Double Bonds

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Questions and Answers

Which of the following statements accurately compares single and double bonds?

  • Double bonds involve sharing one pair of electrons, while single bonds involve sharing two pairs.
  • Double bonds are shorter and have greater electron density between the nuclei compared to single bonds. (correct)
  • Single bonds result in greater repulsion between electron clouds, leading to higher reactivity.
  • Single bonds are shorter and more reactive than double bonds.

Molecules form multiple bonds (double or triple) because they have sufficient valence electrons to complete their valence shells by sharing only one pair of electrons.

False (B)

Explain why double bonds are more reactive than single bonds.

Double bonds have electron clouds that extend out further from the molecule, leading to minimal repulsion and increased reactivity.

Lone pairs in molecules are shown at angles to minimize ______.

<p>repulsion</p> Signup and view all the answers

Match the bond type with the number of electron pairs shared:

<p>Single Bond = One pair of electrons Double Bond = Two pairs of electrons Triple Bond = Three pairs of electrons</p> Signup and view all the answers

Compared to a single bond, a double bond has:

<p>Greater electron density between the nuclei and is shorter. (A)</p> Signup and view all the answers

In a double bond, the nuclei experience a weaker force of attraction compared to a single bond due to less electron density.

<p>False (B)</p> Signup and view all the answers

Give an example of a molecule that contains a double bond.

<p>O2</p> Signup and view all the answers

A double bond is formed when atoms share ______ pairs of electrons.

<p>two</p> Signup and view all the answers

What is the primary reason electron clouds extend further out in a double bond arrangement?

<p>To minimize electron-electron repulsion. (A)</p> Signup and view all the answers

Flashcards

Single Bond

One pair of shared electrons between two atoms.

Double Bond

Two pairs of shared electrons between two atoms.

Triple Bond

Three pairs of shared electrons between two atoms.

Double Bond Formation

Atoms share two pairs of electrons (4 electrons).

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Electron Density in Double Bonds

Greater electron density concentrates the negative charge, strengthening the attraction between nuclei.

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Double vs. Single Bond Length

Double bonds are shorter than single bonds.

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Force on Nuclei

The nucleus feels a stronger force of attraction inwards.

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Electron Cloud Repulsion

Double bonds create more repulsion, causing electron clouds to extend further.

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Double Bond Reactivity

Double bonds are more reactive than single bonds due to electron cloud extension.

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Lone Pair Positioning

Lone pairs are shown at angles in order to minimize repulsion.

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Study Notes

  • Not all molecules have enough valence electrons for full valence shells
  • A single pair of shared electrons between two atoms make a single bond
  • Two pairs of electrons shared between two atoms make a double bond
  • Three pairs of electrons shared between two atoms make a triple bond

Double Bonds

  • Atoms may share 2 pairs of electrons, 4 total, to form a double covalent bond
  • Example: O2
  • Lone pairs arrange at angles to minimize repulsion

Properties

  • Due to the sharing of 4 electrons, double bonds have greater electron density between the two nuclei than single bonds, which share 2 electrons
  • Area between the nuclei is more negative
  • Nuclei experience a stronger force of attraction
  • Double bonds are shorter than single bonds
  • The 4 electrons in a double bond create a lot of repulsion, causing the electron clouds to extend further from the molecule to minimize repulsion
  • Electron clouds stick out more, making double bonds more reactive than single bonds

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