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What is the effect of lanthanide contraction on the properties of elements?
What is the effect of lanthanide contraction on the properties of elements?
What is lanthanide contraction?
What is lanthanide contraction?
What causes the lanthanide contraction?
What causes the lanthanide contraction?
Which of the following best describes lanthanide contraction?
Which of the following best describes lanthanide contraction?
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How does lanthanide contraction affect the properties of elements?
How does lanthanide contraction affect the properties of elements?
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What causes the lanthanide contraction?
What causes the lanthanide contraction?
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Study Notes
Lanthanide Contraction Overview
- Lanthanide contraction refers to the gradual decrease in ionic radii and atomic sizes of the lanthanide series elements as atomic number increases.
- Occurs from lanthanum (La) to lutetium (Lu), where the size of the elements shrinks despite an increase in protons.
Causes of Lanthanide Contraction
- Caused primarily by the poor shielding effect of f-electrons.
- As more f-electrons are added, they do not shield the increasing positive charge of the nucleus effectively, leading to a stronger attraction that pulls electrons closer.
- This results in a reduced atomic radius across the series.
Effects on Element Properties
- Leads to similarities in ionic radii and chemical behavior among lanthanides.
- Affects physical and chemical properties such as melting points, boiling points, and ionization energies.
- The smaller size contributes to higher density and greater ionization energies when compared to preceding elements.
Impact on Subsequent Periods
- The contraction influences the elements in the 5d series (transition metals) following the lanthanides, creating a similarity in properties that wouldn’t be expected based solely on their position in the periodic table.
- Transition metals like hafnium (Hf) and zirconium (Zr) exhibit similar properties due to the contraction.
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Description
Test your knowledge on lanthanide contraction with this quiz! Learn about what it is, the causes behind it, and the impact it has on the properties of elements. Challenge yourself and become a lanthanide contraction expert!