Effect of Concentration on Ecell in Cell Reactions Quiz

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Questions and Answers

In a galvanic cell, how is the potential difference between two electrodes measured?

  • By connecting them to a potentiometer
  • By connecting them to a voltmeter (correct)
  • By connecting them to an ammeter
  • By connecting them to a resistor

In the standard hydrogen electrode setup, what is the potential assigned to the SHE?

  • 0.5 volts
  • -1 volt
  • 0 volts (correct)
  • 1 volt

What components are needed to make an electrode a standard reference electrode?

  • Temperature at 273K
  • Hydrogen gas at pressure of 1 atm
  • Solution containing hydrogen ions at 0.5 mol dm-3
  • Hydrogen gas at pressure of 100 kPa and solution containing hydrogen ions at 1.00 mol dm-3 (correct)

Why are standard conditions necessary for a reference electrode like the standard hydrogen electrode?

<p>To maintain consistency in potential measurements (B)</p> Signup and view all the answers

In a cell diagram, how is the hydrogen electrode represented?

<p>| Pt | H2 (g) | H+ (aq) (B)</p> Signup and view all the answers

How does changing the concentration of Mn+ ions affect the redox equilibrium in a cell?

<p>It shifts the equilibrium to the right (A)</p> Signup and view all the answers

What happens to Ecell as the reactant concentrations drop in a cell reaction?

<p>Ecell decreases (B)</p> Signup and view all the answers

What is the relationship between Ecell and the likelihood of a reaction occurring?

<p>Higher Ecell indicates a more likely reaction (C)</p> Signup and view all the answers

How does increasing the concentration of Fe2+ and decreasing Zn2+ affect Ecell?

<p>Ecell increases (C)</p> Signup and view all the answers

What effect does a temperature rise have on Ecell for exothermic cells?

<p>Ecell decreases (C)</p> Signup and view all the answers

What does a positive Ecell value indicate about a reaction?

<p>The reaction might occur (A)</p> Signup and view all the answers

How does carrying out a reaction at non-standard conditions affect Ecell compared to standard conditions?

<p>Ecell decreases (A)</p> Signup and view all the answers

What is the standard electrode potential for the half cell: Cu2+(aq) | Cu(s)?

<p>+0.34V (A)</p> Signup and view all the answers

How can the percentage apparatus uncertainty in a titration be reduced?

<p>Increasing the volume and concentration in the conical flask (A)</p> Signup and view all the answers

In the reaction Mg + Cu2+ → Cu + Mg2+, which species is undergoing reduction?

<p>Cu (B)</p> Signup and view all the answers

What effect does using a balance that measures to more decimal places have on the percentage uncertainty in weighing a solid?

<p>Decreases the uncertainty (D)</p> Signup and view all the answers

What is the standard electrode potential for the half cell: Mg2+(aq) | Mg(s)?

<p>-2.37V (D)</p> Signup and view all the answers

How does reducing the uncertainty in a burette reading affect the volume of the titre?

<p>Increases the volume of the titre (C)</p> Signup and view all the answers

Which electrode will oxidize and go from right to left in a redox reaction?

<p>Mg(s) (A)</p> Signup and view all the answers

What is the impact of using burettes with lower apparatus uncertainty in a titration?

<p>Decreases the experimental uncertainty (C)</p> Signup and view all the answers

To determine the Ecell for a spontaneous change, what formula is used?

<p>Ecell = Ered - Eox (A)</p> Signup and view all the answers

When looking at a series of measurements, which experiments will have the highest experimental uncertainties?

<p>Experiments with small readings (B)</p> Signup and view all the answers

What will happen in a spontaneous change with regards to the Ecell value?

<p>Ecell will be positive (D)</p> Signup and view all the answers

How does taking two readings during a titration affect the uncertainty on the titre volume?

<p>+/- 0.10 cm3 (D)</p> Signup and view all the answers

What type of electrochemical cell is a non-rechargeable cell?

<p>Irreversible (D)</p> Signup and view all the answers

In the primary non-rechargeable cells provided, what is the overall reaction for the Dry Cell example?

<p>2MnO2(s) + 2NH4+(aq) + Zn → Mn2O3 + 2NH3 + H2O + Zn2+ (D)</p> Signup and view all the answers

What is the standard electrode potential for the primary Lithium–manganese dioxide non-rechargeable cell?

<p>-3.04 V (C)</p> Signup and view all the answers

Which component is not present in the conventional cell diagram of the primary Lithium–manganese dioxide non-rechargeable cell?

<p>| Pt (s) (B)</p> Signup and view all the answers

What is the oxidation half-reaction for the forward reaction in the Lead acid secondary rechargeable cell?

<p>PbSO4 + 2e- → Pb + SO42- (C)</p> Signup and view all the answers

What is the cell potential for the Lead acid secondary rechargeable cell?

<p>+2.91V (B)</p> Signup and view all the answers

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