Anions Identification in Analytical Chemistry

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Questions and Answers

What color precipitate forms when thiocyanate (SCN-) reacts with SnCl2 and Co(NO3)2?

  • Blood red
  • Orange
  • White
  • Prussian blue (correct)

Which compound liberates toxic gas HCN when reacting with SnCl2?

  • Thiocyanate (SCN-) (correct)
  • [Fe(CN)6]3-
  • [Fe(CN)6]4-
  • Phosphate (PO3-4)

What color does the wet reaction of S.S with Magnesia mix produce in the presence of phosphate (PO3-4)?

  • White crystalline ppt
  • Chocolate brown ppt (correct)
  • Yellow ppt
  • -ve

What color does the wet reaction of S.S with AgNO3 solution produce in the presence of arsenate (AsO43-)?

<p>Yellow ppt on cold (A)</p> Signup and view all the answers

What color does the dry test of NO2 - powder with dil. HCl produce?

<p>Brown fumes (D)</p> Signup and view all the answers

Flashcards

SCN- + SnCl2 + Co(NO3)2 color?

Prussian blue precipitate.

HCN gas source with SnCl2?

Thiocyanate (SCN-).

S.S + Magnesia mix + PO43- color?

Chocolate brown precipitate.

S.S + AgNO3 + AsO43- color (cold)?

Yellow precipitate.

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NO2- powder + dil. HCl color?

Brown fumes.

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Study Notes

Chemical Reactions and Precipitates

  • Thiocyanate (SCN-) reacts with SnCl2 and Co(NO3)2 to form a red precipitate.
  • Thiocyanate (SCN-) liberates toxic gas HCN when reacting with SnCl2.
  • The wet reaction of Sulfide (S.S) with Magnesia mix in the presence of phosphate (PO3-4) produces a white color.
  • The wet reaction of Sulfide (S.S) with AgNO3 solution in the presence of arsenate (AsO43-) produces a yellow color.
  • The dry test of NO2 - powder with dil. HCl produces a brown color.

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