Monosaccharides: Structure and Classification
18 Questions
0 Views

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

What is the orientation of the bulky R group in a Haworth projection when the OH group engaged in a nucleophilic attack is on the right-hand side in the straight chain Fisher diagram?

  • Parallel to the ring
  • Perpendicular to the ring
  • Pointed up (correct)
  • Pointed down

What is the simplest rule for determining the orientation of OH groups in a Haworth projection?

  • If they are pointing up in the Fisher straight chain form, they point up in the Haworth form
  • If they are pointing to the left in the Fisher straight chain form, they point up in the Haworth form
  • If they are pointing down in the Fisher straight chain form, they point down in the Haworth form
  • If they are pointing to the right in the Fisher straight chain form, they point down in the Haworth form (correct)

What is the relationship between D-glyceraldehyde and D sugars?

  • D sugars are unrelated to D-glyceraldehyde
  • D sugars are diastereomers of D-glyceraldehyde
  • D sugars are related to D-glyceraldehyde at their last asymmetric center (correct)
  • D sugars are enantiomers of D-glyceraldehyde

What is the prefix 'L' referring to in a sugar molecule?

<p>The mirror image of a D sugar (D)</p> Signup and view all the answers

What is the purpose of the Haworth projection?

<p>To show the relationship between the anomeric OH and the OH on the last chiral C (B)</p> Signup and view all the answers

Why is it important to know the correct orientation of the bulky R group in a Haworth projection?

<p>To determine the stereochemistry of the molecule (C)</p> Signup and view all the answers

What is the minimum number of carbon atoms required in a simple sugar molecule?

<p>Three (A)</p> Signup and view all the answers

What type of reaction occurs to form the ring structure in a sugar molecule?

<p>Intramolecular nucleophilic attack (B)</p> Signup and view all the answers

What is the fate of the carbonyl oxygen during the ring formation in a sugar molecule?

<p>It becomes an OH (A)</p> Signup and view all the answers

What is the predominant form of glucose in solution?

<p>Pyranose (A)</p> Signup and view all the answers

What is the exclusive form of glucose in polysaccharides?

<p>Pyranose (D)</p> Signup and view all the answers

What is the advantage of using Fisher projections to represent sugar molecules?

<p>It is easier to visualize for 3C molecules (D)</p> Signup and view all the answers

When drawing the wedge and dash line of a molecule, how should the C atoms adjacent to the one of interest be oriented?

<p>Pointing down (D)</p> Signup and view all the answers

Which of the following is true about the orientation of the OH group in the Fisher projection and the wedge and dash drawing?

<p>If the OH points right in the Fisher, it points right in the wedge and dash (D)</p> Signup and view all the answers

What is a unique feature of b-D-glucopyranose among aldohexoses?

<p>It has all its bulky substituents in equatorial positions (C)</p> Signup and view all the answers

How do substituents that point to the right in the Fisher structure appear in the Haworth projection?

<p>They point down (C)</p> Signup and view all the answers

What is the orientation of the OH on the a-anomer in the Haworth projection?

<p>It points down (C)</p> Signup and view all the answers

What is the advantage of the Haworth projection over the Fisher projection?

<p>It is more realistic (D)</p> Signup and view all the answers

More Like This

Use Quizgecko on...
Browser
Browser