Molecular Geometry Quiz

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Questions and Answers

Match the following molecular geometries with their corresponding electron pair arrangements and approximate bond angles:

Bent = 2, 2, , <109.5° (<105°) Tetrahedral = 4, 0, 109.5° See-Saw = 5, 1, 90°, <120° Square Planar = 6, 2, 90° Square Pyramidal = 6, 1, 90°, <90° Trigonal Bipyramidal = 5, 0, 90°, 120° Linear = 2, 0, 180°

What is the electron pair arrangement and approximate bond angles for a molecule with 4 electron groups and 2 lone pairs?

  • Square planar, 90°
  • Bent, <109.5° (<105°) (correct)
  • Tetrahedral, 109.5°
  • Trigonal bipyramidal, 90°, 120°

A molecule with 5 electron groups with 1 lone pair has what electron pair arrangement and molecular geometry?

  • See-saw, 90°, <120° (correct)
  • Trigonal bipyramidal, 90°, 120°
  • Tetrahedral, 109.5°
  • T-structure, <90°

What is the bond angle of a molecule with a linear electron pair arrangement?

<p>180° (A)</p> Signup and view all the answers

A molecule with 6 electron groups and 0 lone pairs has an octahedral molecular geometry.

<p>True (A)</p> Signup and view all the answers

What is the electron pair arrangement for a molecule with 4 electron groups and 1 lone pair?

<p>Trigonal pyramidal (D)</p> Signup and view all the answers

A molecule with 5 electron groups and 2 lone pairs has a T-shaped molecular geometry.

<p>True (A)</p> Signup and view all the answers

Flashcards

Electron Pair Arrangement

The arrangement of electron groups (bonding pairs and lone pairs) around a central atom.

Molecular Geometry

The shape of a molecule determined by the positions of the atoms.

Bond Angle

The angle formed between two adjacent bonds.

Linear Electron Pair Arrangement

Two electron groups surrounding a central atom, with zero lone pairs. The atoms have a straight line arrangement.

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Linear Molecular Geometry

A molecule with two atoms connected in a straight line.

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Trigonal Planar Electron Pair Arrangement

Three electron groups surrounding a central atom, with zero lone pairs. The atoms form a flat triangle.

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Trigonal Planar Molecular Geometry

A molecule with three atoms forming a flat triangle.

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Bent Electron Pair Arrangement

Three electron groups surrounding a central atom, with one lone pair. The atoms form a bent or V shape.

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Bent Molecular Geometry

A molecule where two atoms are connected at an angle, creating a bent or V shape.

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Bond Angle in Linear Geometry

The bond angle in a linear molecular geometry is 180 degrees.

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Study Notes

Molecular Geometry

  • Electron pairs and lone pairs affect molecular shape.
  • Electron pair arrangement and molecular geometry are not always the same
  • Different numbers of lone pairs and electron groups result in different molecular shapes.
  • Bond angles are affected by repulsion between electron pairs.

Specific Geometries and Bond Angles

  • 2 Electron Groups:
    • Linear arrangement: 180° bond angle
  • 3 Electron Groups:
    • Trigonal planar arrangement: 120° bond angle
    • Bent arrangement: <120° bond angle
  • 4 Electron Groups:
    • Tetrahedral arrangement: 109.5° bond angle
    • Trigonal pyramidal arrangement: <109.5° (~107°) bond angle
    • Bent arrangement: <109.5° (~105°) bond angle
  • 5 Electron Groups:
    • Trigonal bipyramidal arrangement: 90°, 120° bond angles
    • See-saw arrangement: <90°, <120° bond angles
    • T-shaped arrangement: <90° bond angle
    • Linear arrangement: 180° bond angle
  • 6 Electron Groups:
    • Octahedral arrangement: 90°, 90° bond angles
    • Square pyramidal arrangement: 90°, <90° bond angles
    • Square planar arrangement: 90° bond angle

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