IUPAC Nomenclature Rules for Alkanes

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Questions and Answers

What is the correct IUPAC name for an alkane with a parent chain of six carbon atoms?

  • Hexane (correct)
  • Pentane
  • Heptane
  • Octane

When numbering the parent chain of an alkane with substituents, what is the primary goal?

  • To give the substituents numbers based on their size.
  • To give the substituents the lowest possible numbers. (correct)
  • To give the carbon atoms in the parent chain the highest possible numbers.
  • To give the longest possible name.

In the IUPAC naming system, what separates numbers from words in the name of an organic compound?

  • A space
  • An underscore
  • A comma
  • A hyphen (correct)

How are multiple numbers separated when indicating the positions of identical substituents in an alkane name?

<p>With commas (D)</p> Signup and view all the answers

When listing multiple substituents in the name of an alkane, what determines the order in which they are written?

<p>Alphabetical order (D)</p> Signup and view all the answers

When alphabetizing substituents, which of the following prefixes is ignored?

<p>Di- (B)</p> Signup and view all the answers

Which of the following is the correct IUPAC name for a four-carbon alkane?

<p>Butane (A)</p> Signup and view all the answers

If numbering a carbon chain can start from either end, how to you determine the correct numbering?

<p>Consider the alphabetical order of substituents. (A)</p> Signup and view all the answers

You have the structure of an alkane and need to determine the systematic IUPAC name. Which of the options is the first thing you must do?

<p>Identify the longest continuous carbon chain. (D)</p> Signup and view all the answers

If alphabetizing substituents results in the same numbering set from either side of the parent chain, what determines where numbering starts?

<p>The first substituent encountered gets the lowest number. (A)</p> Signup and view all the answers

Flashcards

Parent Chain

The longest continuous sequence of carbon atoms in an organic molecule; used as the base for naming the compound.

Substituent

A group of atoms that are attached to the parent chain in an organic molecule.

Methane

A one-carbon alkane.

Ethane

A two-carbon alkane.

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Propane

A three-carbon alkane.

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Butane

A four-carbon alkane.

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Pentane

A five-carbon alkane.

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Numbering Rule

Lowest possible numbers should be given to the substituents.

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Alphabetical Order Rule

List in alphabetical order, ignoring prefixes like di-, tri-, tetra-.

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di-, tri-, tetra-

Use these prefixes to indicate multiple identical substituents.

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Study Notes

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