Cosmetics Overview and Categories

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Questions and Answers

Which of the following ingredients would be MOST effective in a shampoo designed to improve hair's shine and manageability?

  • Behentrimonium Methosulfate (correct)
  • Acrylic Acid/VP Crosspolymer
  • Stearalkonium Bentonite
  • Glycol Stearate

A cosmetic manufacturer is formulating a new exfoliating body scrub. Which ingredient is suitable?

  • Essential Oils (correct)
  • Propylene glycol stearate
  • Lactic acid
  • Guar hydroxypropyltrimonium chloride

A chemist is tasked with increasing the thickness of the oil-soluble components in a new lotion formulation. Which of the following ingredients would be MOST suitable for this purpose?

  • Agar
  • Polyquaternium-7
  • Beeswax (correct)
  • Glycolic acid

A cosmetic formulator needs to create a pearlescent effect in a new shampoo product. Which of the following ingredients would be MOST appropriate to use as an opacifying agent?

<p>Stearamide MEA-stearate (A)</p> Signup and view all the answers

Which of the following ingredients functions primarily as a humectant in skincare formulations?

<p>Sodium hyaluronate (B)</p> Signup and view all the answers

Which of the following best describes the function of occlusives in skincare products?

<p>Blocking water evaporation and maintaining skin hydration. (A)</p> Signup and view all the answers

Which ingredient would be MOST effective for holding a styled hair in place?

<p>Acrylates, alkyl acrylate cross polymer (D)</p> Signup and view all the answers

Based on the information provided, what is the historical significance of the clay cylinder found in ancient Babylon?

<p>Evidence of soap making dating back to 2800 B.C. (B)</p> Signup and view all the answers

Which of the following skin conditioning agents primarily functions to impart softness to the skin?

<p>Emollients (B)</p> Signup and view all the answers

If a cosmetic product claims to 'dissolve' other ingredients within the formulation, which type of substance is most likely responsible for this property?

<p>Solvent (D)</p> Signup and view all the answers

How does the conjugation within a molecule affect its visible color, based on the examples provided?

<p>Increased conjugation leads to a shift towards longer wavelengths, resulting in an orange or red color. (C)</p> Signup and view all the answers

In the context of dyes, what is the primary role of an auxochrome?

<p>To modify the color of the dye and/or enhance its solubility and attachment to fibers. (B)</p> Signup and view all the answers

Which of the following best explains why acid dyes are effective on polyamides and proteins?

<p>Acid dyes carry a negative charge and are used on polyamides and proteins that carry a positive charge under acidic conditions. (C)</p> Signup and view all the answers

What is a key disadvantage of acid dyes, despite their cost-effectiveness and light fastness?

<p>Poor wet fastness. (B)</p> Signup and view all the answers

A dye molecule contains a chromophore with limited conjugation. If an auxochrome is added that introduces additional conjugated double bonds, what is the likely effect on the dye's color?

<p>The color will shift towards longer wavelengths (e.g., from yellow to orange). (B)</p> Signup and view all the answers

In the context of mosquito repellents, what is the primary active component of pyrethrum that provides its insecticidal properties?

<p>Pyrethrins (A)</p> Signup and view all the answers

Which dyeing method relies on a coupling reaction between naphthol and a diazo component to develop color?

<p>Azoic Dyeing (B)</p> Signup and view all the answers

Why are reactive dyes particularly effective for dyeing cellulosic fibers?

<p>They undergo a chemical reaction to form a covalent bond with the cellulose. (D)</p> Signup and view all the answers

Considering their chemical properties, which type of dye would be MOST suitable for creating a tie-dye effect on cotton fabric?

<p>Azoic Dyes (D)</p> Signup and view all the answers

Historically, how was pyrethrum utilized in military contexts?

<p>As a powder to combat head and body lice. (A)</p> Signup and view all the answers

What structural modification enhances the efficacy of direct dyes?

<p>Adding alkyl groups to the N-atom. (D)</p> Signup and view all the answers

Which characteristic is a drawback of direct dyes despite their ease of application?

<p>Poor fastness quality. (A)</p> Signup and view all the answers

How does adding sodium chloride impact the direct dyeing process?

