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Questions and Answers
London dispersion forces (LDFs) are one of the common intermolecular forces of attraction. Which of the following is NOT a characteristic of London dispersion forces?
London dispersion forces (LDFs) are one of the common intermolecular forces of attraction. Which of the following is NOT a characteristic of London dispersion forces?
- They are stronger than polar molecules (correct)
- They are present in all molecules.
- They result from temporary dipoles.
- They increase with molecular size.
LDF's are the weakest intermolecular force. What is the fundamental cause of LDFs?
LDF's are the weakest intermolecular force. What is the fundamental cause of LDFs?
- Polar and ion interactions
- Presence of permanent dipoles
- Temporary fluctuations in electron distribution (correct)
- Covalent bond formation
Dipole-dipole forces influence the physical properties of substances such a boiling point. How do dipole-dipole forces affect the boiling point of a substance?
Dipole-dipole forces influence the physical properties of substances such a boiling point. How do dipole-dipole forces affect the boiling point of a substance?
- They only affect melting point.
- They decrease the boiling point.
- They increase the boiling point. (correct)
- They have no effect on the boiling point.
Dipole-dipole forces occur between certain polar molecules. Which of the following molecules exhibits dipole-dipole forces?
Dipole-dipole forces occur between certain polar molecules. Which of the following molecules exhibits dipole-dipole forces?
Dipole-dipole forces are stronger than LDFs in polar molecules. What is the primary difference in the forces between HCl and Cl2?
Dipole-dipole forces are stronger than LDFs in polar molecules. What is the primary difference in the forces between HCl and Cl2?
Which of the following statements about dipole-dipole forces is true?
Which of the following statements about dipole-dipole forces is true?
What makes hydrogen bonding a particularly strong dipole dipole force?
What makes hydrogen bonding a particularly strong dipole dipole force?
A salt crystal dissolves in water. What is the primary intermolecular force involved in this process?
A salt crystal dissolves in water. What is the primary intermolecular force involved in this process?
Ion-dipole forces are stronger than dipole-dipole forces. Which of the following pairs of molecules have the strongest ion-dipole forces?
Ion-dipole forces are stronger than dipole-dipole forces. Which of the following pairs of molecules have the strongest ion-dipole forces?
Ion-dipole forces are strongest when ions are highly charged. Which would create the stronger ion-dipole interaction with water: Na+ or Al3+?
Ion-dipole forces are strongest when ions are highly charged. Which would create the stronger ion-dipole interaction with water: Na+ or Al3+?
When comparing the boiling points of hydrogen chloride (HCl) and hydrogen fluoride (HF), which factor contributes to HF having a higher boiling point?
When comparing the boiling points of hydrogen chloride (HCl) and hydrogen fluoride (HF), which factor contributes to HF having a higher boiling point?
A solution of potassium iodide (KI) in water is prepared. What intermolecular force is responsible for the dissolution of KI in water?
A solution of potassium iodide (KI) in water is prepared. What intermolecular force is responsible for the dissolution of KI in water?
Which of the following correctly ranks the intermolecular forces from weakest to strongest?
Which of the following correctly ranks the intermolecular forces from weakest to strongest?
What type of intermolecular force is primarily responsible for the properties of liquid ammonia (NH3)?
What type of intermolecular force is primarily responsible for the properties of liquid ammonia (NH3)?
Hydrogen bonding is particularly strong in which of the following compounds?
Hydrogen bonding is particularly strong in which of the following compounds?
Intermolecular forces are attractive forces present in between molecules. The first two are collectively known as _____ forces of attraction, named after the Dutch scientist Johannes Van der Waals
Intermolecular forces are attractive forces present in between molecules. The first two are collectively known as _____ forces of attraction, named after the Dutch scientist Johannes Van der Waals
_____ forces are the weakest type of IMFA and are present in between all electrically neutral molecules - polar and nonpolar molecules. This IMFA was named after the German American physicist Fritz London who proposed the origin of this intermolecular attractions.
_____ forces are the weakest type of IMFA and are present in between all electrically neutral molecules - polar and nonpolar molecules. This IMFA was named after the German American physicist Fritz London who proposed the origin of this intermolecular attractions.
When more _____ are present in a molecule, the stronger the LDFs are. This is because larger molecules are more polarized.
