Chemistry: Exothermic and Endothermic Reactions
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Questions and Answers

Which of the following statements is true regarding exothermic reactions?

  • Energy is a reactant.
  • Reactants have less energy than the products.
  • Energy is a product. (correct)
  • Enthalpy change is always positive.

In an endothermic reaction, products possess less energy than the reactants.

False (B)

What does the symbol ΔH represent in a chemical reaction?

Enthalpy change

An exothermic reaction has a __________ energy change.

<p>negative</p> Signup and view all the answers

Match the energy change type with its description:

<p>Exothermic = Energy is released, reactants have more energy Endothermic = Energy is absorbed, products have more energy Enthalpy = Total heat content of a chemical system ΔH = Change in enthalpy during a reaction</p> Signup and view all the answers

What type of reaction is cellular respiration?

<p>Exothermic (D)</p> Signup and view all the answers

Photosynthesis produces carbon dioxide and water.

<p>False (B)</p> Signup and view all the answers

What is the balanced equation for cellular respiration?

<p>C6H12O6 + 6O2 -&gt; 6CO2 + 6H2O + 35099.6kJ</p> Signup and view all the answers

Photosynthesis is an __________ reaction that requires energy.

<p>endothermic</p> Signup and view all the answers

Match the following terms with their definitions:

<p>Cellular Respiration = Energy-releasing process Photosynthesis = Energy-absorbing process Exothermic Reaction = Releases heat energy Endothermic Reaction = Absorbs heat energy</p> Signup and view all the answers

Which statement is correct regarding enthalpy change (ΔH)?

<p>A negative ΔH indicates an exothermic reaction. (C)</p> Signup and view all the answers

Chemical reactions are not influenced by the coefficients in a chemical equation.

<p>False (B)</p> Signup and view all the answers

What is the ΔH for the reaction 2 N2(g) + 6 H2(g) → 4 NH3(g)?

<p>-100 kJ</p> Signup and view all the answers

Reactions with a positive ΔH are _____, meaning they gain energy.

<p>endothermic</p> Signup and view all the answers

Match the following chemical equations with their respective ΔH values:

<p>N2(g) + 3 H2(g) → 2 NH3(g) = -90 kJ 2 N2(g) + 6 H2(g) → 4 NH3(g) = -100 kJ 3 N2(g) + 9 H2(g) → 6 NH3(g) = -270 kJ</p> Signup and view all the answers

What is the overall enthalpy change ( abla H) for the given reaction?

<p>+35099.6 kJ (D)</p> Signup and view all the answers

Molar enthalpy can be expressed as the total enthalpy change divided by the number of moles.

<p>True (A)</p> Signup and view all the answers

What is the equation used to calculate enthalpy change?

<p>ΔH = nH_m</p> Signup and view all the answers

In the equation $ abla H = nH_m$, the variable 'n' represents the _______.

<p>moles</p> Signup and view all the answers

Match the following terms with their correct definitions:

<p>Enthalpy within a chemical reaction = The heat absorbed or released during a reaction Overall enthalpy change = The total change in enthalpy for a reaction Molar enthalpy = Enthalpy change per mole of substance Potential energy diagram = Graphical representation of energy changes during a reaction</p> Signup and view all the answers

What is the standard molar enthalpy of combustion of gasoline?

<p>-5074.1 kJ/mol (A)</p> Signup and view all the answers

The enthalpy change for burning 737 g of gasoline is positive.

<p>False (B)</p> Signup and view all the answers

How many moles of gasoline are in 737 g?

<p>6.4502</p> Signup and view all the answers

The enthalpy change for burning one litre of gasoline is approximately __________ kJ.

<p>-3.27 x 10^4</p> Signup and view all the answers

Match the following quantities with their corresponding calculations:

<p>Hm = -5074.1 kJ/mol moles of gasoline = 6.4502 mol mass of gasoline = 737 g total enthalpy change = -3.27 x 10^4 kJ</p> Signup and view all the answers

What is the molar enthalpy of reaction for NiO(l) in the reaction 2 Al(l) + 3 NiO(l) → Al2O3(s) + 3 Ni(l) + 954 kJ?

<p>-318 kJ/mol (C)</p> Signup and view all the answers

Exothermic reactions absorb energy from their surroundings.

<p>False (B)</p> Signup and view all the answers

What does the reaction 2 Al(l) + 3 NiO(l) produce?

<p>Al2O3(s) and 3 Ni(l)</p> Signup and view all the answers

In the reaction 2 Al(l) + 3 NiO(l) → Al2O3(s) + 3 Ni(l) + 954 kJ, energy is __________.

<p>released</p> Signup and view all the answers

Match the following substances with their role in the reaction:

<p>Al(l) = Reactant that is oxidized NiO(l) = Reactant that is reduced Al2O3(s) = Product formed Ni(l) = Product formed</p> Signup and view all the answers

What is the molar enthalpy of reaction for carbon dioxide in the fermentation reaction?

