CH 15: Mechanism of reaction and of catalysis
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Questions and Answers

What is the role of a catalyst in a chemical reaction?

  • Decreasing the activation energy required for the reaction (correct)
  • Stopping the reaction from occurring
  • Changing the shape of the energy distribution curve
  • Increasing the activation energy required for the reaction
  • How does raising the temperature affect the reaction rate?

  • Decreases the proportion of molecules with energy exceeding activation energy
  • Reduces the number of collisions between reactant molecules
  • Shifts the Maxwell-Boltzmann curve to the right (correct)
  • Flattens the Maxwell-Boltzmann curve to the left
  • What is activation energy?

  • The total energy change in a chemical reaction
  • The energy released during a reaction
  • The energy needed for product formation
  • The minimum energy required for a chemical reaction to occur (correct)
  • How does increasing reactant concentration impact the reaction rate?

    <p>Results in more collisions and increased reaction rate</p> Signup and view all the answers

    What is one way catalysts work to accelerate chemical reactions?

    <p>Forming intermediate species with reactants</p> Signup and view all the answers

    How do biological catalysts, such as enzymes, contribute to biochemical reactions?

    <p>They act as highly efficient catalysts necessary for life processes</p> Signup and view all the answers

    What happens to the Maxwell-Boltzmann curve when a catalyst is present in a chemical reaction?

    <p>It increases in height and shifts to the right</p> Signup and view all the answers

    "Understanding how catalysts work allows chemists to design reactions that are faster, more selective, and less energy-intensive." This statement implies that:

    <p>'Less energy-intensive' reactions can be achieved with catalysts</p> Signup and view all the answers

    Why is studying catalysts and reaction mechanisms crucial according to the text?

    <p>For developing new chemical processes and improving efficiency</p> Signup and view all the answers

    How does a catalyst provide an alternative route for a chemical reaction with lower activation energy?

    <p>By offering a surface for effective collision of reactants</p> Signup and view all the answers

    What is the primary role of a catalyst in a chemical reaction?

    <p>To provide an alternative pathway with lower activation energy</p> Signup and view all the answers

    Which distribution illustrates the spread of kinetic energies among molecules in a substance?

    <p>Maxwell-Boltzmann distribution</p> Signup and view all the answers

    How does a catalyst affect the Maxwell-Boltzmann distribution?

    <p>It increases the area under the curve to the right of a lower activation energy</p> Signup and view all the answers

    What is the relationship between activation energy and the rate of a chemical reaction?

    <p>Higher activation energy leads to a slower reaction rate</p> Signup and view all the answers

    Which of the following statements about catalysts is incorrect?

    <p>Catalysts undergo permanent chemical changes during a reaction</p> Signup and view all the answers

    In the Maxwell-Boltzmann distribution, what does the area under the curve represent?

    <p>The total number of reactant molecules</p> Signup and view all the answers

    What is the significance of the area to the right of the activation energy threshold in the Maxwell-Boltzmann distribution?

    <p>It represents the fraction of molecules with sufficient energy to react</p> Signup and view all the answers

    How does a catalyst affect the activation energy of a chemical reaction?

    <p>It decreases the activation energy</p> Signup and view all the answers

    Which of the following statements about the Maxwell-Boltzmann distribution is true?

    <p>Most molecules have moderate kinetic energies, with fewer having very high or very low energies</p> Signup and view all the answers

    How does a catalyst affect the rate of a chemical reaction?

    <p>It increases the rate of the reaction</p> Signup and view all the answers

    Which of the following best describes the role of a catalyst in a chemical reaction?

    <p>It provides an alternative pathway with a lower activation energy, increasing the reaction rate.</p> Signup and view all the answers

    In the Maxwell-Boltzmann distribution, what does the area to the right of the activation energy threshold represent?

    <p>The fraction of molecules with sufficient energy to overcome the activation energy barrier.</p> Signup and view all the answers

    How does the presence of a catalyst affect the Maxwell-Boltzmann distribution for a chemical reaction?

    <p>It increases the area under the curve to the right of a lower activation energy threshold.</p> Signup and view all the answers

    Which of the following statements about catalysts is incorrect?

    <p>Catalysts undergo permanent chemical changes during the reaction they catalyze.</p> Signup and view all the answers

    What is the significance of the area under the Maxwell-Boltzmann distribution curve?

    <p>It represents the total number of molecules in the system.</p> Signup and view all the answers

    How does raising the temperature of a system affect the reaction rate in the presence of a catalyst?

    <p>It increases the reaction rate by providing more reactant molecules with sufficient energy to overcome the activation energy barrier.</p> Signup and view all the answers

    Which of the following statements best describes the relationship between activation energy and reaction rate?

    <p>Lower activation energy leads to a higher reaction rate.</p> Signup and view all the answers

    What is the primary role of a catalyst in a chemical reaction?

    <p>To provide an alternative pathway with a lower activation energy barrier.</p> Signup and view all the answers

    In the context of the Maxwell-Boltzmann distribution, how does a catalyst affect the fraction of molecules with sufficient energy to react?

    <p>It increases the fraction by increasing the area under the curve to the right of a lower activation energy threshold.</p> Signup and view all the answers

    Which of the following statements best describes the effect of a catalyst on the activation energy barrier of a chemical reaction?

