Van der Waals Forces Quiz

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Questions and Answers

What is a characteristic property of crystalline materials?

  • Brittleness
  • Amorphous structure
  • Long-range atomic order (correct)
  • Optical transparency

What type of bonding is described as temporary and fluctuating with time?

  • Metallic bonding
  • Van der Waals bonding (correct)
  • Ionic bonding
  • Covalent bonding

Which type of materials lack a crystalline structure?

  • Polycrystalline materials
  • Metallic materials
  • Non-crystalline materials
  • Amorphous materials (correct)

Which term describes molecules that have a permanent dipole moment?

<p>Polar molecules (D)</p> Signup and view all the answers

What model illustrates atoms as spheres touching each other at their closest points?

<p>Atomic Hard-Sphere Model (C)</p> Signup and view all the answers

On a bonding tetrahedron, what is located at each vertex to represent the four bonding types?

<p>Van der Waals bond (B)</p> Signup and view all the answers

Which crystal structure has atoms located at each of the cube's corners and center of its faces?

<p>Face-Centered Cubic (FCC) (C)</p> Signup and view all the answers

What term is used for atomic bonds that are mixtures of two or more extreme types of bonds?

<p>Mixed bonds (D)</p> Signup and view all the answers

What is the term used to represent small repeat entities in crystal structures?

<p>Unit cells (B)</p> Signup and view all the answers

What is the coordination number for face-centered cubic crystal structures?

<p>8 (B)</p> Signup and view all the answers

Which material class is associated with metallic bonding?

<p>Metals (D)</p> Signup and view all the answers

What type of bonding is found in molecular solids?

<p>Van der Waals bonding (C)</p> Signup and view all the answers

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Study Notes

Crystal Structure and Properties

  • Crystal structure affects material properties, such as brittleness (e.g., magnesium and beryllium) vs. ductility (e.g., gold and silver)
  • Noncrystalline materials (e.g., ceramics and polymers) are often optically transparent, whereas crystalline forms are opaque or translucent

Crystalline and Non-Crystalline Materials

  • Crystalline materials have long-range atomic order, with atoms arranged in a repetitive three-dimensional pattern
  • Non-crystalline materials lack long-range atomic order and exhibit no crystalline structure

Polycrystalline Materials

  • Exhibit long-range order due to the formation of multiple small crystalline regions or grains, each with its own crystallographic orientation

Atomic Hard-Sphere Model

  • Represents atoms as spheres that touch each other at their closest points, illustrating nearest-neighbor interactions

Lattice and Unit Cells

  • Lattice refers to a three-dimensional array of points coinciding with atom positions (or sphere centers)
  • Unit cells are small repeat entities that make up the crystal structure, often subdivided for convenience

Face-Centered Cubic (FCC) Crystal Structure

  • Common crystal structure found in many metals, characterized by a cubic unit cell with atoms at corners and face centers
  • Important characteristics include coordination number and atomic packing factor (APF)

Bonding Types

  • Ionic, covalent, metallic, and van der Waals bonding types exist, and many real materials exhibit mixed bonding
  • Bonding tetrahedron represents these bonding types, with mixed-bond types on the edges
  • Correlations exist between bonding type and material class (e.g., polymers: covalent, metals: metallic, ceramics: ionic/mixed ionic-covalent)

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