<p>It accelerates the absorption rate of the dye. (A)</p> Signup and view all the answers

Which type of dye requires sodium hydrosulfite dissolved in sodium hydroxide to become soluble?

<p>Vat dyes (D)</p> Signup and view all the answers

What is the primary purpose of using vat dyes and sulfur dyes on cellulosic substrates?

<p>To enhance wet fastness. (D)</p> Signup and view all the answers

Which of these dyes is derived from plant sources?

<p>Indigo (D)</p> Signup and view all the answers

What kind of fabrics are suitable for direct dyes?

<p>Cellulosic polymer like cotton (C)</p> Signup and view all the answers

Upon exposure to water, what is the effect of dyes with low fastness?

<p>Color removal. (A)</p> Signup and view all the answers

Which of the following statements accurately describes the role of builders in cleaning products?

<p>Builders enhance the effectiveness of surfactants by reducing water hardness and maintaining alkalinity. (A)</p> Signup and view all the answers

What is the primary function of surfactants in a cleaning solution?

<p>To lower the surface tension of water, allowing for better wetting and emulsification of oils. (D)</p> Signup and view all the answers

During saponification, what are the main products formed when plant oils and animal fats react with a liquid alkali?

<p>Soap, water, and glycerine. (A)</p> Signup and view all the answers

Which type of surfactant is best suited for use in fabric softeners and fabric-softening laundry detergents?

<p>Cationic surfactants. (B)</p> Signup and view all the answers

If a cleaning product is designed to be effective in hard water and produce low suds, which type of surfactant would be most suitable?

<p>Nonionic. (A)</p> Signup and view all the answers

Which of the following describes a key characteristic of amphoteric (zwitterionic) surfactants?

<p>Their charge can vary (positive, negative, or neutral) depending on the pH of the water. (B)</p> Signup and view all the answers

In the preparation of detergents, what role do petrochemicals and oleochemicals play?

<p>They provide the hydrocarbon chain for the hydrophobic end of the detergent molecule. (B)</p> Signup and view all the answers

Why are anionic surfactants popular choices for laundry and hand dishwashing detergents?

<p>Because of their excellent cleaning properties and high sudsing ability. (C)</p> Signup and view all the answers

Hydrolysis of oils and fats using high-pressure steam primarily yields which of the following products?

<p>Crude fatty acids and glycerine (C)</p> Signup and view all the answers

Which type of cleaning product would most likely contain quaternary ammonium compounds?

<p>Fabric softeners (D)</p> Signup and view all the answers

Flashcards

Glycolic acid

An alpha hydroxy acid used for skin exfoliation.

Hair Conditioning Agents

Ingredients that improve hair's gloss, appearance, and shine.

Opacifying Agents

Substances that make shampoos and gels appear pearlescent.

Preservatives

Chemicals that prevent or slow microbial growth in cosmetics.

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pH Adjusters

Compounds that modify the pH level of cosmetic products.

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Emollients

Substances that soften the skin by remaining on the upper layer.

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Humectants

Ingredients that help retain moisture in the skin and draw in water.

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Occlusives

Agents that prevent water from evaporating, keeping skin moist.

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Historical soap-making

Evidence shows early soap making dates back to 2800 B.C. in Babylon.

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Sodium hydroxymethylglycinate

A preservative used in cosmetics, known for its antimicrobial properties.

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Azo Group

A functional group involved in color production in dyes, consists of a nitrogen-nitrogen double bond.

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Conjugated System

A structure in which pi bonds are alternating with single bonds, allowing color absorption.

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Acid Dyes

Anionic dyes suitable for polyamides and proteins, applied in acidic conditions.

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Auxochromes

Molecular groups that enhance dye color and help attach dyes to fibers.

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Light Fastness

The ability of a dye to resist fading when exposed to light.

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Sulfur dyes

Dyes named for their synthesis using sulfur, often expensive.

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Azoic Dyes (Naphthol dye)

Dyes suitable for cotton and nylon, developed through a coupling reaction.

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Pyrethrum

Natural insecticidal oil derived from pyrethrum daisies used against flying insects.

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Reactive Dyes

Dyes that chemically bond with cellulosic fibers, creating bright colors.

