Chemistry Solutions and Molarity Quiz

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Questions and Answers

What is the definition of molarity in terms of moles and volume?

  • Molarity is the number of grams of solute per liter of solution.
  • Molarity is the number of moles of solute divided by the mass of the solvent in grams.
  • Molarity is the volume of solute divided by the number of moles in the solution.
  • Molarity is the number of moles of solute divided by the volume of the solution in liters. (correct)

If 5g of NaOH is dissolved in 450 mL of water, what is required to calculate its molarity?

  • The molar mass of NaOH. (correct)
  • The total mass of the solvent.
  • The boiling point of the solution.
  • The density of the solution.

What would be the molarity of a solution containing 5g of NaOH in 450 mL?

  • 0.113 M
  • 0.222 M
  • 0.056 M
  • 0.083 M (correct)

What is the unit of molality?

<p>moles per kilogram of solvent (C)</p> Signup and view all the answers

How can one describe the relationship between molarity and density?

<p>Molarity can be calculated from density if the molar mass is known. (D)</p> Signup and view all the answers

What is the equation that represents Henry's law in this context?

<p>p = K_n x (C)</p> Signup and view all the answers

At what temperature is the solubility of methane in benzene being calculated?

<p>298 K (A)</p> Signup and view all the answers

What is a solution primarily composed of?

<p>Homogeneous mixture of two or more components (B)</p> Signup and view all the answers

What is the value of the constant K_n given in the calculation?

<p>177.99 × 10^-5 (A)</p> Signup and view all the answers

In a binary solution, how many components are present?

<p>Two components (A)</p> Signup and view all the answers

How is the solubility of methane calculated in this scenario?

<p>By dividing pressure by K_n (B)</p> Signup and view all the answers

What is the approximate final result of the solubility calculation for methane in benzene?

<p>178 × 10^-5 (B)</p> Signup and view all the answers

What characterizes an aqueous solution?

<p>Water is present in excess (D)</p> Signup and view all the answers

What type of solution is termed non-aqueous?

<p>Solution without excess water (B)</p> Signup and view all the answers

What does a ternary solution consist of?

<p>Three components (D)</p> Signup and view all the answers

Mass percentage of a component in a solution is calculated by which formula?

<p>Mass of the component divided by total mass of solution multiplied by 100 (B)</p> Signup and view all the answers

In the context of solutions, what is a solute?

<p>The substance that dissolves other substances (A)</p> Signup and view all the answers

Which of the following describes a quaternary solution?

<p>Contains four components (B)</p> Signup and view all the answers

What is necessary for forming a saturated solution?

<p>Maximum amount of solute that can be dissolved in a solvent (C)</p> Signup and view all the answers

Which factor does NOT influence solubility according to the content?

<p>Color of the solvent (C)</p> Signup and view all the answers

What is the relationship between molality and mass of solvent?

<p>Molality is calculated as moles of solute per mass of solvent in kg (D)</p> Signup and view all the answers

If 75g of benzene is used, what is the relevant solute-solvent relationship described?

<p>Solute can be completely dissolved in the solvent (B)</p> Signup and view all the answers

What is the definition of solubility?

<p>The maximum amount of solute that can be dissolved in a solvent (D)</p> Signup and view all the answers

What is represented by the term 'molality' in the context of solutions?

<p>Moles of solute per kilogram of solvent (A)</p> Signup and view all the answers

Which statement about the factors affecting solubility is incorrect?

<p>Type of solute has no effect on solubility (A)</p> Signup and view all the answers

When calculating the molality of a solution, what piece of information is essential?

<p>Mass of solvent in kilograms (B)</p> Signup and view all the answers

Which of the following best describes the interaction in ideal solutions?

<p>A-B interactions are similar to A-A and B-B interactions. (C)</p> Signup and view all the answers

Which pair of substances represents a non-ideal solution due to differing interactions?

<p>Ethanol and water (C)</p> Signup and view all the answers

What effect does the difference in interaction strengths have on the vapor pressure of a solution?

<p>It affects vapor pressure of non-ideal solutions differently. (B)</p> Signup and view all the answers

In which scenario is it likely that a solution behaves ideally?

<p>When the components have similar molecular sizes and properties. (B)</p> Signup and view all the answers

What is a characteristic feature of non-ideal solutions based on molecular interactions?

<p>The interactions vary widely compared to ideal mixtures. (D)</p> Signup and view all the answers

What characterizes an unsaturated solution?

<p>More solute can be dissolved at the same temperature. (B)</p> Signup and view all the answers

What is the process called when solid solute particles collide and separate out of a solution?

<p>Crystallization (A)</p> Signup and view all the answers

Which statement about dynamic equilibrium is true?

<p>The number of solute particles going into and out of solution is equal. (D)</p> Signup and view all the answers

What happens during the dissolution process?

<p>Solid solute dissolves into the solvent. (C)</p> Signup and view all the answers

What is the primary factor that determines whether a solution is saturated or unsaturated?

<p>The temperature and pressure conditions. (D)</p> Signup and view all the answers

Which of the following statements about solute particles is correct?

<p>They will stop dissolving at a specific point in a saturated solution. (D)</p> Signup and view all the answers

What results from a saturated solution when additional solute is added?

