ISC XII Chemistry Competency Questions
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Questions and Answers

Which vitamin deficiency causes rickets?

  • Vitamin A
  • Vitamin B
  • Vitamin C
  • Vitamin D (correct)

All vitamins are soluble in water.

False (B)

What is avitaminosis?

Avitaminosis is a condition caused by the deficiency of one or more vitamins in the body, leading to various health problems.

The process of ______ is used in the medical field to regulate fluid movement across cell membranes.

<p>osmosis</p> Signup and view all the answers

What method is used to prevent corrosion on ships?

<p>Cathodic Protection (B)</p> Signup and view all the answers

Match the following applications with their corresponding processes.

<p>Desalination = Reverse Osmosis Salt clumping prevention = Sodium ferrocyanide Preventing phosgene formation in chloroform = Adding C2H6O Fluid movement across cell membranes = Osmosis</p> Signup and view all the answers

What is the chemical formula of phosgene?

<p>COCl2</p> Signup and view all the answers

Chloroform is used as an ______ in medicine.

<p>anesthetic</p> Signup and view all the answers

Which statement about electrophilic substitution reactions in haloarenes is correct?

<p>Both Assertion (A) and Reason (R) are correct, but Reason (R) is not the correct explanation of Assertion (A). (B)</p> Signup and view all the answers

Benzaldehyde nitration produces only ortho nitrobenzaldehyde.

<p>False (B)</p> Signup and view all the answers

What effect does the -CHO group have on the reactivity of benzaldehyde in electrophilic nitration?

<p>-I effect</p> Signup and view all the answers

The half-life of a __________ reaction does not depend on the initial concentration of the reactant.

<p>first order</p> Signup and view all the answers

Match the following concepts with their descriptions:

<p>-CHO group = Exhibits -I effect Electrophilic substitution = Occurs at ortho and para positions First order reactions = Half-life independent of reactant concentration Inductive effect = Electron withdrawing effect</p> Signup and view all the answers

Why is the yield of para-substituted haloarenes generally favored?

<p>Resonance stabilization predominates for para products. (A)</p> Signup and view all the answers

Ethanol is more acidic than water due to the electron releasing effect of the ethyl group.

<p>False (B)</p> Signup and view all the answers

What is the reason that the half-life of a first order reaction does not depend on initial concentration?

<p>The expression for half-life is independent of concentration.</p> Signup and view all the answers

What does Kohlrausch's conclusion about specific conductivity imply?

<p>It is unique for each type of ion regardless of its source. (D)</p> Signup and view all the answers

Kohlrausch's law is applicable to both strong and weak electrolytes.

<p>True (A)</p> Signup and view all the answers

What is an example of a weak electrolyte mentioned in the content?

<p>Acetic acid</p> Signup and view all the answers

Kohlrausch concluded that each type of migrating ion has a specific __________.

<p>conductivity</p> Signup and view all the answers

Match the following terms with their descriptions:

<p>Strong electrolytes = Ions that dissociate completely in solution Weak electrolytes = Ions that partially dissociate in solution Specific conductivity = Unique conductivity for each ion regardless of source Kohlrausch's law = A principle relating conductivity to concentration</p> Signup and view all the answers

How can molar conductivity of acetic acid be calculated according to Kohlrausch's law?

<p>By multiplying its specific conductivity by its molar concentration. (B)</p> Signup and view all the answers

Conductivity of ions is influenced by their origin according to Kohlrausch.

<p>False (B)</p> Signup and view all the answers

What major observation did Kohlrausch make regarding weak electrolytes?

<p>More complex behavior compared to strong electrolytes.</p> Signup and view all the answers

What is hydroboration-oxidation primarily used for in organic chemistry?

<p>Converting alkenes to alcohols (B)</p> Signup and view all the answers

The presence of 3-nitrophenol makes it a stronger acid than phenol.

<p>True (A)</p> Signup and view all the answers

What reagent can be used to convert chloropropane to propan-2-ol?

<p>Soda lime</p> Signup and view all the answers

The ____ factor indicates the degree of dissociation of solute particles in solution.

<p>Van't Hoff</p> Signup and view all the answers

Match the following compounds with their properties:

<p>Phenol = Weak acid 4-methyl phenol = Less acidic than phenol 3-nitrophenol = Stronger acid than phenol Ethanol = Neutral alcohol</p> Signup and view all the answers

What is the result of applying pressure to a compartment containing a solvent in an osmosis experiment?

<p>Stops the flow of solvent (B)</p> Signup and view all the answers

Barium chloride dissociates completely in solution, resulting in a Van't Hoff factor greater than 3.

<p>False (B)</p> Signup and view all the answers

What is the boiling point elevation of a solution containing naphthalene?

