Electrochemistry: Cell Reactions and Commercial Applications
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Questions and Answers

What is the electrode potential for the disproportionation reaction involving Cu​2+​ ions?

  • +0.52V
  • +0.15V
  • +0.37V (correct)
  • +0.34V

Which type of electrochemical cell is commonly used as a source of energy for commercial use?

  • Fuel cells (correct)
  • Rechargeable cells
  • Non-rechargeable cells
  • Hydrogen fuel cells

What is the main waste product produced in a hydrogen fuel cell?

  • Oxygen
  • Methane
  • Carbon dioxide
  • Water (correct)

Why are fuel cells considered advantageous for generating electrical current?

<p>They generate electricity without needing to be recharged (A)</p> Signup and view all the answers

What is one of the downsides of hydrogen fuel cells?

<p>High flammability of hydrogen (A)</p> Signup and view all the answers

Based on the provided electrode potentials, is the disproportionation reaction thermodynamically feasible?

<p>Yes, it is thermodynamically feasible (D)</p> Signup and view all the answers

What aspect of a reaction does the cell emf value indicate?

<p>Thermodynamic feasibility (A)</p> Signup and view all the answers

Why might a reaction not actually occur even if it is thermodynamically feasible?

<p>Slow rate of reaction (D)</p> Signup and view all the answers

What series can standard electrode potentials be ordered into?

<p>Electrochemical series (D)</p> Signup and view all the answers

Which type of electrode potentials are better oxidising agents?

<p>Highly positive (B)</p> Signup and view all the answers

In a disproportionation reaction, what happens to the oxidation number of a species?

<p>It both increases and decreases (B)</p> Signup and view all the answers

How can electrode potentials help determine if a species will undergo disproportionation?

<p>By checking if the overall E​ө​cell​ value is positive (C)</p> Signup and view all the answers

How does increasing the concentration of the solutions in an electrochemical cell affect the cell emf?

<p>It makes the cell emf more positive. (C)</p> Signup and view all the answers

Which of the following is the most correct statement about the relationship between cell emf and entropy change?

<p>Cell emf is directly proportional to the total entropy change of the reaction. (B)</p> Signup and view all the answers

Which of the following electrochemical cells could be used to study disproportionation reactions?

<p>A cell with the same element in different oxidation states. (A)</p> Signup and view all the answers

What is the effect of increasing the pressure on the cell emf?

<p>It makes the cell emf more negative. (C)</p> Signup and view all the answers

What is a major limitation in using the standard hydrogen electrode (SHE) to determine the feasibility of a reaction?

<p>The SHE cannot be used to accurately measure the standard cell potential of the reaction. (D)</p> Signup and view all the answers

Which type of electrochemical cell is most commonly used in commercial applications?

<p>Fuel cells that use a metal and a gas electrode. (B)</p> Signup and view all the answers

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