IUPAC naming, Isomers, and Molecular Formulas Quiz

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Questions and Answers

Which of the following best describes a structural isomer?

  • Same molecular formula, different connectivity (correct)
  • Different molecular formula, different connectivity
  • Same molecular formula, same connectivity
  • Different molecular formula, same connectivity

Which type of isomerism is exhibited by the E isomer of compound J, leaf alcohol?

  • Functional group isomerism
  • Chain isomerism
  • Positional isomerism
  • Geometric isomerism (correct)

If compound J has the molecular formula C6H14O, how many possible structural isomers could exist?

  • 8
  • 7 (correct)
  • 6
  • 5

What structural feature distinguishes the secondary amine among the isomers with the molecular formula C4H11N?

<p>Has a nitrogen atom bonded to two carbon atoms and one hydrogen atom (B)</p> Signup and view all the answers

What mass of maleic acid should have been obtained if 6.53 g of organic product were formed?

<p>16.53 g (D)</p> Signup and view all the answers

How many different structural isomers are possible for the molecular formula C₅H₁₂?

<p>4 (D)</p> Signup and view all the answers

What is the term used to describe molecules with the same molecular formula but different structural formulae?

<p>Constitutional isomers (C)</p> Signup and view all the answers

What is the mechanism involved when 2-bromo-2-methylpentane forms two structural isomers upon heating with potassium hydroxide in ethanol?

<p>Elimination (A)</p> Signup and view all the answers

Which of the following accurately describes structural isomers?

<p>They have different connectivity between atoms. (A)</p> Signup and view all the answers

What type of isomerism occurs in molecules that have the same molecular formula but different arrangements of atoms in space?

<p>Geometric isomerism (B)</p> Signup and view all the answers

What is the IUPAC name for isooctane?

<p>2,2,4-Trimethylpentane (B)</p> Signup and view all the answers

How many peaks would be observed in the 13C NMR spectrum of isooctane?

<p>10 peaks (B)</p> Signup and view all the answers

In the thermal cracking reaction given, why do the products indicate thermal cracking?

<p>Presence of unsaturated hydrocarbons (C)</p> Signup and view all the answers

How many monochloro isomers are formed by isooctane?

<p>5 isomers (C)</p> Signup and view all the answers

Which skeletal formula represents the monochloro compound formed when an isomer of isooctane reacts with chlorine?

<p><code>CH3CH2CH(CH3)CH(CH3)CH2CH(CH3)Cl</code> (B)</p> Signup and view all the answers

In the reaction where isooctane, propene, and ethene are formed, what type of isomerism are the resulting monochloro isomers classified as?

<p>Structural isomers (D)</p> Signup and view all the answers

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Study Notes

Haloalkanes

  • A haloalkane is an organic compound containing a halogen atom bonded to an alkyl group
  • Examples of haloalkanes include chloroalkanes, bromoalkanes, iodoalkanes, and fluoroalkanes

Structural Isomers

  • Structural isomers are molecules with the same molecular formula but different arrangements of atoms
  • The molecular formula C4H9Br has 4 structural isomers
  • The molecular formula C5H12 has 3 structural isomers

Leaf Alcohol (Compound J)

  • Compound J is also known as leaf alcohol, with the structural formula CH3CH2CH=CHCH2CH2OH
  • The E isomer of J is responsible for the smell of freshly cut grass
  • Dehydration of J using concentrated sulfuric acid forms a product with a specific skeletal formula

Isooctane (C8H18)

  • Isooctane is a branched-chain hydrocarbon that burns smoothly in car engines
  • The IUPAC name for isooctane can be determined from its skeletal formula
  • Isooctane has a specific 13C NMR spectrum with a certain number of peaks
  • Isooctane can be formed through the thermal cracking of an alkane with 20 carbon atoms, accompanied by propene and ethene

Thermal Cracking

  • Thermal cracking is a reaction where a large molecule breaks down into smaller molecules, often with the application of heat
  • The products of thermal cracking, such as isooctane, propene, and ethene, demonstrate the characteristics of thermal cracking

Monochloro Isomers of Isooctane

  • Isooctane can form several monochloro isomers, with one of them existing as a pair of optical isomers
  • The number of monochloro isomers formed by isooctane can be determined

Reaction Mechanisms

  • 2-bromo-2-methylpentane reacts with potassium hydroxide in ethanol to form two structural isomers
  • The mechanism for the formation of one of the isomers involves a specific reaction pathway

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