Electrochemistry Flashcards

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Questions and Answers

What is the purpose of a salt bridge in an electrochemical cell?

maintain electrical neutrality in the half-cells via migration of ions

What is the cathode in an alkaline battery?

MnO2

What is the anode in an alkaline battery?

Zn powder

What is the cathode in the hydrogen fuel cell?

<p>KOH</p> Signup and view all the answers

In a lead-acid battery, what is the anode?

<p>Pb</p> Signup and view all the answers

What is one of the differences between a voltaic cell and an electrolytic cell?

<p>a nonspontaneous reaction is forced to occur</p> Signup and view all the answers

What is the term for the gain of electrons by an element?

<p>reduction</p> Signup and view all the answers

What is the electrode at which oxidation occurs called?

<p>anode</p> Signup and view all the answers

In a voltaic cell, electrons flow from the ________ to the _____________.

<p>anode, cathode</p> Signup and view all the answers

The more _______ the value of Ered, the greater the driving force for reduction.

<p>positive</p> Signup and view all the answers

Galvanized iron is coated with __________.

<p>zinc</p> Signup and view all the answers

What retards corrosion of iron?

<p>high PH conditions</p> Signup and view all the answers

Flashcards

Salt Bridge Purpose

Maintains electrical neutrality in half-cells by allowing ion migration.

Alkaline Battery Cathode

Manganese dioxide ((MnO_2)).

Alkaline Battery Anode

Zinc powder.

Hydrogen Fuel Cell Cathode

Potassium hydroxide (KOH)

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Lead-Acid Battery Anode

Lead (Pb).

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Voltaic vs. Electrolytic Cells

Voltaic cells produce a spontaneous reaction; electrolytic cells force a nonspontaneous reaction.

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Reduction

The gain of electrons by an element or ion.

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Electrode Where Oxidation Occurs

Anode

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Electron Flow in Voltaic Cell

Anode to cathode

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Ered and Reduction Force

Positive

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Coating on Galvanized Iron

Zinc

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Conditions That Retard Iron Corrosion

High pH (basic) conditions.

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Study Notes

Salt Bridge Function

  • Maintains electrical neutrality in electrochemical cells through ion migration.

Alkaline Battery Components

  • Cathode material: Manganese dioxide (MnO2).
  • Anode material: Zinc powder (Zn).

Hydrogen Fuel Cell

  • Cathode material: Potassium hydroxide (KOH).

Lead-Acid Battery

  • The anode is made of lead (Pb), with electrodes consumed during operation.

Cell Types

  • Voltaic cells generate spontaneous reactions; electrolytic cells force nonspontaneous reactions.

Reduction Process

  • Gain of electrons by an element defines reduction.

Oxidation Location

  • Oxidation occurs at the anode in an electrochemical cell.

Electron Flow in Voltaic Cells

  • Electrons flow from the anode to the cathode.

Reduction Driving Force

  • A more positive Ered value indicates a greater driving force for reduction.

Galvanization

  • Iron is protected against corrosion by coating with zinc (galvanized iron).

Corrosion Prevention

  • High pH conditions help retard the corrosion of iron.

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