Introduction to Environmental Chemistry

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Questions and Answers

Who first detected chlorofluorocarbons (CFCs) in the atmosphere?

  • James Lovelock (correct)
  • Paul Crutzen
  • Arie Jan Haagen-Smit
  • Gordon Dobson

Sydney Chapman contributed to the understanding of photochemical smog.

False (B)

What is the term used to describe the average time a gas spends in the atmosphere?

Residence Time

In 1995, Paul Crutzen, Mario Molina, and Frank Sherwood Rowland were awarded the __________ for their work in atmospheric chemistry.

<p>Nobel Prize in Chemistry</p> Signup and view all the answers

Match the scientist with their corresponding discovery:

<p>Gordon Dobson = Measurements of total-column ozone Sydney Chapman = Ozone layer theory Arie Jan Haagen-Smit = Emergence of photochemical smog James Lovelock = Detection of CFCs</p> Signup and view all the answers

What were the primary components of the Earth's primitive atmosphere?

<p>Hydrogen and helium (A)</p> Signup and view all the answers

The secondary atmosphere formed after the Earth cooled was primarily composed of nitrogen and oxygen.

<p>False (B)</p> Signup and view all the answers

What role did volcanic activity play in the formation of the secondary atmosphere?

<p>It released gases from the Earth's interior that formed the secondary atmosphere.</p> Signup and view all the answers

The atmosphere that formed due to the cooling of Earth and the release of gases from volcanoes is called the ________ atmosphere.

<p>secondary</p> Signup and view all the answers

Match the following stages of atmospheric formation with their characteristics:

<p>Primitive Atmosphere = Comprised mainly of hydrogen and helium Secondary Atmosphere = Formed from volcanic gases Oxidizing Atmosphere = Characterized by the presence of oxygen</p> Signup and view all the answers

Which gas was formed by the breakdown of ammonia molecules through sunlight?

<p>Nitrogen (D)</p> Signup and view all the answers

The early atmosphere was able to withstand strong solar winds due to the Earth's magnetic field.

<p>False (B)</p> Signup and view all the answers

What process led to the formation of oxygen in the atmosphere?

<p>Photochemical dissociation of water vapor by ultraviolet radiation</p> Signup and view all the answers

Which of the following is classified as a constant gas in the atmosphere?

<p>Nitrogen (C)</p> Signup and view all the answers

Carbon dioxide is classified as a highly variable gas in the atmosphere.

<p>False (B)</p> Signup and view all the answers

What process allows nitrogen to become part of living organisms?

<p>Nitrogen fixation</p> Signup and view all the answers

The third most abundant gas in the atmosphere is ______.

<p>argon</p> Signup and view all the answers

Match the following gases with their correct classification:

<p>Nitrogen = Constant gas Carbon dioxide = Variable gas Water vapor = Highly variable gas Nitrous oxide = Long-lived trace gas</p> Signup and view all the answers

Which of the following percentage represents the abundance of oxygen in the atmosphere?

<p>20.95% (D)</p> Signup and view all the answers

Nitrogen can be fixed by soil bacteria or through lightning during precipitation.

<p>True (A)</p> Signup and view all the answers

What role does photosynthesis play in the exchange of oxygen?

<p>It produces oxygen.</p> Signup and view all the answers

What is the typical pH level range for bodies of water?

<p>6 to 9.5 (A)</p> Signup and view all the answers

Hard water dissolves easily with soap.

<p>False (B)</p> Signup and view all the answers

What branch of science deals with the chemical composition and reactions of soils?

<p>soil chemistry</p> Signup and view all the answers

The smallest unit that can be considered soil is called a ______.

<p>pedon</p> Signup and view all the answers

What percentage of the Earth's crust is composed of inorganic components by volume?

<p>90% (B)</p> Signup and view all the answers

Secondary minerals are formed from the weathering of primary minerals.

<p>True (A)</p> Signup and view all the answers

Which of the following cations primarily contribute to water hardness?

<p>Calcium and magnesium (A)</p> Signup and view all the answers

Match the following soil components with their description:

<p>Peds = Aggregation of soil particles into larger structures Profiles = Layers of varying texture and structure in soil Pedon = The smallest identifiable unit of soil Polypedon = An area of similar pedons</p> Signup and view all the answers

Name one common example of a primary mineral.

<p>quartz</p> Signup and view all the answers

Environmental soil chemistry focuses solely on soil reactions affecting plant growth.

<p>False (B)</p> Signup and view all the answers

Soil organic matter, also known as ______, includes total organic compounds in soils.

<p>humus</p> Signup and view all the answers

What elements are found in soils in the highest quantities?

