Introduction to Environmental Chemistry
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Questions and Answers

Which organisms were the first to undergo photosynthesis and release oxygen?

  • Plants
  • Algae
  • Cyanobacteria (correct)
  • Fungi

The ozone layer was formed as a result of O$_2$ molecules absorbing UV radiation.

True (A)

What gas was used in the oxidation of metals like iron as oxygen levels began to rise?

Oxygen

The Karman Line identifies the boundary between the atmosphere and __________.

<p>outer space</p> Signup and view all the answers

Match the discovered elements/compounds with their discoverers:

<p>Carbon dioxide = Joseph Black Hydrogen = Henry Cavendish Nitrogen = Daniel Rutherford Ozone = Christian Friedrich Schonbein</p> Signup and view all the answers

What role did plants play in the atmosphere as higher life forms emerged?

<p>Producing oxygen (B)</p> Signup and view all the answers

The atmosphere acts as a barrier that prevents life on Earth from thriving.

<p>False (B)</p> Signup and view all the answers

In what year was oxygen discovered?

<p>1774</p> Signup and view all the answers

What is the main reason water has high surface tension?

<p>Hydrogen bonds (B)</p> Signup and view all the answers

Water expands when it freezes.

<p>True (A)</p> Signup and view all the answers

What are the two main sources of usable fresh water?

<p>Surface water and ground water</p> Signup and view all the answers

What are aquifers?

<p>Layers of soil and rocks that store water (C)</p> Signup and view all the answers

The process by which water is continuously replenished in the environment is called the ______.

<p>hydrological cycle</p> Signup and view all the answers

Match the following terms with their definitions:

<p>Cohesion = The property that allows water molecules to stick together Osmosis = The movement of water through a semipermeable membrane Specific Heat Capacity = The amount of energy required to raise the temperature of a substance Capillary Action = The ability of water to flow in narrow spaces against gravity</p> Signup and view all the answers

Point sources of water pollution come from indirect sources like runoff.

<p>False (B)</p> Signup and view all the answers

Name one common natural source of water pollution.

<p>Siltation</p> Signup and view all the answers

Which of the following statements is true regarding ground water?

<p>It fills the pores between soil particles and rocks (D)</p> Signup and view all the answers

97% of the Earth's water is fresh water.

<p>False (B)</p> Signup and view all the answers

Groundwater pollution occurs when polluted water seeps into an ______.

<p>aquifer</p> Signup and view all the answers

What role do certain organisms in surface water play?

<p>They break down pollutants into harmless substances.</p> Signup and view all the answers

Which of the following is an example of an anthropogenic source of water pollution?

<p>Agricultural runoff (A)</p> Signup and view all the answers

Non-point sources of pollution are easier to manage than point sources.

<p>False (B)</p> Signup and view all the answers

What can cause groundwater pollution in cities and towns?

<p>Raw sewage dumped on soil</p> Signup and view all the answers

Match the types of water pollution with their descriptions:

<p>Point Sources = Directly discharge pollutants into water bodies Non-Point Sources = Indirectly affect water bodies through runoff Natural Sources = Increase concentration of naturally occurring substances Anthropogenic Sources = Caused by human activities and wastes</p> Signup and view all the answers

What is a significant factor affecting the dissolved oxygen levels in the hypolimnion?

<p>Biodegradable organic material (C)</p> Signup and view all the answers

An increase in water temperature has no effect on the metabolic rates of aquatic organisms.

<p>False (B)</p> Signup and view all the answers

What is the primary chemical that contributes to the alkalinity of water?

<p>Bicarbonates</p> Signup and view all the answers

Dissolved oxygen is vital for the survival of underwater organisms, including _______ and invertebrates.

<p>fish</p> Signup and view all the answers

Which of the following is a common source of acidity in water bodies?

<p>Carbon dioxide (D)</p> Signup and view all the answers

Acidity from industrial waste primarily originates from sulfuric acid.

<p>True (A)</p> Signup and view all the answers

What is the impact of thermal pollution on aquatic life?

<p>It increases water temperature, potentially harming aquatic organisms.</p> Signup and view all the answers

What major issue contributes to groundwater pollution?

<p>Nitrogenous fertilizers (B)</p> Signup and view all the answers

Groundwater pollution is easier to trace because it originates from specific sources.

<p>False (B)</p> Signup and view all the answers

What phenomenon is described as having a significant temperature difference between layers in a body of water?

<p>Thermal Stratification</p> Signup and view all the answers

The layer between the epilimnion and hypolimnion is called the ______.

<p>thermocline</p> Signup and view all the answers

Which layer of a water body is known for heavy algae growth due to sunlight exposure?

<p>Epilimnion (D)</p> Signup and view all the answers

Groundwater has direct access to air, allowing pollutants to oxidize.

<p>False (B)</p> Signup and view all the answers

Impurities that infiltrate the ground water may be found at a ______ point far from the source.

<p>different</p> Signup and view all the answers

What does SOM stand for?

<p>Soil Organic Matter (A)</p> Signup and view all the answers

In situ techniques for soil decontamination require the excavation of soil.

<p>False (B)</p> Signup and view all the answers

What is the primary purpose of phytoremediation?

<p>To use plants for decontaminating soils and water.</p> Signup and view all the answers

The technique that enhances naturally occurring microorganisms to degrade soil contaminants is known as __________.