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Mosquito repellents

Natural smoke and herbs used to deter mosquitoes in different cultures.

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Surfactants

Agents that lower surface tension in liquids, aiding in cleaning.

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Saponification

The process of making soap using fats and an alkali.

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Anionic Surfactants

Surfactants with a negative charge, excellent for cleaning.

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Nonionic Surfactants

Surfactants with no charge, low sudsing, resistant to hard water.

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Cationic Surfactants

Surfactants with a positive charge, used for disinfection and softening.

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Zwitterionic Surfactants

Surfactants that can be positive or negative based on pH.

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Builders

Compounds that enhance surfactant cleaning and reduce water hardness.

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Hydrophobic End

The part of a surfactant that repels water and attracts greasy soils.

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Emulsification

The process of mixing oil and water to suspend dirt in a cleaner.

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Detergents

Cleaning agents derived from petrochemicals or oleochemicals.

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Direct Dyes

Dyes applied to cellulosic fibers like cotton, requiring no mordant.

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Alkyl Groups

Hydrocarbon chains added to dyes to enhance dyeing ability.

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Water-solubility

Ability of dyes to dissolve in water, a key feature of direct dyes.

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Natural Dyes

Dyes obtained from plant, mineral, or insect sources.

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Indigo

A traditional blue dye made from fermented plant leaves.

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Vat Dyes

Water-insoluble dyes made soluble using sodium hydrosulfite and hydroxide.

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Sodium Chloride in Dyeing

Salt added to accelerate the absorption rate of dyes.

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Fastness Quality

Dye stability against fading from water and sunlight exposure.

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Study Notes

Cosmetics

  • Cosmetics are substances applied to the external human body to cleanse, protect and change appearance.
  • Global Data reports that rising populations and decreasing unemployment are driving cosmetic industry growth due to increasing consumer focus on image.

Major Cosmetics Categories

  • Skin Care: Cleansers, toners, moisturizers, serums, and sunscreens.
  • Makeup: Foundation, concealer, blush, eyeshadow, mascara, eyeliner, lip products.
  • Hair Care: Shampoos, conditioners, styling products, and hair colors.
  • Fragrances: Perfumes, colognes, and body mists.
  • Personal Care: Deodorants, body lotions, and shower products.

Cosmetic Product Forms

  • Viscosity: resistance to flow; a vital quality control factor in cosmetics.
  • Important factors for viscosity: ease of application, dispensing method, and customer perception.
  • Different forms based on viscosity include:
    • Liquid: Ranging from water-like to honey-like; Water-based liquids have limited oil content. Examples: perfumes, body mists, skin toners.
    • Gel: Thicker than liquid with limited flow; formed with gums or thickeners. Examples: water-based hair gels, viscous hair oils.
    • Foaming Gel: Honey-like viscosity; foams, limiting flow and preventing dripping. Examples: shampoos, body washes, mousses, foaming facial cleansers.
    • Serum: Low viscosity gel to lotion-like; penetrates deeply into skin; used for delivering potent ingredients.
    • Lotion: Low viscosity emulsions; easily pumped or squeezed from packaging.
    • Cream: Medium to high viscosity emulsions; comes in jars or bottles. Examples: anti-aging creams, skincare creams.
    • Powder: Used in color cosmetics like eyeshadow, blushes, pressed and loose powders. Examples: baby powder, talc, blushes.
    • Balm: Primarily oil-based with semi-solid consistency. Examples: hair and lip balm, lipstick.
    • Mud: Semi-solid product containing clays and oils. Examples: mud masks.
    • Scrub: Contains particles for mechanical skin exfoliation. Examples: salt, sugar scrubs.

Brief History of Cosmetics

  • Ancient Egyptians used scented oils and ointments for skin care, odor masking, and sun protection.
  • Myrrh, thyme, and other natural ingredients were part of religious and cosmetic rituals.
  • Materials like Galena and Malachite were used for coloration, used in ancient cultures for complexion enhancement.

Other Information

  • Mehndi: An art practice involving intricate henna designs traditionally used before Hindu weddings.
  • Social customs: Egg whites and white lead were used to achieve a pale complexion in certain societies.

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