<p>0.30 K</p> Signup and view all the answers

Which statement correctly explains why [𝐹𝐹𝐹𝐹(𝐻𝐻2 𝑂𝑂)6 ]2+ is strongly attracted to a magnet compared to [𝐹𝐹𝐹𝐹(𝐶𝐶𝐶𝐶)6 ]4−?

<p>[𝐹𝐹𝐹𝐹(𝐻𝐻2 𝑂𝑂)6 ]2+ is an inner orbital complex. (C)</p> Signup and view all the answers

Toluene reacts with chromyl chloride in 𝐶𝐶𝐶𝐶𝐶𝐶4 to give a compound that shows a yellow precipitate of iodoform.

<p>False (B)</p> Signup and view all the answers

What is the order of reaction if a student observes a parallel line with the X-axis in a plot of rate against concentration?

<p>Zero order</p> Signup and view all the answers

In nucleophilic substitution reactions, the most reactive compound from the following is ______.

<p>Formaldehyde</p> Signup and view all the answers

Which compound is least reactive towards nucleophilic substitution?

<p>Acetophenone (D)</p> Signup and view all the answers

A slow reaction will produce a negative slope in the rate vs concentration graph.

<p>False (B)</p> Signup and view all the answers

Match the compounds with their respective behaviors in nucleophilic substitution:

<p>Acetone = Least reactive Benzaldehyde = Moderately reactive Formaldehyde = Most reactive Acetophenone = Least reactive</p> Signup and view all the answers

Which compound shown below is likely to yield a brick red precipitate with Fehling's solution?

<p>Formaldehyde (B)</p> Signup and view all the answers

Flashcards

Weak Ligand

A coordination complex where the ligand is weakly bonded to the central metal ion, resulting in more instability and a higher tendency to lose the ligand.

Strong Ligand

A coordination complex where the ligand is strongly bonded to the central metal ion, resulting in greater stability and a lower tendency to lose the ligand.

Inner Orbital Complex

A coordination complex where the central metal ion uses only 'd' orbitals for bonding with ligands, resulting in low spin complexes.

Outer Orbital Complex

A coordination complex where the central metal ion uses both 'd' and 's' orbitals for bonding with ligands, leading to high spin complexes.

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Paramagnetic Complex

A complex where the central metal ion has unpaired electrons, making it attracted to a magnetic field.

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Diamagnetic Complex

A complex where the central metal ion has all paired electrons, making it have no attraction towards a magnetic field.

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Nucleophilic Substitution Reaction

A reaction where a molecule reacts with an electron-rich species (nucleophile) at a specific site, often an electrophilic center.

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Zero Order Reaction

The rate of a reaction is independent of the concentration of the reactant. The plot of rate against concentration gives a straight line parallel to the x-axis.

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Competency-Based Education

An educational approach that focuses on developing practical skills and knowledge that students can apply in real-world situations.

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Competency-Based Assessment

An approach to assessment that goes beyond rote memorization and focuses on evaluating a student's ability to apply knowledge and skills in complex situations.

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Council for the Indian School Certificate Examinations (CISCE)

A national-level examination board in India that promotes quality education and aims to integrate competency-based education into its curriculum and assessments.

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Teacher Capacity-Building

The process of providing teachers with training and resources to improve their skills and knowledge, particularly in the area of developing competency-based assessments.

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Higher-Order Thinking Questions

Questions designed to assess a student's ability to analyze information, solve problems, and think critically, often requiring them to apply their understanding in new contexts.

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Item Bank of Competency-Focused Practice Questions

A collection of practice questions that focus on developing specific skills and knowledge in a given subject area, often categorized by cognitive domain (understanding, analysis, application, etc.).

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Cognitive Learning Domains

Mental processes involved in learning, such as understanding, analyzing, applying, evaluating, and creating. These domains represent different levels of cognitive complexity.

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Assessment for Learning

Assessment that aims to gauge a student's understanding and ability to apply their knowledge and skills in real-world settings to develop their learning journeys.

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Electrophilic Substitution in Haloarenes

In haloarenes, electrophilic substitution occurs predominantly at the ortho and para positions, with the para product being the major one. This is due to the halogen's electron-withdrawing nature (-I effect) and its resonance stabilization.

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Nitration of Benzaldehyde

Benzaldehyde undergoes nitration to produce ortho and para nitro benzaldehyde, but not meta. This is due to the electron-withdrawing effect (-I) of the -CHO group, combined with the electron-donating resonance effect (+R) of the benzene ring.

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Half-life of First-Order Reaction

The half-life of a first-order reaction is independent of the initial concentration of the reactant. This means it takes the same amount of time for the concentration to halve, regardless of how much reactant is initially present.