<p>biodegradation</p> Signup and view all the answers

Match each decontamination technique with its description:

<p>Volatilization = Mechanically drawing air through soil to remove resistant compounds Biodegradation = Boosting microbes to degrade soil contaminants Phytoremediation = Using plants to absorb chemicals from soil In situ = Methods used directly at the contamination site</p> Signup and view all the answers

Which of the following is NOT a characteristic of soil humus?

<p>Inability to decompose (B)</p> Signup and view all the answers

Volatilization is effective for both volatile and non-volatile contaminants.

<p>False (B)</p> Signup and view all the answers

What is the main advantage of using in situ methods for soil decontamination?

<p>Minimization of exposure pathways.</p> Signup and view all the answers

What property of water allows insects to walk on its surface?

<p>Cohesion (C)</p> Signup and view all the answers

About 75% of Earth's water is fresh water.

<p>False (B)</p> Signup and view all the answers

What process allows water to rise through plants to their tops?

<p>Capillary action</p> Signup and view all the answers

The continuous movement of water through evaporation, condensation, and precipitation is known as the ______.

<p>water cycle</p> Signup and view all the answers

Why is water considered an effective cooling agent?

<p>It has high specific heat capacity (C)</p> Signup and view all the answers

What is the primary source of fresh water on Earth?

<p>Glaciers and polar ice caps</p> Signup and view all the answers

What was the primary by-product of photosynthesis released by cyanobacteria?

<p>Oxygen (C)</p> Signup and view all the answers

The ozone layer was formed directly from the nitrification of soil.

<p>False (B)</p> Signup and view all the answers

What is the significance of the Karman Line?

<p>It identifies the boundary between the atmosphere and outer space.</p> Signup and view all the answers

The thick mixture of gases surrounding our planet is called __________.

<p>air</p> Signup and view all the answers

Match the year of discovery with the respective element or compound:

<p>1750s = Carbon dioxide 1766 = Hydrogen 1774 = Oxygen 1840 = Ozone</p> Signup and view all the answers

What role did plants play in the rise of atmospheric O$_2$ levels?

<p>They produced oxygen through photosynthesis. (D)</p> Signup and view all the answers

Who discovered ozone in 1840?

<p>Christian Friedrich Schonbein</p> Signup and view all the answers

As altitude increases, the amount of atmospheric material also increases.

<p>False (B)</p> Signup and view all the answers

Which gas is considered a highly variable gas in the atmosphere?

<p>Water vapor (A)</p> Signup and view all the answers

Oxygen is primarily removed from the atmosphere through the process of nitrogen fixation.

<p>False (B)</p> Signup and view all the answers

What process allows nitrogen to be converted into ammonia in the nitrogen cycle?

<p>Nitrogen fixation</p> Signup and view all the answers

The third most abundant gas in the atmosphere is ______.

<p>argon</p> Signup and view all the answers

Match the atmospheric gas with its main characteristic:

<p>Nitrogen = Inert and essential for living systems Oxygen = Crucial for photosynthesis and respiration Argon = Radiogenic isotope derived from potassium decay Carbon Dioxide = Key variable gas in climate change</p> Signup and view all the answers

Which of the following gases is classified as a trace gas?

<p>Carbon monoxide (C)</p> Signup and view all the answers

Methane is classified as a constant gas in the atmosphere.

<p>False (B)</p> Signup and view all the answers

What is the most abundant gas in the Earth's atmosphere?

<p>Nitrogen</p> Signup and view all the answers

What is the primary disadvantage of the leaching method for soil decontamination?

<p>It produces large volumes of wastewater. (C)</p> Signup and view all the answers

Vitrification can immobilize contaminants for up to 5,000 years.

<p>False (B)</p> Signup and view all the answers

What is the main purpose of land treatment in soil decontamination?

<p>To promote natural biodegradation processes.</p> Signup and view all the answers

The process of __________ involves applying extreme heat to contaminated soil to break down pollutants.

<p>thermal treatment</p> Signup and view all the answers

Match the soil decontamination method with its primary feature:

<p>Leaching = Uses water and surfactant to remove contaminants Vitrification = Solidifies contaminants with electric current Land Treatment = Excavated soil is spread for natural decomposition Solidification/Stabilization = Encapsulates contaminants with additives</p> Signup and view all the answers

Which statement best describes the process of asphalt incorporation in soil decontamination?

<p>It mixes contaminated soil into hot asphalt for road paving. (C)</p> Signup and view all the answers

Solidification/Stabilization completely destroys contaminants in the soil.

<p>False (B)</p> Signup and view all the answers

What is a primary economic concern associated with the vitrification method?

<p>High electricity costs.</p> Signup and view all the answers

What are aquifers primarily used for?

<p>Holding water (D)</p> Signup and view all the answers

Point sources of water pollution come from indirect sources such as runoff.

<p>False (B)</p> Signup and view all the answers

Name one common anthropogenic source of water pollution.

<p>Industrial waste</p> Signup and view all the answers

Pollution due to human activities is referred to as __________ sources.