<p>-29.2 kJ/mol (A)</p> Signup and view all the answers

The original source of energy stored in glucose is the Sun.

<p>True (A)</p> Signup and view all the answers

How many kilograms of methanol are required to produce an enthalpy change of -9.00 x 104 kJ?

<p>4.52 kg</p> Signup and view all the answers

In the reaction of methanol, the heat released is represented by ΔH = __________ kJ.

<p>-1275.8</p> Signup and view all the answers

Match the following components to their respective roles:

<p>C6H12O6 = Substrate in fermentation 2H2O = Product of combustion in methanol reaction O2 = Reactant in methanol combustion 3CO2 = Byproduct of fermentation</p> Signup and view all the answers

What is the standard molar enthalpy of combustion, $ riangle H^ heta$, for ethyne?

<p>-1 301.1 kJ/mol (D)</p> Signup and view all the answers

The combustion of ethyne produces four moles of carbon dioxide and two moles of water.

<p>True (A)</p> Signup and view all the answers

What is the coefficient for $O_2(g)$ in the complete combustion of ethyne equation?

<p>5</p> Signup and view all the answers

In the given combustion reaction, ethyne ($C_2H_2(g)$) reacts with __________ gas.

<p>oxygen</p> Signup and view all the answers

Match the compounds with their respective coefficients in the combustion of ethyne:

<p>$C_2H_2(g)$ = 5 $O_2(g)$ = 5 $CO_2(g)$ = 4 $H_2O(l)$ = 2</p> Signup and view all the answers

Flashcards

Exothermic Reaction

A chemical reaction where energy is released into the surroundings, resulting in a decrease in the system's energy content.

Endothermic Reaction

A chemical reaction where energy is absorbed from the surroundings, resulting in an increase in the system's energy content.

Enthalpy

The total internal energy of a chemical system, including both kinetic energy (energy of motion) and potential energy (stored energy).

Enthalpy Change (ΔH)

The change in enthalpy (heat content) during a chemical reaction. It represents the heat absorbed or released by the system.

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Relationship between enthalpy change and reaction type

A positive enthalpy change indicates an endothermic reaction, where heat is absorbed by the system. A negative enthalpy change indicates an exothermic reaction, where heat is released by the system.

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Stoichiometry and Enthalpy Change

The enthalpy change is directly proportional to the amount of reactants or products involved in the reaction.

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Cellular Respiration

The process by which living organisms break down glucose to release energy in the form of ATP. This process occurs in the mitochondria of cells.

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Photosynthesis

The process where plants use sunlight energy to create glucose (food) from carbon dioxide and water. This occurs in chloroplasts.

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Enthalpy Change ($ \Delta H$)

The change in energy content during a reaction. It's a measure of how much energy is released or absorbed.

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Standard Molar Enthalpy of Combustion

The amount of heat released or absorbed when one mole of a substance undergoes a specific chemical reaction under standard conditions.

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Molar Mass

The mass of one mole of a substance, calculated from the sum of the atomic masses of all atoms in the molecule.

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Density

The ratio of the mass of a substance to its volume. It is a measure of how much mass is contained in a given volume.

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Enthalpy Change

The total amount of heat energy released or absorbed in a chemical reaction.

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Number of Moles

The number of moles of a substance present in a given mass.

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Overall Enthalpy Change (Reaction Enthalpy)

Describes the enthalpy change for the complete reaction when all the amounts are in the chemical equation's stoichiometric ratio.

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Molar Enthalpy (Hm)

The enthalpy change per mole of a substance involved in the reaction. It's calculated by dividing the enthalpy change by the number of moles of the substance.

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Potential Energy Diagram

A diagram that illustrates the energy changes during a reaction. It shows the relative energy levels of reactants, products, and the activation energy.

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Calculating Enthalpy Change

The enthalpy change of a reaction can be calculated by multiplying the number of moles of the substance by its molar enthalpy.

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Molar Enthalpy of Reaction

The enthalpy change associated with one mole of a specific reactant or product in a chemical reaction.

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Calculating Molar Enthalpy

The process of finding the enthalpy change for a specific substance in a chemical reaction. It involves dividing the total enthalpy change by the number of moles of that substance.

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Negative Enthalpy Change

A negative value for enthalpy change indicates that energy is released from the system, resulting in an exothermic reaction.

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Balancing a Chemical Equation

The process of balancing a chemical equation by adjusting the coefficients in front of each chemical formula to ensure that the number of atoms of each element on the reactant and product sides are equal.

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Coefficients in a Balanced Equation

A balanced chemical equation shows the relative amounts of reactants and products involved in a chemical reaction. Coefficients represent the mole ratios.

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Molar enthalpy of reaction (Hm)

The enthalpy change per mole of a substance in a chemical reaction. It tells you how much energy is released or absorbed for each mole of a specific reactant or product.

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Sun

The original source of energy for glucose production in plants, providing the basis for energy storage in living organisms.

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