Isomers

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Questions and Answers

What is the definition of stereoisomers?

  • Compounds with the same physical and chemical properties
  • Compounds with the same molecular formula but different spatial arrangement of atoms (correct)
  • Compounds with the same IUPAC names and different functional groups
  • Compounds with different IUPAC names and different functional groups

What distinguishes geometric stereoisomers from optical isomers?

  • Optical isomers have different physical properties, while geometric isomers have the same physical properties
  • Geometric isomers have different functional groups, while optical isomers have the same functional groups
  • Optical isomers exhibit chiral and optical activity, while geometric isomers are cis/trans isomers (correct)
  • Geometric isomers have identical IUPAC names, while optical isomers have different IUPAC names

What is the main difference between constitutional isomers and stereoisomers?

  • Constitutional isomers differ in the way atoms are oriented in space, while stereoisomers have different functional groups
  • Constitutional isomers have different physical properties, while stereoisomers have different chemical properties
  • Constitutional isomers have different IUPAC names, while stereoisomers have the same IUPAC names (correct)
  • Constitutional isomers have the same functional groups, while stereoisomers have different functional groups

What defines a molecule as chiral?

<p>Its mirror image is non-superimposable (D)</p> Signup and view all the answers

What is the term used to describe a particular three-dimensional arrangement of atoms in stereoisomers?

<p>Configuration (A)</p> Signup and view all the answers

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Study Notes

Stereoisomers

  • Molecules with the same molecular formula and the same connectivity of atoms but different spatial arrangements of atoms.
  • They differ in their three-dimensional structures.

Geometric and Optical Isomers

  • Geometric isomers are stereoisomers that differ in the arrangement of atoms around a double bond or a ring.
  • Optical isomers are stereoisomers that are non-superimposable mirror images of each other. They are also known as enantiomers.

Constitutional and Stereoisomers

  • Constitutional isomers are molecules with the same molecular formula but different connectivity of atoms. This means that the atoms are connected to each other in different orders.
  • Stereoisomers are molecules with the same molecular formula and the same connectivity of atoms but different spatial arrangements of atoms. This means that the atoms are connected to each other in the same order, but they are arranged differently in space.

Chirality

  • A molecule is chiral if it is non-superimposable on its mirror image.
  • This means that the molecule and its mirror image are different, just like your left and right hands.

Configuration

  • Configuration refers to the specific three-dimensional arrangement of atoms in a molecule.
  • It is a key feature that distinguishes stereoisomers.

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