<p>anthropogenic</p> Signup and view all the answers

Match the following types of water pollution with their descriptions:

<p>Surface Water Pollution = Pollution affecting lakes, rivers, and oceans Ground Water Pollution = Pollution that occurs when water seeps into aquifers Point Source Pollution = Pollution from a single, identifiable source Non-Point Source Pollution = Pollution from diffuse and indirect sources</p> Signup and view all the answers

Which type of pollution is more challenging to manage?

<p>Non-point source pollution (A)</p> Signup and view all the answers

Siltation is a consequence of human activities such as deforestation.

<p>True (A)</p> Signup and view all the answers

Raw sewage dumped on soil can cause ________ pollution when it seeps into aquifers.

<p>groundwater</p> Signup and view all the answers

What gases primarily comprised the primitive atmosphere of Earth?

<p>Hydrogen and Helium (B)</p> Signup and view all the answers

The secondary atmosphere of Earth was formed by the condensation of water vapor.

<p>True (A)</p> Signup and view all the answers

What type of atmosphere formed after the primitive atmosphere as Earth cooled?

<p>Secondary atmosphere</p> Signup and view all the answers

The primary gaseous components released by volcanic activity that formed the secondary atmosphere were _____, water vapor, and ammonia.

<p>carbon dioxide</p> Signup and view all the answers

Match the atmospheric stages with their characteristics:

<p>Primitive Atmosphere = Mainly hydrogen and helium Secondary Atmosphere = Water vapor, carbon dioxide, ammonia Oxidizing Atmosphere = Formation of oxygen through photochemical dissociation Inert Nitrogen = Formed from the breakdown of ammonia</p> Signup and view all the answers

What phenomenon allowed the formation of oxygen in the atmosphere?

<p>Photochemical dissociation of water vapor (A)</p> Signup and view all the answers

Strong solar winds blew away the primitive atmosphere due to Earth's lack of a magnetic field.

<p>True (A)</p> Signup and view all the answers

As the atmosphere cooled, most of the water vapor condensed and formed _____ which eventually created oceans.

<p>clouds</p> Signup and view all the answers

What was the primary beneficial role of the ozone layer in Earth's atmosphere?

<p>It protects life from harmful UV radiation (A)</p> Signup and view all the answers

The atmosphere is a thin layer of gases surrounding Earth and does not change with altitude.

<p>False (B)</p> Signup and view all the answers

Which organism was primarily responsible for the first significant production of oxygen on Earth?

<p>Cyanobacteria</p> Signup and view all the answers

The __________ line identifies the boundary between the atmosphere and outer space.

<p>Karman</p> Signup and view all the answers

What was one of the first gaseous elements discovered in the 18th century?

<p>Hydrogen (D)</p> Signup and view all the answers

Match each discovered element/compound with the corresponding discoverer:

<p>Carbon dioxide = Joseph Black Oxygen = Joseph Priestly and Carl Wilhem Scheele Ozone = Christian Friedrich Schonbein Argon = Lord Rayleigh and William Ramsay</p> Signup and view all the answers

The oxygen released during photosynthesis was crucial for the oxidation of metals like copper.

<p>False (B)</p> Signup and view all the answers

What was the effect of oxygen accumulation in the atmosphere on the Earth's environment?

<p>It allowed for the development of the ozone layer and supported life.</p> Signup and view all the answers

Which of the following best defines soil organic matter (SOM)?

<p>The total organic compounds in soils, excluding undecayed tissues (C)</p> Signup and view all the answers

Fulvic acid is the insoluble fraction of soil organic matter.

<p>False (B)</p> Signup and view all the answers

What is the function of organic matter in soil regarding water retention?

<p>Organic matter can hold up to 20 times its weight in water.</p> Signup and view all the answers

The alkali insoluble fraction of soil organic matter is called ______.

<p>Humin</p> Signup and view all the answers

Match the following organic soil components with their descriptions:

<p>Humic substances = High-molecular-weight substances formed by synthesis reactions Soil biomass = Organic matter present as live microbial tissue Humic acid = Dark-colored organic material extracted by reagents Nonhumic substances = Compounds like amino acids and carbohydrates</p> Signup and view all the answers

Which of the following statements about humic acid is true?

<p>It can be extracted using various reagents. (A)</p> Signup and view all the answers

What are the primary components of organic residues in soil?

<p>Undecayed plant and animal tissues and their partial decomposition products.</p> Signup and view all the answers

Nonhumic substances are exclusively made up of complex biopolymers.

<p>False (B)</p> Signup and view all the answers

Which of the following statements about thermal treatment of contaminated soil is correct?

<p>Soil is heated to break down pollutants. (C)</p> Signup and view all the answers

In land treatment, the soil pH is adjusted to 7.0 to enhance the activity of soil microbes.

<p>True (A)</p> Signup and view all the answers

What happens to contaminants in the asphalt incorporation method?

<p>They are volatilized or decomposed and immobilized in asphalt.</p> Signup and view all the answers

The method that encapsulates contaminants with additives before landfilling is known as __________.

<p>solidification/stabilization</p> Signup and view all the answers

What is the maximum number of hydrogen bonds that a water molecule can form?

<p>4 (A)</p> Signup and view all the answers

Match the soil decontamination method with its description:

<p>Land Treatment = Biodegradation in natural conditions Thermal Treatment = Heat application to break down pollutants Asphalt Incorporation = Addition of contaminated soil to asphalt mixes Solidification/Stabilization = Encapsulation of contaminants in a landfill</p> Signup and view all the answers

What is one disadvantage of thermal treatment?

