Free Energy Change (ΔG) and Reaction Direction Prediction

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

According to the first law of thermodynamics, what is true about the total energy of a system?

  • The total energy of a system, including its surroundings, remains constant. (correct)
  • The total energy of a system can be created or destroyed during a change.
  • The total energy of a system is constantly decreasing.
  • The total energy of a system is constantly increasing.

What does the second law of thermodynamics state about the entropy of a system?

  • The entropy of a system has no bearing on whether a process will occur spontaneously.
  • The entropy of a system must always remain constant for a process to occur spontaneously.
  • The entropy of a system must always decrease for a process to occur spontaneously.
  • The entropy of a system must always increase for a process to occur spontaneously. (correct)

Which of the following best describes the relationship between Gibbs free energy change (ΔG) and the changes in enthalpy (ΔH) and entropy (ΔS) during a chemical reaction?

  • ΔG = ΔH + TΔS
  • ΔG = ΔH - TΔS (correct)
  • ΔG = ΔH * TΔS
  • ΔG = ΔH / TΔS

Which of the following statements about the Gibbs free energy change (ΔG) is correct?

<p>A negative ΔG indicates that the reaction is spontaneous and releases energy. (D)</p> Signup and view all the answers

Which of the following statements about the relationship between ΔG, ΔH, and ΔS is correct?

<p>A reaction with a negative ΔH and positive ΔS will have a negative ΔG. (D)</p> Signup and view all the answers

Which of the following statements about the relationship between Gibbs free energy (G) and the spontaneity of a reaction is correct?

<p>A reaction with a negative ΔG is spontaneous, while a reaction with a positive ΔG is non-spontaneous. (C)</p> Signup and view all the answers

What does a negative ΔG value indicate about a reaction?

<p>The reaction goes spontaneously from A to B (D)</p> Signup and view all the answers

In which scenario is ΔG zero?

<p>The system is at equilibrium (B)</p> Signup and view all the answers

What happens if ΔG is a positive number?

<p>The reaction requires energy to proceed from B to A (D)</p> Signup and view all the answers

What is the significance of ΔG°′ in biochemistry?

<p>It defines the pH of the standard state (D)</p> Signup and view all the answers

What does it mean when ΔG has a great magnitude in a reaction?

<p>The reaction goes virtually to completion and is essentially irreversible (D)</p> Signup and view all the answers

How does ΔG allow prediction of the direction of a reaction?

<p>By indicating whether the reaction goes spontaneously or requires energy input (C)</p> Signup and view all the answers

What is the relationship between the Gibbs free energy change (ΔG) and the standard free-energy change (ΔG°) for a chemical reaction?

<p>ΔG = ΔG° - RT ln([B]/[A]) (C)</p> Signup and view all the answers

What is the significance of the standard free-energy change (ΔG°) in chemical reactions?

<p>All of the above. (D)</p> Signup and view all the answers

How is the equilibrium constant (K'eq) related to the standard free-energy change (ΔG°')?

<p>ΔG°' = -RT ln K'eq (D)</p> Signup and view all the answers

What is the difference between exergonic and endergonic processes in biological systems?

<p>Exergonic processes release free energy, while endergonic processes require free energy. (D)</p> Signup and view all the answers

What is the significance of coupling in biological systems?

<p>Coupling allows endergonic processes to proceed by linking them to exergonic processes. (B)</p> Signup and view all the answers

Which statement about the laws of thermodynamics is correct?

<p>The first law of thermodynamics states that energy is conserved in a closed system. (C)</p> Signup and view all the answers

Flashcards are hidden until you start studying

More Like This

Use Quizgecko on...
Browser
Browser