Iron Enzymes and Catalase Mechanisms

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Questions and Answers

Catalase is a ______ enzyme.

heme

This enzyme brings about the disproportionation of ______ peroxide.

hydrogen

The chemical reaction releases ______ gas.

oxygen

The enzyme contains ______ or related compounds as a prosthetic group.

<p>heme</p> Signup and view all the answers

These enzymes catalyze the decomposition of peroxides especially ______ peroxide to oxygen and water.

<p>hydrogen</p> Signup and view all the answers

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Flashcards

Catalase

An enzyme that breaks down hydrogen peroxide (H₂O₂) into water (H₂O) and oxygen (O₂).

Disproportionation Reaction

A chemical reaction where a single substance acts as both the oxidizer and the reducer, resulting in the formation of two different products.

Prosthetic Group

A non-protein molecule that helps an enzyme function.

Peroxide

A compound containing an oxygen atom bonded to another oxygen atom.

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Enzyme Specificity

The ability of an enzyme to catalyze a specific chemical reaction.

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Study Notes

Metal Activated Enzymes: Iron Enzymes

  • Iron is an essential element in redox reactions in plant metabolism.
  • Catalases are heme enzymes.
  • Catalases catalyze the disproportionation of hydrogen peroxide.
  • Harmful H₂O₂ is decomposed into O₂ and H₂O.
  • The reaction is: 2H₂O₂ → O₂ + 2H₂O.

Catalase Mechanism

  • Catalase is an enzyme with a systematic name "donor hydrogen peroxide oxidoreductase".
  • It catalyzes the chemical reaction: (1) to release oxygen.
  • It's a strong catalyst using hydrogen peroxide as the donor.
  • It uses a prosthetic group, containing haematin or related compounds.
  • These enzymes catalyze the decomposition of peroxidases like hydrogen peroxide, breaking it down into oxygen and water.
  • This process avoids buildup of toxic peroxides.

Catalase as a Donor

  • Catalase has a donor role, receiving or accepting electrons.
  • The enzyme acts as an oxidising agent in some cases.

Chemical Reaction

  • The chemical reaction H₂O₂ is converted to products O₂ and H₂O.
  • Peroxide is the donor and is used as an oxidising agent by the enzyme.
  • The chemical reaction releases oxygen.
  • This chemical equation is 2H₂O₂ → O₂ + 2H₂O.

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