<p>It is a costly method of remediation. (D)</p> Signup and view all the answers

Ice has a higher density than liquid water.

<p>False (B)</p> Signup and view all the answers

The ozone layer is essential for the sustainability of life on Earth.

<p>True (A)</p> Signup and view all the answers

What is the latent heat of vaporization for water in calories?

<p>540</p> Signup and view all the answers

The average number of nearest neighbor atoms with respect to a central atom is known as the ______.

<p>coordination number</p> Signup and view all the answers

During the formation of the atmosphere, which organisms were responsible for producing much of the first oxygen?

<p>Cyanobacteria</p> Signup and view all the answers

Which factor contributes to a decrease in vapor pressure?

<p>Addition of solutes (D)</p> Signup and view all the answers

Match each term with its definition:

<p>Latent Heat of Fusion = Energy required to convert 1 gram of ice to water at 0 °C Specific Heat = Energy required to raise the temperature of 1 g of water by 1 °C Vapor Pressure = Pressure exerted by vapor molecules in a closed container Coordination Number = Average number of nearest neighbor atoms</p> Signup and view all the answers

What charge do the hydrogen atoms in a water molecule acquire?

<p>slightly positive</p> Signup and view all the answers

Liquid water is expected to be gaseous at room temperature due to its hydrogen bonds.

<p>False (B)</p> Signup and view all the answers

What is the most abundant gas in the atmosphere?

<p>Nitrogen (D)</p> Signup and view all the answers

Oxygen is removed from the atmosphere exclusively through respiration.

<p>False (B)</p> Signup and view all the answers

What process converts atmospheric nitrogen into ammonia?

<p>Nitrogen fixation</p> Signup and view all the answers

The gas that is responsible for photosynthesis is __________.

<p>carbon dioxide</p> Signup and view all the answers

Which of the following is NOT a trace gas?

<p>Nitrogen (A)</p> Signup and view all the answers

Match the following gases with their classification:

<p>Nitrogen = Constant Gas Carbon Dioxide = Variable Gas Water Vapor = Highly Variable Gas Argon = Constant Gas</p> Signup and view all the answers

Argon is the second most abundant gas in the atmosphere.

<p>False (B)</p> Signup and view all the answers

What is one source of nitrogen returning to the atmosphere?

<p>Biomass combustion or denitrification</p> Signup and view all the answers

What is the primary chemical contributor to the alkalinity of water?

<p>Bicarbonates (C)</p> Signup and view all the answers

The hardness of water is primarily caused by monovalent metallic cations.

<p>False (B)</p> Signup and view all the answers

What is the typical pH range for bodies of water?

<p>6 to 9.5</p> Signup and view all the answers

Acidic waters are a major concern because of their __________ characteristics.

<p>corrosive</p> Signup and view all the answers

Match the following terms related to water chemistry with their characteristics:

<p>Alkalinity = Measure of the capacity to neutralize acids Acidity = Result of dissolved CO2 and industrial waste Hardness = Presence of divalent metallic cations like calcium Dissolved Oxygen = Essential for the decomposition of organic matter</p> Signup and view all the answers

Which industrial activity is most likely to contribute to increased water acidity?

<p>Metallurgical processes (B)</p> Signup and view all the answers

Soft waters originate in areas where limestone formations are prevalent.

<p>False (B)</p> Signup and view all the answers

What branch of science focuses on the chemical composition and properties of soils?

<p>Soil chemistry</p> Signup and view all the answers

Who developed the spectrophotometer and started measurements of total-column ozone in 1924?

<p>Gordon Dobson (A)</p> Signup and view all the answers

The emergence of photochemical smog was described by Arie Jan Haagen-Smit in 1960.

<p>True (A)</p> Signup and view all the answers

What significant discovery related to chlorofluorocarbons (CFCs) did James Lovelock make?

<p>He first detected chlorofluorocarbons (CFCs) in the atmosphere.</p> Signup and view all the answers

The average amount of time that a gas spends in the atmosphere is referred to as its ______.

<p>residence time</p> Signup and view all the answers

Match the scientists with their respective discoveries:

<p>Gordon Dobson = Spectrophotometer for ozone Sydney Chapman = Ozone layer theory Paul Crutzen = Nobel Prize for atmospheric chemistry James Lovelock = Detection of CFCs</p> Signup and view all the answers

Which gas is the most abundant in the atmosphere?

<p>Nitrogen (A)</p> Signup and view all the answers

Carbon dioxide is considered a constant gas in the atmosphere.

<p>False (B)</p> Signup and view all the answers

What process involves the conversion of atmospheric nitrogen into ammonia?

<p>Nitrogen fixation</p> Signup and view all the answers

The gas that plays a crucial role in photosynthesis and respiration is __________.

<p>Oxygen</p> Signup and view all the answers

What is the primary process by which nitrogen returns to the atmosphere?

<p>Denitrification (C)</p> Signup and view all the answers

Argon is the least abundant gas in the atmosphere.

<p>False (B)</p> Signup and view all the answers

Name one long-lived trace gas mentioned in the content.

<p>Methane</p> Signup and view all the answers

What is the primary reason water remains in a liquid state at room temperature despite its expected gaseous state?

