Exothermic and Endothermic Reactions
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Questions and Answers

What is a major environmental advantage of using hydrogen fuel cells compared to traditional combustion engines?

  • Hydrogen fuel cells are less expensive to manufacture.
  • Hydrogen fuel cells require significantly less maintenance.
  • Hydrogen fuel cells produce only water as a byproduct. (correct)
  • Hydrogen fuel cells can operate at higher temperatures.

Which safety concern is most associated with using hydrogen as a fuel source?

  • Its production of harmful greenhouse gases.
  • Its corrosive reaction with common metals.
  • Its high flammability and potential for explosion. (correct)
  • Its tendency to solidify at room temperature.

Why is it important to use an insulated container when investigating temperature changes during a chemical reaction, as described in the required practical?

  • To prevent the reactants from reacting too quickly.
  • To increase the rate of the reaction.
  • To minimize heat exchange with the surroundings. (correct)
  • To allow for better visibility of the reaction.

A reaction releases 500 J of energy and requires 200 J of energy to initiate. What is the net energy change for this reaction?

<p>-300 J (C)</p> Signup and view all the answers

Why is repeating the temperature change experiment with different concentrations of reactants important?

<p>To improve the accuracy and reliability of the results. (B)</p> Signup and view all the answers

Which of the following processes exemplifies an exothermic reaction?

<p>The combustion of methane gas. (D)</p> Signup and view all the answers

In an endothermic reaction, how does the energy level of the reactants compare to that of the products?

<p>The reactants start at a lower energy level than the products. (C)</p> Signup and view all the answers

Considering bond energies, what is the overall energy change for a reaction where total energy required to break the bonds is 950 kJ and the total energy released from bond formation is 1200 kJ?

<p>-250 kJ (Exothermic) (C)</p> Signup and view all the answers

How do rechargeable batteries differ from non-rechargeable batteries in terms of their chemical reactions?

<p>Rechargeable batteries can reverse the chemical reactions using electricity, while non-rechargeable batteries cannot. (B)</p> Signup and view all the answers

Which of the listed scenarios accurately describes the energy flow in an exothermic reaction, using the concept of activation energy?

<p>Energy is absorbed to reach activation energy, then more energy is released overall, warming the surroundings. (A)</p> Signup and view all the answers

For the reaction $N_2 + 3H_2 \rightarrow 2NH_3$, the bond energies are: N≡N is 945 kJ/mol, H-H is 436 kJ/mol, and N-H is 391 kJ/mol. Calculate the overall energy change for this reaction.

<p>-93 kJ/mol (Exothermic) (A)</p> Signup and view all the answers

In a reaction profile, what does the difference in energy between the reactants and the peak of the curve represent?

<p>The activation energy of the reaction. (B)</p> Signup and view all the answers

Why are cold packs typically considered an application of endothermic reactions?

<p>They absorb energy from the surroundings, causing a cooling effect. (B)</p> Signup and view all the answers

Flashcards

Exothermic Reaction

Reactions that release energy to the surroundings, increasing temperature.

Endothermic Reaction

Reactions that absorb energy from the surroundings, decreasing temperature.

Combustion

Burning fuels, releasing energy as heat and light.

Thermal Decomposition

Breaking down a compound using heat.

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Activation Energy

The initial energy needed to start a chemical reaction.

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Bond Breaking

Energy is absorbed when breaking bonds.

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Bond Making

Energy is released when forming bonds.

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Batteries

Chemical reactions produce electricity.

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Hydrogen Fuel Cell

A device that combines hydrogen and oxygen to produce electricity, water, and heat.

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Fuel Cell Advantage

Only water is produced, making it a clean energy alternative.

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Fuel Cell Disadvantage

Hydrogen is highly flammable and requires special handling.

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Temperature Change Experiment

Measure initial temperature, react in an insulated container, stir, and record temperature change.

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Energy Change Calculation

Energy change equals the energy needed to break bonds MINUS energy released when bonds form.

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Study Notes

  • Energy changes involve exothermic reactions that release energy and endothermic reactions that absorb energy.

Exothermic Reactions

  • Release energy into the surroundings, increasing the temperature.
  • Examples include combustion, neutralization, and oxidation reactions.
  • Self-heating cans and hand warmers utilize exothermic reactions.

Endothermic Reactions

  • Absorb energy from the surroundings, decreasing the temperature.
  • Examples include thermal decomposition, electrolysis, and photosynthesis
  • Cold packs use endothermic reactions for instant cooling.

Reaction Profiles

  • Illustrate energy changes during a reaction.

Exothermic Reaction Profile

  • Reactants start at a higher energy level than the products.
  • Energy is released, warming the surroundings.
  • Activation energy is the initial energy needed to start the reaction.

Endothermic Reaction Profile

  • Reactants start at a lower energy level than the products.
  • Energy is absorbed, cooling the surroundings.
  • Activation energy is typically higher than in exothermic reactions.

Bond Energy Calculations

  • Bond breaking is endothermic, requiring energy input.
  • Bond making is exothermic, releasing energy.
  • The overall energy change is the total energy in minus the total energy out.
  • For Hâ‚‚ + Clâ‚‚ → 2HCl, with bond energies H-H = 436 kJ/mol, Cl-Cl = 242 kJ/mol, and H-Cl = 431 kJ/mol:
    • Total energy in = 436 + 242 = 678 kJ
    • Total energy out = 2 x 431 = 862 kJ
    • Overall energy change = 678 - 862 = -184 kJ (exothermic)

Batteries

  • Chemical reactions generate electricity.
  • Rechargeable batteries can have their reactions reversed using electricity.
  • Non-rechargeable batteries stop working when reactants are used up.

Hydrogen Fuel Cells

  • Combine hydrogen and oxygen to produce water and energy: 2Hâ‚‚ + Oâ‚‚ → 2Hâ‚‚O
  • Advantages include water as the only emission, high efficiency, and no need for recharging.
  • Disadvantages include the explosive nature of hydrogen and the high costs of storage and transport.

Investigating Temperature Changes Practical

  • Measure initial temperature of reactants.
  • Combine reactants in an insulated container to minimize heat loss.
  • Stir and record the temperature change.
  • Repeat using different reactant concentrations.

Key Equations

  • Energy change in a reaction: Total Energy In - Total Energy Out
  • Hydrogen Fuel Cell Equation: 2Hâ‚‚ + Oâ‚‚ → 2Hâ‚‚O

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Description

Explore energy changes in chemical reactions, focusing on exothermic reactions that release energy and endothermic reactions that absorb energy. Understand reaction profiles, activation energy, and real-world applications like self-heating cans and cold packs. Learn how these reactions impact temperature and energy levels.

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