<p>O, Si, Al, Fe, C, Ca, K, Na, Mg</p> Signup and view all the answers

Match the following mineral types with their characteristics:

<p>Primary minerals = Not chemically altered since deposition Secondary minerals = Result from the weathering of primary minerals Inorganic components = Make up more than 90% of solid components of soil Soil organic matter = Total organic compounds in soil excluding undecayed tissues</p> Signup and view all the answers

What is the primary definition of soil organic matter (SOM)?

<p>Mixture of plant and animal residues in various decomposition stages (B)</p> Signup and view all the answers

Cation exchange capacity (CEC) of soil humus refers to the ability of humus to retain water only.

<p>False (B)</p> Signup and view all the answers

Name one method of soil decontamination that does not require excavation.

<p>In situ methods</p> Signup and view all the answers

The method that uses plants to decontaminate soils is called __________.

<p>phytoremediation</p> Signup and view all the answers

Which of the following is an effective method for degrading non-volatile contaminants in soils?

<p>Biodegradation (D)</p> Signup and view all the answers

Match the following soil decontamination methods with their descriptions:

<p>Volatilization = Air is vented through soil to remove volatile compounds Biodegradation = Enhancing natural microbes to degrade contaminants Phytoremediation = Using plants to absorb chemicals from soil Excavation = Physically removing contaminated soil for treatment</p> Signup and view all the answers

Volatilization works effectively on non-volatile organic carbons.

<p>False (B)</p> Signup and view all the answers

List a chemical that sunflowers can absorb as part of phytoremediation.

<p>Uranium</p> Signup and view all the answers

Flashcards

Dobson Spectrophotometer

A device for measuring ozone in the atmosphere.

Ozone Layer Theory

Explanation of ozone layer existence, created in 1930.

Photochemical Smog

Air pollution caused by chemical reactions in the atmosphere.

CFCs in Atmosphere

Chlorofluorocarbons detected in the atmosphere in 1973.

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Nobel Prize in Atmospheric Chemistry

Awarded in 1995 for ozone research.

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Primitive Atmosphere

The Earth's early atmosphere, primarily composed of hydrogen and helium, along with some simple compounds like ammonia and methane.

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Secondary Atmosphere

The atmosphere formed after the Earth cooled, mainly composed of water vapor, carbon dioxide, and ammonia. It was also known as the reducing atmosphere.

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Oxidizing Atmosphere

The atmosphere that formed after UV radiation broke down water vapor, creating oxygen. However, the amount of oxygen from this process was minimal.

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Earth's Formation

The Earth formed as a hot, molten rock, resulting in the initial atmosphere.

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Volcanic Activity

Active volcanoes released gases from the Earth's interior, contributing to the secondary atmosphere.

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Water Vapor Condensation

As the atmosphere cooled, water vapor condensed into clouds, leading to the formation of oceans.

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Atmospheric CO2 Absorption

The process where oceans absorbed carbon dioxide from the atmosphere.

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Photochemical Dissociation

The breaking down of water vapor by strong ultraviolet radiation, which resulted in the formation of oxygen.

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Major components of atmosphere

The most abundant gases in the atmosphere, primarily nitrogen, oxygen, and argon.

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Trace gases

Gases present in much smaller amounts than major components, including noble gases, and others like methane and nitrous oxide.

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Nitrogen's role

Essential for living organisms, removed from the atmosphere, enters living systems through the nitrogen cycle.

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Nitrogen Fixation

Conversion of atmospheric nitrogen (N2) into ammonia (NH3), a usable form for living beings.

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Oxygen's role

Crucial for living things, exchanged between atmosphere and biosphere via photosynthesis and respiration.

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Argon's source

Mostly a radiogenic isotope formed from potassium decay in Earth's crust.

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Constant Gases

Atmospheric gases with relatively stable concentrations over time.

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Variable Gases

Atmospheric gases with concentrations that fluctuate within a range over time.

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What makes up most of the Earth's crust?

Inorganic components of soil, primarily minerals, make up over 90% of the Earth's crust by weight.

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What are primary minerals?

Primary minerals are minerals that haven't been chemically altered since they formed from molten lava.

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Quartz and feldspar

These are common examples of primary minerals found in soils.

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What are secondary minerals?

Secondary minerals form from the weathering of primary minerals, through changes in their structure or reprecipitation.

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Humus

Humus is another name for soil organic matter (SOM), which includes all the organic compounds in soil.

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Water Hardness

The presence of divalent metallic cations, like calcium, magnesium, strontium, iron, and manganese, in water, mainly originating from limestone formations.

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Soil Chemistry

The study of chemical composition, properties, and reactions within soil, focusing on how these factors influence plant growth and the environment.