<p>Formation of hydrogen bonds (C)</p> Signup and view all the answers

Ice is denser than liquid water.

<p>False (B)</p> Signup and view all the answers

What is the latent heat of fusion for water?

<p>80 calories</p> Signup and view all the answers

Water can form up to _____ hydrogen bonds.

<p>4</p> Signup and view all the answers

Which of the following factors leads to an increase in vapor pressure?

<p>High temperature (A)</p> Signup and view all the answers

The boiling point of water increases with higher vapor pressure.

<p>False (B)</p> Signup and view all the answers

What effect do impurities like salts and sugars have on the vapor pressure of water?

<p>Decrease the vapor pressure</p> Signup and view all the answers

What is a common effect of agricultural runoff on water quality?

<p>Eutrophication (C)</p> Signup and view all the answers

Sediments can positively affect the water quality by providing habitats for aquatic organisms.

<p>False (B)</p> Signup and view all the answers

What pollutant is primarily caused by sediments from agricultural land?

<p>Poor water quality</p> Signup and view all the answers

Waste from _______ is a common source of organic pollutants in water bodies.

<p>households</p> Signup and view all the answers

Match the following pollutants with their primary sources:

<p>Fertilizers = Agricultural runoff Radioactive materials = Uranium mining Heat = Cooling industrial processes Plastics = Industrial waste and household waste</p> Signup and view all the answers

Which of the following is NOT a consequence of thermal pollution?

<p>Improved water clarity (A)</p> Signup and view all the answers

Radioactive materials can cause genetic defects and cancer in living organisms.

<p>True (A)</p> Signup and view all the answers

Name one effect of pesticides as organic pollutants in water bodies.

<p>Toxic effects to aquatic life</p> Signup and view all the answers

What is the primary role of alkalinity in bodies of water?

<p>To neutralize acids (D)</p> Signup and view all the answers

The only disadvantage of hard water is that it doesn’t dissolve with soap.

<p>True (A)</p> Signup and view all the answers

What is the common source of acidity in water?

<p>Carbon dioxide</p> Signup and view all the answers

___ are the principal hardness causing cations in water.

<p>Calcium and magnesium</p> Signup and view all the answers

Match the term with its description:

<p>Alkalinity = Capacity to neutralize acids Acidity = Presence of dissolved CO2 Hardness = Caused by divalent metallic cations Soil Chemistry = Study of soil composition and properties</p> Signup and view all the answers

Which substance is most significantly responsible for the alkalinity of water?

<p>Bicarbonates (D)</p> Signup and view all the answers

What is environmental soil chemistry concerned with?

<p>Impact of contaminants on health</p> Signup and view all the answers

Soft waters originate in areas with thick top soil and limestone formations.

<p>False (B)</p> Signup and view all the answers

What phenomenon occurs due to a significant temperature difference between layers of a body of water?

<p>Thermal stratification (C)</p> Signup and view all the answers

The hypolimnion layer of a body of water contains higher levels of dissolved oxygen compared to the epilimnion layer.

<p>False (B)</p> Signup and view all the answers

What is the layer between the epilimnion and hypolimnion called?

<p>thermocline</p> Signup and view all the answers

Cold water can dissolve more __________ than warm water.

<p>oxygen</p> Signup and view all the answers

Match the following water layers with their characteristics:

<p>Epilimnion = Warm layer exposed to sunlight Hypolimnion = Cold and dense layer at the bottom Thermocline = Zone of rapid temperature change</p> Signup and view all the answers

What effect does an increase in water temperature have on aquatic organisms?

<p>Increases metabolic rates (C)</p> Signup and view all the answers

Thermal pollution occurs when cooler water enters a stream and raises the overall temperature of the body of water.

<p>False (B)</p> Signup and view all the answers

Which aquatic organisms rely heavily on dissolved oxygen for survival?

<p>fish and invertebrates</p> Signup and view all the answers

Flashcards

Photosynthesis

The process used by cyanobacteria to create energy and release oxygen as a byproduct

Cyanobacteria

Early organisms that were the first to perform photosynthesis and release oxygen.

Ozone Layer Formation

Oxygen molecules in the atmosphere absorb UV radiation and form ozone.

Atmospheric Chemistry

The study of the gases surrounding Earth and their interactions

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Early Oxygen Use

Early oxygen was used to oxidize metals.

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Atmospheric Oxygen Increase

Oxygen levels in the atmosphere increased due to photosynthesis and oxidation of materials.

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Karman Line

Boundary between atmosphere and outer space.

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Atmospheric Composition

Mixture of gases surrounding Earth, held by gravity.

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Cohesion of water

The attraction between water molecules due to hydrogen bonds, creating surface tension and important for water transport in plants.

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High Specific Heat Capacity of Water

Water needs a lot of energy to change its temperature, making it good for regulating temperature and heat transfer.

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Water Expansion on Freezing

Water expands when it freezes, unlike most substances, which makes ice less dense than liquid water.

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Surface Water

Precipitation that flows over the land surface, forming streams and rivers.

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Ground Water

Precipitation that seeps into the ground, filling spaces between soil and rock.

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Osmosis

The movement of water across a semipermeable membrane from a high water concentration to a low water concentration.

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Capillary Action

The ability of water to flow in narrow spaces against gravity.