When more _____ are present in a molecule, the stronger the LDFs are. This is because larger molecules are more polarized.
_____ is the measure of how easy it is to distort the electron distribution of a molecule. In large molecules, the electrons are less tightly held by the attraction with the nucleus so they can form temporary dipoles easier.
_____ is the measure of how easy it is to distort the electron distribution of a molecule. In large molecules, the electrons are less tightly held by the attraction with the nucleus so they can form temporary dipoles easier.
LDFs are caused by _____ in the electron distribution within atoms or molecules. This happens when an atom, which is usually non-polar, becomes polar due to the continual motion of its electrons resulting in a _____ dipole. The temporary dipole of a molecule induces instantaneous dipoles to neighboring molecules.
LDFs are caused by _____ in the electron distribution within atoms or molecules. This happens when an atom, which is usually non-polar, becomes polar due to the continual motion of its electrons resulting in a _____ dipole. The temporary dipole of a molecule induces instantaneous dipoles to neighboring molecules.
Flashcards
Intermolecular forces
Intermolecular forces
Attractive forces present between molecules.
London Dispersion Forces (LDF)
London Dispersion Forces (LDF)
The weakest type of intermolecular force.
Johannes van der Waals
Johannes van der Waals
Dutch scientist that Van der Waals forces were named after.
Fritz London
Fritz London
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Polarizability
Polarizability
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London dispersion forces
London dispersion forces
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van der Waals forces
van der Waals forces
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Electrons
Electrons
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Dipole-dipole forces
Dipole-dipole forces
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Dipole-dipole forces
Dipole-dipole forces
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Study Notes
Intermolecular Forces of Attraction (IMFA)
- Intermolecular forces are attractive forces found between molecules.
- Van der Waals forces collectively describe the first two types of intermolecular forces.
- Johannes van der Waals was a Dutch scientist, the forces are named after him.
- London dispersion forces (LDFs) are considered the weakest type of IMFA
- London dispersion forces are present in all electrically neutral molecules, whether polar or nonpolar.
- Fritz London, a German American physicist, is the namesake of this IMFA, who proposed its origin.
- LDFs increase in strength when more electrons are present in a molecule.
- Larger molecules are more easily polarized.
- Polarizability measures how easy it is to distort a molecule's electron distribution.
- Electrons in larger molecules are less tightly held by the nucleus, facilitating the formation of temporary dipoles.
- Fluctuations in electron distribution within atoms or molecules cause LDFs.
- Atoms that are usually non-polar can become polar due to the constant movement of their electrons and result in a temporary dipole.
- A temporary dipole in one molecule can induce instantaneous dipoles in neighboring molecules.
Types of Intermolecular Forces
- London dispersion forces (LDFs) increase with molecular size, are present in all molecules, and result from temporary dipoles.
- Dipole-dipole forces affect a substance's boiling point.
- Dipole-dipole forces occur between polar molecules.
- Dipole-dipole forces are stronger than LDFs in polar molecules.
- The primary difference between HCl and Clâ‚‚ is that HCl has dipole-dipole forces, while Clâ‚‚ has LDFs.
- Dipole-dipole forces occur between molecules with permanent dipoles.
Hydrogen Bonding
- High electronegativity of nitrogen, oxygen, or fluorine contributes to particularly strong dipole-dipole force.
- Hydrogen bonding is primarily responsible for the properties of liquid ammonia (NH3)
- Hydrogen bonding is particularly strong in Hâ‚‚O (water).
Ion-Dipole Forces
- Ion-dipole forces are involved when a salt crystal dissolves in water.
- Ion-dipole forces are stronger than dipole-dipole forces.
- The strongest ion-dipole forces occur between Na+ and Hâ‚‚O.
- Higher charge creates stronger ion-dipole interaction between water and A13+.
Intermolecular Forces Ranking
- The correct ranking of intermolecular forces from weakest to strongest is: London dispersion forces < dipole-dipole forces < hydrogen bonding < ion-dipole forces.
Boiling Points
- Hydrogen bonding contributes to hydrogen fluoride (HF) having a higher boiling point compared to hydrogen chloride (HCl).
Dissolution
- Ion-dipole forces are responsible for the dissolution of potassium iodide (KI) in water.
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