Iodimetric and Iodometric Methods
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Questions and Answers

Explain how the addition of HCO3- can push the reaction forward in the context of the given chemical equation and explanation?

The addition of HCO3- removes H+ ions, which lowers the potential of the AsO43-/AsO33- system, allowing arsenite to be oxidized quantitatively by iodine.

How can the presence of excess I2 push the reaction forward in the Fe3+/ Fe2+ system?

Excess I2 lowers the oxidation potential of the I2/I- system, allowing I- to be oxidized quantitatively into iodine.

Explain how the addition of F- or phosphate can push the reaction backward in the I2/2I- system & Cu2+/Cu+ system?

The addition of F- or phosphate forms complexes with Fe3+, lowering the oxidation potential of the I2/2I- system, which pushes the reaction backward.

What is the expected behavior of Cu2+ salts in the context of the given chemical equations?

<p>Cu2+ salts liberate iodine from iodides, despite the expectation that cuprous compounds would reduce iodine into iodide.</p> Signup and view all the answers

How does the increase of H+ ions push the reaction backward in the context of the given chemical equations and explanation?

<p>The increase of H+ ions increases the oxidation potential of the AsO43-/AsO33- system, causing arsenate to oxidize iodide in the presence of systems with oxidation potentials near that of the iodine/iodide system.</p> Signup and view all the answers

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