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Water Cycle

The continuous movement of water between the Earth's surface and the atmosphere, involving evaporation, condensation, and precipitation.

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Aquifer

Layers of soil and rocks that hold or bear water.

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Water Pollution

The contamination of water by harmful substances.

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Point Source Pollution

Pollution from a specific, identifiable source, like a factory.

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Non-Point Source Pollution

Pollution from a diffuse source that doesn't have a clear origin, like runoff from a farm.

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Siltation

The build-up of silt and sediment in a body of water, usually from erosion.

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Anthropogenic Pollution

Pollution caused by human activities.

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Groundwater Pollution

Contamination of groundwater aquifers by pollutants.

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High Water Table

A situation where groundwater is relatively close to the surface of the Earth.

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Groundwater Movement

The flow of water underground, often over long distances due to the vast spaces beneath the Earth's surface.

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Tracing Groundwater Pollution

The challenge of identifying the source of impurities in groundwater, often difficult because it moves over vast distances.

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Oxidation of Pollutants

The process of breaking down pollutants into harmless substances using oxygen.

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Thermal Stratification

The formation of distinct layers within a body of water, caused by temperature differences.

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Epilimnion

The warm, top layer of a stratified body of water.

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Hypolimnion

The cold, bottom layer of a stratified body of water.

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Soil Organic Matter (SOM)

A complex mixture of partially decomposed plant and animal residues, microbial byproducts, and living/dead microorganisms. It's the organic component of soil.

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Humus

Stable, decomposed organic matter in soil, rich in nutrients and improves soil structure.

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What are the general properties of SOM?

SOM influences soil structure, water retention, nutrient availability, and microbial activity.

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In situ Soil Decontamination

Cleaning up contaminated soil without removing it from the site. It reduces disturbance and exposure to pollutants.

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Volatilization

Removing volatile compounds from contaminated soil by drawing air through it.

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Biodegradation

Using microorganisms to break down pollutants in soil.

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Phytoremediation

Using plants to remove pollutants from soil.

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Non-in-situ Soil Decontamination

Cleaning up contaminated soil by removing it from the site and treating it elsewhere.

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Dissolved Oxygen (DO)

The amount of oxygen gas present in water, crucial for the survival of aquatic organisms.

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Alkalinity

A measure of a body of water's ability to neutralize acids, primarily due to bicarbonates and other salts of weak and strong acids.

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CO2 Acidity

Acidity in water caused by the dissolution of carbon dioxide, a common source of acidity.

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Metabolic Rates

The speed at which an organism's chemical reactions occur, influenced by factors like temperature.

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Thermal Pollution

The discharge of heated water into a body of water, causing a rise in temperature that can harm aquatic life.

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Primitive Atmosphere

The Earth's first atmosphere, formed from hydrogen and helium, similar to the atmospheres of Jupiter and Saturn today.

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Secondary Atmosphere

The second atmosphere of Earth, formed from volcanic activity, composed mainly of water vapor, carbon dioxide, and ammonia, similar to the atmospheres of Mars and Venus today.

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Oxidizing Atmosphere

The current atmosphere of Earth, rich in oxygen, formed through the photochemical dissociation of water vapor by strong ultraviolet radiation.

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Reducing Atmosphere

An atmosphere lacking free oxygen, with a high concentration of reducing agents like methane and ammonia.

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Photochemical Dissociation

The breaking down of molecules by light, especially ultraviolet radiation.

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How did the early atmosphere disappear?

The early atmosphere, composed of hydrogen and helium, was blown away by strong solar winds because the young Earth lacked a magnetic field.

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What is the significance of oxygen in the atmosphere?

Oxygen is essential for life as we know it, and it plays a critical role in processes like respiration and the formation of the ozone layer.

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Why is the Earth's current atmosphere considered oxidizing?

The presence of free oxygen in the atmosphere allows for the oxidation of materials, leading to rusting and combustion, processes that require oxygen.

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Major Components

Gases that make up the largest proportion of the atmosphere, like nitrogen and oxygen.

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Trace Gases

Gases present in tiny amounts in the atmosphere, like carbon dioxide and methane.

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Constant Gases

Gases with relatively stable concentrations in the atmosphere over time, like nitrogen and argon.

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Variable Gases

Gases whose concentrations change over time, like carbon dioxide, which fluctuates due to human activities.

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Highly Variable Gases

Gases with concentrations that change dramatically over short periods, like water vapor, influenced by weather patterns.

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Nitrogen Fixation

The process of converting atmospheric nitrogen gas (N2) into usable forms for living organisms.

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Denitrification

The process of converting nitrates back into nitrogen gas, returning it to the atmosphere.

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Argon's Origin

Most atmospheric argon comes from the decay of potassium in the Earth's crust.

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Cyanobacteria and Photosynthesis

Cyanobacteria were the first organisms to perform photosynthesis, releasing oxygen as a byproduct. This process involves using sunlight, water, and carbon dioxide to produce energy and oxygen.

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Water's Cohesion

Water molecules stick together due to hydrogen bonds, creating surface tension and aiding water transport in plants.

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Water's High Specific Heat

Water requires a large amount of energy to change temperature, making it a good heat regulator.

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Early Earth's Atmosphere

The early Earth atmosphere was primarily composed of gases like methane, ammonia, carbon dioxide, and water vapor. It lacked free oxygen.

