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Questions and Answers
Which of the following best describes a structural isomer?
Which of the following best describes a structural isomer?
- Same molecular formula, different connectivity (correct)
- Different molecular formula, different connectivity
- Same molecular formula, same connectivity
- Different molecular formula, same connectivity
Which type of isomerism is exhibited by the E isomer of compound J, leaf alcohol?
Which type of isomerism is exhibited by the E isomer of compound J, leaf alcohol?
- Functional group isomerism
- Chain isomerism
- Positional isomerism
- Geometric isomerism (correct)
If compound J has the molecular formula C6H14O, how many possible structural isomers could exist?
If compound J has the molecular formula C6H14O, how many possible structural isomers could exist?
- 8
- 7 (correct)
- 6
- 5
What structural feature distinguishes the secondary amine among the isomers with the molecular formula C4H11N?
What structural feature distinguishes the secondary amine among the isomers with the molecular formula C4H11N?
What mass of maleic acid should have been obtained if 6.53 g of organic product were formed?
What mass of maleic acid should have been obtained if 6.53 g of organic product were formed?
How many different structural isomers are possible for the molecular formula C₅H₁₂?
How many different structural isomers are possible for the molecular formula C₅H₁₂?
What is the term used to describe molecules with the same molecular formula but different structural formulae?
What is the term used to describe molecules with the same molecular formula but different structural formulae?
What is the mechanism involved when 2-bromo-2-methylpentane forms two structural isomers upon heating with potassium hydroxide in ethanol?
What is the mechanism involved when 2-bromo-2-methylpentane forms two structural isomers upon heating with potassium hydroxide in ethanol?
Which of the following accurately describes structural isomers?
Which of the following accurately describes structural isomers?
What type of isomerism occurs in molecules that have the same molecular formula but different arrangements of atoms in space?
What type of isomerism occurs in molecules that have the same molecular formula but different arrangements of atoms in space?
What is the IUPAC name for isooctane?
What is the IUPAC name for isooctane?
How many peaks would be observed in the 13C NMR spectrum of isooctane?
How many peaks would be observed in the 13C NMR spectrum of isooctane?
In the thermal cracking reaction given, why do the products indicate thermal cracking?
In the thermal cracking reaction given, why do the products indicate thermal cracking?
How many monochloro isomers are formed by isooctane?
How many monochloro isomers are formed by isooctane?
Which skeletal formula represents the monochloro compound formed when an isomer of isooctane reacts with chlorine?
Which skeletal formula represents the monochloro compound formed when an isomer of isooctane reacts with chlorine?
In the reaction where isooctane, propene, and ethene are formed, what type of isomerism are the resulting monochloro isomers classified as?
In the reaction where isooctane, propene, and ethene are formed, what type of isomerism are the resulting monochloro isomers classified as?
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Study Notes
Haloalkanes
- A haloalkane is an organic compound containing a halogen atom bonded to an alkyl group
- Examples of haloalkanes include chloroalkanes, bromoalkanes, iodoalkanes, and fluoroalkanes
Structural Isomers
- Structural isomers are molecules with the same molecular formula but different arrangements of atoms
- The molecular formula C4H9Br has 4 structural isomers
- The molecular formula C5H12 has 3 structural isomers
Leaf Alcohol (Compound J)
- Compound J is also known as leaf alcohol, with the structural formula CH3CH2CH=CHCH2CH2OH
- The E isomer of J is responsible for the smell of freshly cut grass
- Dehydration of J using concentrated sulfuric acid forms a product with a specific skeletal formula
Isooctane (C8H18)
- Isooctane is a branched-chain hydrocarbon that burns smoothly in car engines
- The IUPAC name for isooctane can be determined from its skeletal formula
- Isooctane has a specific 13C NMR spectrum with a certain number of peaks
- Isooctane can be formed through the thermal cracking of an alkane with 20 carbon atoms, accompanied by propene and ethene
Thermal Cracking
- Thermal cracking is a reaction where a large molecule breaks down into smaller molecules, often with the application of heat
- The products of thermal cracking, such as isooctane, propene, and ethene, demonstrate the characteristics of thermal cracking
Monochloro Isomers of Isooctane
- Isooctane can form several monochloro isomers, with one of them existing as a pair of optical isomers
- The number of monochloro isomers formed by isooctane can be determined
Reaction Mechanisms
- 2-bromo-2-methylpentane reacts with potassium hydroxide in ethanol to form two structural isomers
- The mechanism for the formation of one of the isomers involves a specific reaction pathway
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