid Structure

    Linolenic acid is a polyunsaturated fatty acid with three double bonds in its carbon chain, making it liquid at room temperature. It's classified as an Omega-3 fatty acid and is essential for human health.

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    Triglyceride Structure

    Triglycerides like 1-oleoyl-2-palmitoyl-3-stearoylglycerol are complex lipids formed from glycerol and fatty acids. Due to the presence of both saturated and unsaturated fatty acids, they have a liquid consistency at room temperature. These lipids can be hydrolyzed into their components (glycerol and fatty acids).

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    Purine Structure

    Purines are nitrogenous bases found in DNA and RNA. They have a fused ring structure consisting of a pyrimidine ring and an imidazole ring.

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    Pyrrole Structure

    Pyrrole is a five-membered heterocyclic compound containing one nitrogen atom. Its N-H bond is acidic, allowing it to participate in reactions with electrophilic reagents.

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    Study Notes

    Organic Chemistry Training Tests

    • Discipline: Chemistry
    • Course of Study: 1
    • Specialty: Medicine, Pediatrics
    • Language of Instruction: English
    • Department/Module: Chemistry
    • Academic Year: 2024-2025

    Theoretical Foundations of the Structure and Reactivity of Organic Compounds

    • Hydrocarbon Radical Names:
      • isobutyl
      • isopropyl
      • sec-butyl
      • tert-butyl
      • propyl
      • benzyl
    • Hydrocarbon Radical C6H5-CH2-: benzyl
    • Compound Class CH3-C(O)-C3H7: ester
    • Functional Group of Ethanolamine (HO-CH2-CH2-NH2): amino group
    • Functional Groups of Serine (HO-CH2-CH(NH2)-COOH):
      • hydroxy group
      • carboxy group
      • amino group
    • Parent Alkane in Compound C(CH3)3-CH2 CH-CH2CH3: hexane
    • Number of Primary Carbon Atoms in Compound: 3
    • Number of Secondary Carbon Atoms in Compound: 2
    • Identical Compounds: identical (same)
    • Chain Isomers: different compounds made of the same atoms in different orders
    • Geometric Isomers: different compounds that have the same atoms in the same order, but the atoms have different positions around a double bond
    • Functional Group Isomers: compounds that have the same molecular formula, but the functional groups are in different locations / have different chemical properties
    • Interclass Isomers: compounds that have the same molecular formula, but the functional groups are in different categories
    • IUPAC Nomenclature (CH3)2CH - C(CH3)2 – CH2-CH3: 2,3-dimethylpentane
    • IUPAC Nomenclature CH3-CH-CH2-CH-CH-CH CH3(with CH3 branches): 2-ethyl-4,5-dimethylhexane
    • Reaction type CH3CH2 NH CH3 + CH3I →: alkylation
    • Reaction type CH3CH2 NH2 + (CH3CO)2O →: acylation
    • Polyatomic Alcohol: glycerol
    • Alcohol Formula CH3-CH-CH2-CH2OH CH3: secondary monoatomic alcohol
    • Functional Group of Aldehydes and Ketones: -C(=O)-
    • Strongest Bronsted Acid (according to Bronsted-Lowry): phenol (pKa = 10)
    • IUPAC Nomenclature (CH3)2CH - C(CH3)2 – CH2 - CH3): 2,3-dimethylpentane

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    Description

    Test your knowledge on organic compounds, functional groups, and hydrocarbon radicals with this quiz. Dive into questions about IUPAC nomenclature, isomers, and chemical reactions to assess your understanding of organic chemistry principles.

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