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Iron Oxidation

Early oxygen released by cyanobacteria reacted with dissolved iron in the oceans, leading to the formation of iron oxides and rust. This process removed oxygen from the atmosphere, temporarily.

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Water's Expansion Upon Freezing

Water expands upon freezing, unlike most substances, which makes ice less dense than liquid water.

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Life's Sustainability

The formation of the ozone layer was crucial for the development and sustainability of life on Earth. It shielded life from harmful UV radiation, allowing life to evolve and thrive.

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Atmospheric Oxygen Levels

Over time, oxygen levels in the atmosphere stabilized due to a balance between plant production (photosynthesis) and animal consumption (respiration).

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Point sources of pollution

Pollutants directly released into water from specific locations, like factories or sewage pipes.

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Non-point sources of pollution

Pollutants indirectly affecting water through widespread environmental changes, like runoff from farms.

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Natural sources of pollution

Pollution from naturally occurring substances, like silt from erosion.

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Anthropogenic sources of pollution

Pollution caused by human activities, like sewage or industrial waste.

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What makes ground water pollution difficult to treat?

Contaminated water can seep deep underground and travel long distances, making it hard to identify and clean.

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Leaching

A soil decontamination method using water and a surfactant to remove contaminants. The contaminated water (leachate) is collected for treatment or disposal.

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Land Treatment

Contaminated soil is spread over land for natural processes like biodegradation to clean it. The soil pH is adjusted for better microbial action.

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Thermal Treatment

Excavated soil is heated intensely, breaking down pollutants. The released volatile compounds are collected and treated.

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Asphalt Incorporation

Contaminated soil is mixed with hot asphalt for road paving. The heating process helps remove some pollutants, but heavier compounds may remain.

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Solidification/Stabilization

An additive is mixed with contaminated soil to encapsulate contaminants. The mixture is landfilled, making contaminants immobile.

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Cyanobacteria's Role

Cyanobacteria were the first organisms to perform photosynthesis, releasing oxygen as a byproduct, paving the way for the oxygen-rich atmosphere we have today.

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What are the main components of the atmosphere?

The main components of the atmosphere are nitrogen (78.08%), oxygen (20.95%), and argon (0.934%).

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What are trace gases?

Trace gases are gases that make up a very small percentage of the atmosphere, like carbon dioxide and methane.

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What are variable gases?

Variable gases are those whose concentrations change over time, such as carbon dioxide, which fluctuates due to human activities.

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Nitrogen's Importance

Nitrogen is an essential element for living organisms, and it is cycled through the atmosphere, soil, and living things.

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Oxygen's Role

Oxygen is important for respiration, the process by which living organisms use it to generate energy.

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What is the nitrogen cycle?

The nitrogen cycle is the process by which nitrogen is converted between different forms and cycled through the atmosphere, soil, and organisms.

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What is denitrification?

Denitrification is the process by which bacteria convert nitrates back into nitrogen gas, returning it to the atmosphere.

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What is argon?

Argon is the third most abundant gas in the atmosphere, and it is mainly a result of the decay of potassium in the Earth's crust.

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Hydrogen Bond

A weak bond between polar compounds where a hydrogen atom of one molecule is attracted to an electronegative atom of another molecule.

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Coordination Number

The average number of nearest neighbor atoms surrounding a central atom.

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Specific Heat

The amount of heat required to raise the temperature of 1 gram of a substance by 1 degree Celsius.

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Latent Heat of Fusion

The energy needed to melt 1 gram of a solid into a liquid at its melting point.

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Latent Heat of Vaporization

The energy required to convert 1 gram of a liquid into a gas at its boiling point.

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Vapor Pressure

The pressure exerted by the vapor molecules of a liquid in a closed system.

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Boiling Point

The temperature at which the vapor pressure of a liquid equals the surrounding atmospheric pressure.

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Factors Affecting Vapor Pressure

Temperature and impurities affect vapor pressure. Higher temperatures lead to increased vapor pressure, while impurities decrease it.

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What are the main types of organic matter in soil?

Soil organic matter consists of organic residues, soil biomass, humic substances, and nonhumic substances.

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Humic Substances

A complex mixture of high-molecular-weight, brown-to-black substances formed through secondary synthesis reactions. They are not like the biopolymers of microbes or plants.

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Nonhumic Substances

Compounds belonging to known biochemical classes like amino acids, carbohydrates, fats, waxes, resins, and organic acids.

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Fulvic Acid

The colored material remaining in solution after removing humic acid by acidification.

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How does SOM affect soil?

SOM influences soil structure, water retention, nutrient availability, and microbial activity.

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What is dissolved oxygen's role in water?

Dissolved oxygen (DO) is essential for the survival of aquatic organisms and the decomposition of organic matter. It is dissolved into water from the atmosphere.

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What is alkalinity?

Alkalinity is a measure of water's capacity to neutralize acids. It's primarily due to the presence of bicarbonates and other salts of weak acids, which act as buffers to resist pH changes.

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What is CO2 acidity?

CO2 acidity is caused by dissolved carbon dioxide in water, contributing to the overall acidity of the water body. Industry waste and natural processes like respiration can increase CO2 levels and acidity.

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What causes water hardness?