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Environmental Soil Chemistry

A branch of soil chemistry investigating chemical reactions in soil concerning environmental contaminants, like metals and organic chemicals, and their impacts on living things.

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Peds

Larger soil structures formed by the aggregation of sand, silt, and clay particles, often shaped by soil-forming factors.

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Soil Profiles

Distinct layers within the soil, each with varying texture, structure, color, and other properties, developing from the surface to the underlying rock.

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Pedon

The smallest unit considered 'soil,' including all horizons from the surface down to the underlying rock.

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Polypedon

An area containing similar pedons, indicating a consistent soil type.

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Most Prevalent Soil Elements

Oxygen, silicon, aluminum, iron, carbon, calcium, potassium, sodium, and magnesium are the most abundant elements found in soils.

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Soil Organic Matter (SOM)

A complex mixture of decomposed plant and animal matter, microbial byproducts, and living organisms.

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In Situ Soil Decontamination

Cleaning up contaminated soil without removing it from the site.

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Volatilization

Removing contaminants by turning them into vapors and removing them using air flow.

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Biodegradation

Breaking down contaminants using naturally occurring microbes in the soil.

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Phytoremediation

Using plants to clean up soil and water contamination.

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Cation Exchange Capacity (CEC)

A measure of soil's ability to retain positively charged nutrients.

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Non-in-situ Soil Decontamination

Cleaning up contaminated soil by removing it from the site for treatment.

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Study Notes

Introduction to Chemistry of the Environment

  • The environment is a complex system involving air, land, water, and climate.
  • Chemistry is important for understanding, monitoring, protecting, and improving the environment.
  • Chemists develop tools and techniques for measuring and understanding pollution.
  • Chemistry helps to understand climate change.

Formation of the Atmosphere

  • Primitive Atmosphere: Early Earth was a hot molten rock with hydrogen, helium, ammonia, and methane.
  • Strong solar winds blew away the primitive atmosphere due to the lack of a magnetic field.
  • Secondary Atmosphere: Volcanic activity released gases like water vapor, carbon dioxide, and ammonia, forming a reducing atmosphere similar to Mars and Venus.
  • Precipitation formed oceans, absorbing CO2.
  • Breakdown of ammonia formed nitrogen. Other gases included hydrogen, methane, carbon monoxide, hydrogen sulfide, sulfur dioxide, and chlorine.
  • Oxidizing Atmosphere: Photochemical dissociation of water vapor by UV radiation produced oxygen. However, the amount was negligible initially.
  • Most of the oxygen came from photosynthetic organisms including cyanobacteria.

Atmospheric Chemistry

  • Atmosphere: A mixture of gases surrounding Earth.
  • Atmospheric gases are classified by their amount and residence time.
  • Important Discoveries: Scientists and the years they discovered various elements in the atmosphere are provided in tabular format. This includes Carbon Dioxide (Joseph Black, 1750s) and other elements.
  • Ozone Layer: The formation of the ozone layer became crucial for life on Earth by absorbing UV radiation.

Composition of the Atmosphere

  • Atmospheric gases are classified by amount (major components and trace gases) and residence time (constant, variable, highly variable).
  • Nitrogen, oxygen, argon, and carbon dioxide make up most of the atmosphere.
  • Properties like residence time and amount help classify different gases.
  • Various gases have different roles and impacts on the environment.

Water Chemistry

  • Water is a chemical compound made of hydrogen and oxygen atoms.
  • Water has a significant impact on weather and climate.
  • Water vapor absorbs solar radiation, impacting temperature and climate.
  • Water is an excellent solvent, a crucial property for biological processes.
  • High specific heat and surface tension contribute to various biological and physical properties of water.

Soil Chemistry

  • Soils are mixtures of inorganic materials (sand, silt, clay) and organic matter (humus) and microorganisms.
  • Soil chemistry focuses on the chemical reactions in soil that affect plant growth and other biota.
  • Inorganic components include primarily quartz and feldspar minerals.
  • Organic components include dead plant and animal matter, decomposed products, and live microorganisms.

Water Pollution

  • Parameters of Pollution: Physical (color, odor, turbidity) and chemical (carbonates, sulfates).
  • Sources: Point sources (direct discharge) and non-point sources (runoff) and could be natural or anthropogenic.
  • Types of Pollutants: Pathogens, organic pollutants, inorganic pollutants, radioactive materials, heat, and sediments.
  • Effects: Depletion of dissolved oxygen, health problems, destruction of marine life, aesthetic damage.

Factors Affecting Water Quality

  • Temperature, influences chemical and biological processes (thermal stratification).
  • Dissolved oxygen is crucial for aquatic life.
  • Alkalinity measures water's acid-neutralizing capacity.
  • Acidity is caused by dissolved carbon dioxide and other substances from industries.

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