Electrochemistry: Galvanic and Electrolytic Cells

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10 Questions

What type of energy conversion occurs in galvanic cells?

Chemical energy to electrical energy

What is the role of the anode in electrochemical cells?

Negative terminal

In which type of cell do reactions require external electrical input?

Electrolytic cells

What happens at the cathode in an electrolytic cell?

Receives electrons

Where are the anode and cathode placed in an electrolytic cell?

In the same container

Where does oxidation occur in an electrochemical cell?

Anode

What is the role of the Salt Bridge in an electrochemical cell?

Completing the circuit and maintaining electrical neutrality

Which metal undergoes oxidation in a Daniell cell?

Zinc

In an electrochemical cell, what happens at the cathode?

Reduction

Why is it important to understand oxidation and reduction in electrochemical cells?

To correctly represent cells and understand chemical reactions

Study Notes

  • There are two types of electrochemical cells: galvanic cells and electrolytic cells.
  • In electrochemistry, the subject is divided into three portions: galvanic cell, electrolytic cell, and electrolytic solution.
  • Electrochemical cells convert chemical energy into electrical energy (galvanic cells) and vice versa (electrolytic cells).
  • Galvanic cells have chemical input and electrical output, while electrolytic cells have electrical input and chemical output.
  • Chemical reactions in galvanic cells are spontaneous, while in electrolytic cells, they are non-spontaneous and require external electrical input.
  • The value of delta G in thermodynamics is negative for spontaneous reactions and positive for non-spontaneous reactions.
  • Anode and cathode in electrochemical cells are placed in different containers, but in electrolytic cells, they are in the same container.
  • Anode is the positive terminal, while cathode is the negative terminal in electrochemical cells.
  • Understanding the difference between anode (positive terminal) and cathode (negative terminal) is crucial in electrochemistry.
  • Remembering the definitions of anode (negative terminal) and cathode (positive terminal) is essential for understanding electrochemical cells.- The text discusses the concepts of Galvanic cell and Electrolytic cell in chemistry.
  • It explains that in a Galvanic cell, the left side container is for the anode and the right side container is for the cathode.
  • Anode is where oxidation occurs, while cathode is where reduction occurs.
  • The text mentions about the Salt Bridge, which helps in completing the circuit and maintaining electrical neutrality.
  • It talks about the Daniell cell, where zinc undergoes oxidation in one container and copper undergoes reduction in another container.
  • The process involves the release of electrons and conversion of chemical energy to electrical energy.
  • It emphasizes the importance of understanding oxidation (loss of electrons) and reduction (gain of electrons) in chemical reactions.
  • It highlights the representation of cells in a circuit, with a focus on indicating the anode and cathode sides correctly.
  • The text touches upon using the Salt Bridge to maintain electrical balance in the circuit.
  • It concludes by reminding the readers about the significance of correctly representing cells and understanding chemical reactions in electrochemical cells.

Learn about the differences between galvanic cells and electrolytic cells in electrochemistry. Understand the concepts of anode, cathode, oxidation, reduction, salt bridge, and the conversion of chemical energy to electrical energy. Explore the importance of representing cells correctly in a circuit.

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