Water hardness is mainly caused by the presence of divalent metallic cations like calcium and magnesium. Hard water originates in areas with limestone formations, while soft water is from areas lacking limestone.

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What is soil chemistry?

Soil chemistry is the branch of science that studies the chemical composition, properties, and reactions occurring in soil. It focuses on how these processes affect plant growth, nutrition, and environmental health.

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What is environmental soil chemistry?

Environmental soil chemistry is a branch of soil chemistry that focuses on the impacts of contaminants in soil and water on plant, animal, and human health. It deals with pollution and its effects on the environment.

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What are the disadvantages of acidic water?

Acidic waters are corrosive, meaning they can damage pipes and infrastructure. Acidic waters can also harm aquatic life and affect plant growth.

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What is the pH range for most bodies of water?

The pH level of most bodies of water is usually maintained between 6 and 9.5. This range is optimal for most aquatic life and prevents extreme acidity or alkalinity.

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What is the significance of the ozone layer?

The ozone layer protects life on Earth by absorbing harmful ultraviolet radiation from the sun.

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Spectrophotometer

A device used to measure the amount of light absorbed or transmitted by a substance, which can be used to analyze atmospheric gases.

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Ozone Layer

A region in the stratosphere with a high concentration of ozone, which absorbs harmful ultraviolet radiation from the sun.

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Photochemical Smog

A type of air pollution formed by the reaction of sunlight with pollutants like nitrogen oxides and volatile organic compounds.

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CFCs

Chlorofluorocarbons, a group of synthetic compounds that were once widely used in refrigerants and aerosols but are now banned because they deplete the ozone layer.

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Residence Time

The average amount of time that a gas spends in the atmosphere, influenced by factors like how quickly it reacts or breaks down.

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What is the importance of nitrogen in the atmosphere?

Nitrogen is essential for life as we know it. It's a key component of DNA , RNA and proteins, and the nitrogen cycle ensures its availability for organisms.

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What is the role of oxygen in the atmosphere?

Oxygen is essential for breathing and respiration in many organisms. It also plays a key role in processes like photosynthesis and the formation of the ozone layer.

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Organic Pollutants

Pollutants derived from living organisms or their byproducts, often persistent and harmful to the environment and human health.

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Inorganic Pollutants

Pollutants that are not derived from living organisms, often mineral-based and can have severe consequences for aquatic ecosystems.

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Eutrophication

Excessive nutrient enrichment in a body of water, often caused by runoff from agricultural fertilizers, leading to algal blooms and oxygen depletion.

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Thermocline

The transition zone between the epilimnion and hypolimnion, where temperature rapidly changes.

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How does temperature affect dissolved oxygen in water?

Cold water can hold more dissolved oxygen than warm water. As water temperature increases, the ability of water to hold oxygen decreases.

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What is thermal pollution?

The release of heated water into a body of water, causing a rise in temperature that can harm aquatic life.

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What is DO?

Dissolved oxygen (DO) is the amount of oxygen gas present in water, crucial for the survival of aquatic organisms.

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How does DO affect aquatic life?

Low levels of dissolved oxygen can lead to fish kills. Most aquatic organisms need dissolved oxygen to survive.

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Water Hardness

Caused by divalent metallic cations like calcium and magnesium, making water less effective with soap.

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Soil Chemistry

The study of the chemical composition, properties, and reactions of soil. It impacts plant growth and environmental health.

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What causes acidity in water bodies?

The most common source of acidity is dissolved carbon dioxide. Industrial wastes, particularly from metallurgy and synthetic organic material production, can also contribute.

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Why is acidity in water a concern?

Acidic water can be corrosive, damaging infrastructure and harming aquatic life.

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Study Notes

Introduction to Chemistry of the Environment

  • Our environment is complex and includes air, land, water, and climate
  • Chemistry is important for understanding, monitoring, protecting, and improving the environment
  • Chemists develop tools to measure and monitor pollutants
  • Chemistry helps track how climate has changed over time

Chemistry of the Atmosphere

A. Formation of the Atmosphere

  • Early Earth was a hot molten rock
  • Primitive atmosphere was primarily hydrogen and helium, plus ammonia and methane
  • Strong solar winds from the sun blew away the early atmosphere
  • Secondary atmosphere formed as the Earth cooled, with volcanoes releasing gases (primarily water vapor, carbon dioxide, and ammonia)
  • Water vapor condensed to form clouds and oceans, absorbing carbon dioxide
  • Other gases formed from the breakdown of other molecules (e.g., nitrogen from ammonia)

B. Secondary Atmosphere

  • Volcanic activity released gases from the Earth's interior
  • The gases (water vapor, carbon dioxide, and ammonia) formed the reducing atmosphere
  • Similar to the atmospheres of Mars and Venus
  • Cooling atmosphere resulted in water vapor condensation and cloud formation, and ocean creation
  • Oceans absorb carbon dioxide

C. Oxidizing Atmosphere

  • Photochemical dissociation of water vapor by UV radiation created oxygen
  • Minimal oxygen was produced through this process
  • Photosynthesis by cyanobacteria released significant oxygen into the atmosphere

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Explore the fundamental concepts of environmental chemistry, including the formation and composition of the atmosphere. This quiz will test your understanding of how chemistry plays a critical role in monitoring and improving our environment. Get ready to dive into the intricate connections between chemistry and Earth's climate.

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