Exothermic and Endothermic Reactions

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Questions and Answers

Explain how the enthalpy change (ΔH) indicates whether a reaction is exothermic or endothermic.

A negative ΔH indicates an exothermic reaction because the products have less energy than the reactants, releasing heat. A positive ΔH indicates an endothermic reaction because the products have more energy than the reactants, absorbing heat.

Describe what happens to the temperature of the surroundings during an exothermic reaction and why this temperature change occurs.

The temperature of the surroundings increases. This is because the reaction releases heat into the surroundings, increasing the kinetic energy of the surrounding molecules.

Explain why it is not possible to directly measure enthalpy (H), but enthalpy change (ΔH) can be easily measured.

Enthalpy (H) is a state function that represents the total heat content of a system, which is difficult to quantify absolutely. Instead, we measure the change in heat content during a reaction, which is the enthalpy change (ΔH).

Provide an example, other than those listed, of an everyday process that represents an endothermic reaction, and explain why it is endothermic.

<p>Photosynthesis is an example of an endothermic reaction. Plants absorb light energy from the sun to convert carbon dioxide and water into glucose and oxygen. This energy input is required for the reaction to occur.</p> Signup and view all the answers

Explain the difference in energy levels between the reactants and products in an exothermic reaction using the terms 'Hproducts' and 'Hreactants'.

<p>In an exothermic reaction, Hproducts is less than Hreactants. This means that the products have lower energy than the reactants, and the excess energy is released as heat.</p> Signup and view all the answers

For an endothermic reaction, describe how the enthalpy change (ΔH) is related to the energy absorbed from the surroundings.

<p>In an endothermic reaction, the enthalpy change (ΔH) is equal to the amount of energy absorbed from the surroundings. Because energy is absorbed, ΔH is positive.</p> Signup and view all the answers

Why do hand warmers get hot?

<p>Hand warmers get hot because they contain chemicals that undergo an exothermic reaction. This reaction releases heat, raising the temperature of the hand warmer and the surrounding environment.</p> Signup and view all the answers

Describe what happens to the temperature of the surroundings during an endothermic reaction and explain why this temperature change occurs.

<p>The temperature of the surroundings decreases. This is because the reaction absorbs heat from the surroundings, decreasing the kinetic energy of the surrounding molecules.</p> Signup and view all the answers

Predict whether the change in enthalpy, $\Delta H$, for the reaction of an acid reacting with a metal would be positive or negative. Explain your answer.

<p>The change in enthalpy, $\Delta H$, for an acid reacting with a metal would be negative. Because acids reacting with metals is an <em>exothermic</em> reaction, heat is given off to the surroundings.</p> Signup and view all the answers

Are thermal decomposition reactions exothermic or endothermic? Explain your answer.

<p>Thermal decomposition reactions are generally endothermic. Thermal decomposition requires the input of heat to break chemical bonds and cause a substance to decompose.</p> Signup and view all the answers

Flashcards

Exothermic Reaction

Reactions that release energy, causing an increase in temperature of the surroundings.

Endothermic Reaction

Reactions that absorb energy from the surroundings, usually in the form of heat.

Enthalpy (H)

The total energy content of a system held at constant pressure.

Enthalpy Change (ΔH)

The change in enthalpy during a chemical reaction, measured in joules (J) or kilojoules (kJ).

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ΔH in Exothermic Reactions

In exothermic reactions, heat is released, so the enthalpy of products is less than reactants, resulting in a negative ΔH.

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ΔH in Endothermic Reactions

In endothermic reactions, heat is absorbed, so the enthalpy of products is greater than reactants, resulting in a positive ΔH.

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Study Notes

  • Chemical reactions often involve energy transfer with the surroundings.
  • Energy release in a reaction leads to a temperature increase in the reaction mixture and its immediate environment.
  • Reactions that release energy are classified as exothermic.

Exothermic Reactions

  • Acids reacting with metals exemplify exothermic reactions.
  • Oxidation of iron, as utilized in hand warmers, is an exothermic process.
  • The thermite reaction, involving aluminium and iron(III) oxide, is exothermic.

Endothermic Reactions

  • Energy absorption from the surroundings occurs as heat in endothermic reactions.
  • Melting ice is an endothermic process requiring energy input.
  • Dissolving ammonium chloride in water, such as in cold packs, is endothermic.
  • Thermal decomposition of group 2 carbonates needs energy input, making it endothermic.
  • The amount of heat transferred in a chemical reaction depends on the conditions under which it occurs.
  • Most lab reactions happen under constant pressure.
  • Enthalpy (H) is the total energy content of a system at constant pressure.
  • Enthalpy cannot be directly measured.
  • Enthalpy change (ΔH) can be easily measured in joules (J) or kilojoules (kJ).
  • ΔH is calculated as H(products) − H(reactants).
  • In exothermic reactions, heat is released so H(products) < H(reactants), meaning ΔH is negative.
  • In endothermic reactions, heat is absorbed so H(products) > H(reactants), meaning ΔH is positive.
  • Enthalpy changes are represented using enthalpy profile diagrams.

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