Electrochemistry and Battery Chemistry
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Questions and Answers

What is the reduction process for Quinhydrone electrode?

The electrodic reaction for the reduction process is not specified in the content.

What are Lithium-ion batteries?

Lithium-ion batteries are secondary rechargeable batteries that contain lithium intercalated carbon as anode and lithium metal oxide as cathode, with a non-aqueous electrolyte.

Distinguish between electrolytic and electrochemical cells.

The distinctions are not explicitly mentioned in the content.

What is a battery? Give one example each for primary and secondary batteries.

<p>A battery is a device consisting of one or more electrochemical cells that converts stored chemical energy into electrical energy. Example of primary battery: Zinc-Carbon battery; Example of secondary battery: Lead-Acid battery.</p> Signup and view all the answers

Differentiate primary battery from secondary battery.

<p>Primary batteries are not rechargeable, while secondary batteries can be recharged. Primary batteries undergo irreversible reactions, while secondary batteries have reversible reactions.</p> Signup and view all the answers

Calculate the electrode potential of Zn | Zn²⁺ (0.01) electrode at 25 °C. (E° Zn | Zn = 0.76 V)

<p>E = E° - (RT/nF) ln(Q), where R = 8.314 J/(mol·K), T = 298 K, n = 2, F = 96485 C/mol; Apply the values to get the electrode potential.</p> Signup and view all the answers

Represent the Calomel electrode and write its electrode reaction.

<p>The Calomel electrode is represented as Pt-Hg/Hg₂Cl₂/KCl(aq), and its reaction involves the conversion of Hg₂Cl₂ to Hg in the presence of KCl.</p> Signup and view all the answers

Find the EMF of the following cell...

<p>The specific details for calculating the EMF are not provided in the content.</p> Signup and view all the answers

Study Notes

Electrochemistry and Battery Chemistry

  • Quinhydrone electrode: A type of electrode used to measure pH. It consists of a platinum wire immersed in a solution containing quinhydrone (an equimolar mixture of quinone and hydroquinone). The electrode reaction involves the reduction of quinone to hydroquinone.
  • Lithium-ion batteries (LIB): Popular rechargeable batteries consisting of a carbon anode, a lithium metal oxide cathode, and an organic electrolyte. The battery's reaction involves lithium ions moving between the anode and cathode during charging/discharging.
  • Electrolytic and electrochemical cells: Electrolytic cells use electricity to drive non-spontaneous chemical reactions, while electrochemical cells convert chemical energy to electrical energy via spontaneous reactions.
  • Batteries: Devices composed of one or more electrochemical cells converting stored chemical energy into electrical energy.
    • Primary batteries: Not rechargeable, examples include Zinc-carbon batteries.
    • Secondary batteries (rechargeable): Can be recharged, examples include Lead-acid batteries and Lithium-ion batteries.
  • Calomel electrode: A reference electrode that uses mercury in contact with mercurous chloride (calomel). Its electrode reaction involves the reduction of mercurous ions to mercury.

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Test your knowledge on electrochemical principles and the functioning of batteries. This quiz covers topics such as quinhydrone electrodes, lithium-ion batteries, and the differences between electrolytic and electrochemical cells. Challenge yourself to understand the core concepts that drive modern energy storage technologies.

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