    <p>It provides an alternative pathway with a lower activation energy barrier, making it easier for reactant molecules to overcome it.</p> Signup and view all the answers

    What is the primary effect of a catalyst on the shape of the distribution curve?

    <p>The shape of the distribution curve remains unchanged, but the required energy for reaction decreases.</p> Signup and view all the answers

    How does a catalyst affect the proportion of molecules with energies exceeding the activation energy?

    <p>It increases the proportion of molecules with energies exceeding the activation energy.</p> Signup and view all the answers

    Which of the following is NOT a way that catalysts typically work to accelerate chemical reactions?

    <p>Increasing the concentration of reactants in the reaction mixture.</p> Signup and view all the answers

    How does increasing the concentration of reactants affect the reaction rate according to the text?

    <p>Increasing the concentration of reactants increases the number of molecules in the reaction mixture but does not change the shape of the energy distribution, resulting in an increased reaction rate.</p> Signup and view all the answers

    What is the significance of the area to the right of the activation energy threshold in the Maxwell-Boltzmann distribution?

    <p>The area to the right of the activation energy threshold represents the fraction of molecules with kinetic energy greater than the activation energy, which can react.</p> Signup and view all the answers

    Which of the following statements about the effect of a catalyst on the Maxwell-Boltzmann distribution is correct?

    <p>The presence of a catalyst reduces the activation energy, increasing the fraction of molecules that can react, depicted as a larger shaded area under the curve at the same temperature.</p> Signup and view all the answers

    Which of the following statements about the role of biological catalysts, such as enzymes, is correct?

    <p>Biological catalysts, such as enzymes, act as highly efficient catalysts for biochemical reactions necessary for life.</p> Signup and view all the answers

    Which of the following statements about the relationship between activation energy and reaction rate is incorrect?

    <p>Increasing the activation energy of a reaction decreases the reaction rate.</p> Signup and view all the answers

    Which of the following is a key way that catalysts work to accelerate chemical reactions according to the text?

    <p>Catalysts work by providing a surface for the reactants to come together, reducing the energy needed for effective collisions.</p> Signup and view all the answers

    What is the main reason that the study of catalysts and reaction mechanisms is crucial according to the text?

    <p>The study of catalysts and reaction mechanisms is crucial for developing new chemical processes, improving energy efficiency, creating new materials, and understanding biological pathways.</p> Signup and view all the answers

    In the context of chemical reactions, what role does a catalyst play in the Maxwell-Boltzmann distribution?

    <p>Increasing the fraction of molecules with sufficient energy to react</p> Signup and view all the answers

    How does a catalyst impact the activation energy barrier in a chemical reaction?

    <p>Lowering the activation energy barrier for reactant particles</p> Signup and view all the answers

    What effect does a catalyst have on the spread of kinetic energies among molecules in a substance according to the Maxwell-Boltzmann distribution?

    <p>Enhancing the number of molecules with very high or very low energies</p> Signup and view all the answers

    What impact does a catalyst have on successful collisions in a chemical reaction, based on the Maxwell-Boltzmann distribution?

    <p>Increasing the number of successful collisions by decreasing activation energy</p> Signup and view all the answers

    How does a catalyst affect the fraction of molecules that can react in a chemical reaction, as shown in the Maxwell-Boltzmann distribution?

    <p>Increasing the fraction of molecules with sufficient energy to react</p> Signup and view all the answers

    What does the area under the curve in the Maxwell-Boltzmann distribution represent?

    <p>Total number of molecules at any temperature</p> Signup and view all the answers

    How does a catalyst alter the kinetic energies among molecules compared to uncatalyzed reactions based on the Maxwell-Boltzmann distribution?

    <p>Shifting more molecules to have sufficient energy for reactions</p> Signup and view all the answers

    What role does a catalyst play in providing an alternative pathway for a chemical reaction according to mechanism descriptions?

    <p>Lowering the activation energy required for successful reactions</p> Signup and view all the answers

    How does a catalyst contribute to increasing reaction rates based on mechanism descriptions?

    <p>By lowering activation energy and increasing successful collisions</p> Signup and view all the answers

    What impact does a catalyst have on successful collisions in a chemical reaction, based on mechanism descriptions?

    <p>Increasing collisions by providing alternative lower-energy pathway</p> Signup and view all the answers

    What is the main effect of a catalyst on a chemical reaction?

    <p>Lowers the energy required for effective collisions</p> Signup and view all the answers

    How does raising the temperature impact the Maxwell-Boltzmann distribution curve?

    <p>Shifts it to the right and flattens it</p> Signup and view all the answers

    In a chemical reaction, what does the presence of a catalyst enable?

    <p>More molecules to participate by lowering activation energy</p> Signup and view all the answers

    How do catalysts typically provide an alternative route for chemical reactions?

    <p>By forming intermediate species to reduce energy pathway</p> Signup and view all the answers

    What effect does increasing reactant concentration have on a chemical reaction?

    <p>Results in more collisions and increased reaction rate</p> Signup and view all the answers

    What is one primary implication of understanding catalysts and reaction mechanisms?

    <p>Designing faster and less energy-intensive reactions</p> Signup and view all the answers

    Why are enzymes considered highly efficient catalysts in biological systems?

    <p>Their effectiveness in facilitating biochemical reactions</p> Signup and view all the answers

    What is the function of biological catalysts, such as enzymes, in living organisms?

    <p>To lower activation energy barriers for reactions</p> Signup and view all the answers

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