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Acidity of Ethanol vs. Water

Ethanol (CH3CH2OH) has a lower acidity than water (H2O). This is because the electron-donating inductive effect of the ethyl group (CH3CH2-) on the ethanol molecule weakens the O-H bond, making it less likely to lose a proton (H+).

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Hydroboration-Oxidation

A reaction involving the addition of borane (BH3) to an alkene, followed by oxidation with hydrogen peroxide (H2O2) in the presence of a base, typically NaOH. It results in the formation of an alcohol with the hydroxyl group attached to the less substituted carbon atom of the double bond.

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Acidic Strength

The ability of a molecule to donate a proton (H+). A stronger acid will have a higher tendency to release a proton.

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3-Nitrophenol

The presence of the nitro group (-NO2) at the meta position increases the acidic strength of phenol by withdrawing electron density from the ring, making it more likely to release a proton.

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4-Methyl Phenol

The methyl group (+I effect) increases the electron density in the ring, making it less likely to release a proton, thus decreasing its acidic strength.

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Order of Acidity

Phenol is more acidic than 4-methylphenol but less acidic than 3-nitrophenol due to the electron-withdrawing effect of the nitro group.

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Van't Hoff factor

The van't Hoff factor (i) is a measure of the number of particles a solute dissociates into when dissolved in a solvent. It helps determine the extent of dissociation or association of a solute in solution.

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Van't Hoff factor and Dissociation

The van't Hoff factor (i) is directly related to the degree of dissociation (α) of a solute. For a strong electrolyte like barium chloride (BaCl2), the relationship is given by: i = 1 + α (n - 1), where n is the number of ions the solute dissociates into (in this case, n = 3: Ba2+ and 2Cl-)

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Solvent Flow

The flow of solvent will occur from the compartment with lower solute concentration (higher water potential) to the compartment with higher solute concentration (lower water potential).

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Kohlrausch's Law of Independent Migration of Ions

Each type of ion has a specific conductivity that doesn't depend on where the ion originated. This means that a chloride ion from sodium chloride will conduct electricity at the same rate as a chloride ion from potassium chloride.

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Explain Kohlrausch's Law

Kohlrausch's Law states that the molar conductivity of a strong electrolyte at infinite dilution can be determined by adding the molar conductivities of its constituent ions. This means you can predict the conductivity of a solution if you know the conductivities of its individual ions.

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Calculating Molar Conductivity of Weak Electrolytes

For a weak electrolyte, you can calculate the molar conductivity by measuring the conductivity of the solution at different concentrations and then extrapolating the values to infinite dilution. This is because weak electrolytes don't fully dissociate, so their conductivity at finite concentrations is lower than their theoretical value at infinite dilution.

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What is Rickets?

A deficiency in vitamin D that leads to weak bones and skeletal deformities. This condition is often seen in children.

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What is Scurvy?

This is a deficiency in Vitamin C that leads to poor wound healing, bleeding gums, and fragile blood vessels.

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What are vitamins?

Vitamins are organic compounds the body needs in small amounts. They're not directly involved in energy production, but they participate in various metabolic reactions and functions.

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What is Avitaminosis?

A condition where a person lacks sufficient amounts of one or more vitamins, leading to various health problems.

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What is osmosis?

The movement of water across a semi-permeable membrane from a region of high water concentration to a region of low water concentration.

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What is reverse osmosis?

This process reverses the natural flow of osmosis, using pressure to force water from a high salt concentration area to a low salt concentration area. It's commonly used to remove salt from seawater for drinking.

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How is reverse osmosis used for desalination?

A process that involves removing salt from seawater by using reverse osmosis to push saltwater through a semi-permeable membrane, leaving freshwater on the other side.

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What is corrosion?

The process of a metal being attacked by its environment, usually by a chemical reaction with the environment.

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Study Notes

ISC XII Chemistry, Competency-Focused Practice Questions

  • These practice questions are for ISC Class XII Chemistry, Paper 1-Theory.
  • They focus on competency-based education, going beyond rote memorization to develop critical thinking and problem-solving skills.
  • The questions cover various topics in chemistry, including multiple choice questions, assertion-reason questions, fill-in-the-blank questions, very short answer questions, short answer questions, long answer questions, and answer keys, all designed for higher order thinking.
  • The questions are accompanied by the relevant topic and cognitive learning domains they address, like understanding, analysis, application, evaluation, and creativity.

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This quiz features competency-based practice questions for ISC Class XII Chemistry, focusing on critical thinking and problem-solving. It includes multiple types of questions designed to enhance understanding and application of various chemistry topics. Ideal for students aiming to deepen their knowledge and prepare effectively for their exams.

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