Intermolecular Forces of Attraction (IMFA)

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Questions and Answers

London dispersion forces (LDFs) are one of the common intermolecular forces of attraction. Which of the following is NOT a characteristic of London dispersion forces?

  • They are stronger than polar molecules (correct)
  • They are present in all molecules.
  • They result from temporary dipoles.
  • They increase with molecular size.

LDF's are the weakest intermolecular force. What is the fundamental cause of LDFs?

  • Polar and ion interactions
  • Presence of permanent dipoles
  • Temporary fluctuations in electron distribution (correct)
  • Covalent bond formation

Dipole-dipole forces influence the physical properties of substances such a boiling point. How do dipole-dipole forces affect the boiling point of a substance?

  • They only affect melting point.
  • They decrease the boiling point.
  • They increase the boiling point. (correct)
  • They have no effect on the boiling point.

Dipole-dipole forces occur between certain polar molecules. Which of the following molecules exhibits dipole-dipole forces?

<p>HCL (C)</p> Signup and view all the answers

Dipole-dipole forces are stronger than LDFs in polar molecules. What is the primary difference in the forces between HCl and Cl2?

<p>HCl has dipole-dipole, Cl2 has LDFs. (B)</p> Signup and view all the answers

Which of the following statements about dipole-dipole forces is true?

<p>They occur between molecules with permanent dipoles. (B)</p> Signup and view all the answers

What makes hydrogen bonding a particularly strong dipole dipole force?

<p>The high electronegativity of N, O, or F (A)</p> Signup and view all the answers

A salt crystal dissolves in water. What is the primary intermolecular force involved in this process?

<p>Ion-dipole forces between the ions and water molecules. (A)</p> Signup and view all the answers

Ion-dipole forces are stronger than dipole-dipole forces. Which of the following pairs of molecules have the strongest ion-dipole forces?

<p>Na+ and H2O (B)</p> Signup and view all the answers

Ion-dipole forces are strongest when ions are highly charged. Which would create the stronger ion-dipole interaction with water: Na+ or Al3+?

<p>Al3+ (B)</p> Signup and view all the answers

When comparing the boiling points of hydrogen chloride (HCl) and hydrogen fluoride (HF), which factor contributes to HF having a higher boiling point?

<p>Hydrogen bonding (B)</p> Signup and view all the answers

A solution of potassium iodide (KI) in water is prepared. What intermolecular force is responsible for the dissolution of KI in water?

<p>Ion-dipole forces (D)</p> Signup and view all the answers

Which of the following correctly ranks the intermolecular forces from weakest to strongest?

<p>London dispersion forces &lt; dipole-dipole forces &lt; hydrogen bonding &lt; ion-dipole forces (D)</p> Signup and view all the answers

What type of intermolecular force is primarily responsible for the properties of liquid ammonia (NH3)?

<p>Hydrogen bonding (D)</p> Signup and view all the answers

Hydrogen bonding is particularly strong in which of the following compounds?

<p>H2O (A)</p> Signup and view all the answers

Intermolecular forces are attractive forces present in between molecules. The first two are collectively known as _____ forces of attraction, named after the Dutch scientist Johannes Van der Waals

<p>van der Waals</p> Signup and view all the answers

_____ forces are the weakest type of IMFA and are present in between all electrically neutral molecules - polar and nonpolar molecules. This IMFA was named after the German American physicist Fritz London who proposed the origin of this intermolecular attractions.

<p>London dispersion</p> Signup and view all the answers

When more _____ are present in a molecule, the stronger the LDFs are. This is because larger molecules are more polarized.

<p>electrons</p> Signup and view all the answers

_____ is the measure of how easy it is to distort the electron distribution of a molecule. In large molecules, the electrons are less tightly held by the attraction with the nucleus so they can form temporary dipoles easier.

<p>Polarizability</p> Signup and view all the answers

LDFs are caused by _____ in the electron distribution within atoms or molecules. This happens when an atom, which is usually non-polar, becomes polar due to the continual motion of its electrons resulting in a _____ dipole. The temporary dipole of a molecule induces instantaneous dipoles to neighboring molecules.

<p>fluctuations, temporary</p> Signup and view all the answers

Flashcards

Intermolecular forces

Attractive forces present between molecules.

London Dispersion Forces (LDF)

The weakest type of intermolecular force.

Johannes van der Waals

Dutch scientist that Van der Waals forces were named after.

Fritz London

American physicist who proposed the origin of London dispersion forces.

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Polarizability

The measure of how easily the electron distribution of a molecule can be distorted.

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London dispersion forces

Caused by fluctuations in the electron distribution within atoms or molecules.

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van der Waals forces

The first two intermolecular forces collectively known as...

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Electrons

When more of these are present in a molecule, the stronger the LDFs are.

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Dipole-dipole forces

Forces between molecules with permanent dipoles.

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Dipole-dipole forces

Exhibited by HCl.

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Study Notes

Intermolecular Forces of Attraction (IMFA)

  • Intermolecular forces are attractive forces found between molecules.
  • Van der Waals forces collectively describe the first two types of intermolecular forces.
  • Johannes van der Waals was a Dutch scientist, the forces are named after him.
  • London dispersion forces (LDFs) are considered the weakest type of IMFA
  • London dispersion forces are present in all electrically neutral molecules, whether polar or nonpolar.
  • Fritz London, a German American physicist, is the namesake of this IMFA, who proposed its origin.
  • LDFs increase in strength when more electrons are present in a molecule.
  • Larger molecules are more easily polarized.
  • Polarizability measures how easy it is to distort a molecule's electron distribution.
  • Electrons in larger molecules are less tightly held by the nucleus, facilitating the formation of temporary dipoles.
  • Fluctuations in electron distribution within atoms or molecules cause LDFs.
  • Atoms that are usually non-polar can become polar due to the constant movement of their electrons and result in a temporary dipole.
  • A temporary dipole in one molecule can induce instantaneous dipoles in neighboring molecules.

Types of Intermolecular Forces

  • London dispersion forces (LDFs) increase with molecular size, are present in all molecules, and result from temporary dipoles.
  • Dipole-dipole forces affect a substance's boiling point.
  • Dipole-dipole forces occur between polar molecules.
  • Dipole-dipole forces are stronger than LDFs in polar molecules.
  • The primary difference between HCl and Clâ‚‚ is that HCl has dipole-dipole forces, while Clâ‚‚ has LDFs.
  • Dipole-dipole forces occur between molecules with permanent dipoles.

Hydrogen Bonding

  • High electronegativity of nitrogen, oxygen, or fluorine contributes to particularly strong dipole-dipole force.
  • Hydrogen bonding is primarily responsible for the properties of liquid ammonia (NH3)
  • Hydrogen bonding is particularly strong in Hâ‚‚O (water).

Ion-Dipole Forces

  • Ion-dipole forces are involved when a salt crystal dissolves in water.
  • Ion-dipole forces are stronger than dipole-dipole forces.
  • The strongest ion-dipole forces occur between Na+ and Hâ‚‚O.
  • Higher charge creates stronger ion-dipole interaction between water and A13+.

Intermolecular Forces Ranking

  • The correct ranking of intermolecular forces from weakest to strongest is: London dispersion forces < dipole-dipole forces < hydrogen bonding < ion-dipole forces.

Boiling Points

  • Hydrogen bonding contributes to hydrogen fluoride (HF) having a higher boiling point compared to hydrogen chloride (HCl).

Dissolution

  • Ion-dipole forces are responsible for the dissolution of potassium iodide (KI) in water.

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