<p>Excess solute remains undissolved. (B)</p> Signup and view all the answers

What occurs when a saturated solution reaches dynamic equilibrium?

<p>The amount of solute particles dissolving equals those crystallizing. (C)</p> Signup and view all the answers

Flashcards

Solution

A homogeneous mixture of two or more components. The component present in lesser amount is called solute and the component present in larger amount is called solvent.

Binary Solution

A solution made up of two components.

Ternary Solution

A solution made up of three components.

Quaternary Solution

A solution made up of four components.

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Aqueous Solution

A solution where water is present in excess.

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Non-Aqueous Solution

A solution where water is not present in excess.

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Mass Percentage

A method to express the concentration of a solution by calculating the ratio of the mass of a component to the total mass of the solution, multiplied by 100.

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Concentration

The concentration of a solution.

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Molality (m)

A measure of the concentration of a solute in a solution. It's defined as the moles of solute per kilogram of solvent.

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Density (d)

A measure of how much mass is contained in a given volume. It's defined as mass per unit volume.

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Molarity (M)

A measure of the concentration of a solute in a solution. It's defined as the moles of solute per liter of solution.

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Molar Mass (MM)

The mass of one mole of a substance. It's expressed in units of grams per mole (g/mol).

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Volume Conversion

Conversion of Units: 1 mL = 1 cm³

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Saturated Solution

A solution in which no more solute can be dissolved at a given temperature and pressure. It is a state of equilibrium where the rate of dissolution equals the rate of crystallization.

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Unsaturated Solution

A solution in which more solute can be dissolved at the same temperature and pressure.

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Dissolution

The process of dissolving a solid solute in a solvent to form a solution. The concentration of the solution increases as more solute dissolves.

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Crystallization

The process where solute particles in a solution collide with the solid solute and separate out of the solution, forming crystals. This happens when the solution becomes saturated or if the temperature is lowered.

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Dynamic Equilibrium

A state of dynamic equilibrium in a saturated solution where the rate of dissolution of solute particles equals the rate of crystallization of solute particles.

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Solubility

The amount of solute dissolved in a given amount of solvent at a specific temperature and pressure.

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Solubility (mass/mass)

The mass of solute dissolved in 100g of solvent.

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Solubility (mass/volume)

The mass of solute dissolved in 100mL of solvent.

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Molality

A measure of the concentration of a solution expressed as the number of moles of solute per kilogram of solvent.

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Mole

The unit used to measure the amount of a substance, equal to the molecular weight in grams.

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Molar Mass

The mass of one mole of a substance.

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Henry's Law

Henry's Law states that the solubility of a gas in a liquid is directly proportional to the partial pressure of the gas above the liquid. This means that the higher the partial pressure of the gas, the more soluble it will be.

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Henry's Law Constant (Kn)

A constant that relates the partial pressure of a gas to its solubility in a liquid at a given temperature. It is specific to each gas and solvent combination.

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Partial Pressure and Mole Fraction

The partial pressure of a gas above a liquid is directly proportional to the mole fraction of the gas in the liquid. This relationship is used to calculate the solubility of a gas in a liquid.

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Gas Dissolution

The process of a gas dissolving into a liquid. The solubility of a gas is influenced by factors such as temperature, pressure, and the nature of the gas and solvent.

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Raoult's Law

The total vapor pressure of a solution is determined by the partial pressures of its components. The vapor pressure of each component is proportional to its mole fraction in the solution. This relationship can be expressed by Raoult's Law, which states that the partial pressure of a component in an ideal solution is equal to the product of its mole fraction and its vapor pressure in the pure state.

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Ideal vs. Non-ideal Solutions

In an ideal solution, the interactions between the different components are the same as the interactions between the same components. In a non-ideal solution, the interactions between the different components are different from the interactions between the same components. This difference can affect the vapor pressure, boiling point, and other properties of the solution.

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Mole Fraction

The mole fraction of a component in a binary mixture is the ratio of the number of moles of that component to the total number of moles in the mixture.

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Vapor Pressure of Ideal Solutions

The total vapor pressure of an ideal solution is a linear function of the mole fraction of each component. This means that the vapor pressure of the solution will be directly proportional to the amount of each component present.

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Deviations from Raoult's Law

The deviation from Raoult's Law can be positive, negative, or both. Positive deviations occur when the interactions between the different components are weaker than the interactions between the same components, resulting in a higher vapor pressure than predicted by Raoult's Law. Negative deviations occur when the interactions between the different components are stronger than the interactions between the same components, resulting in a lower vapor pressure than predicted by Raoult's Law.

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Study Notes

Solutions

  • Solutions are homogeneous mixtures of two or more components
  • Solute is the component present in lesser amount
  • Solvent is the component present in larger amount
  • Binary solution has two components
  • Ternary solution has three components
  • Quaternary solution has four components
  • Aqueous solution: Water is the solvent
  • Non-aqueous solution: Water is not the solvent

Types of Solutions

  • Gaseous solutions: Gas in gas (e.g., mixture of oxygen and nitrogen gases)
  • Liquid solutions: Gas in liquid (e.g., oxygen dissolved in water), liquid in liquid (e.g., ethanol dissolved in water), solid in liquid (e.g., glucose dissolved in water)
  • Solid solutions: Gas in solid (e.g., hydrogen in palladium), liquid in solid (e.g., amalgam of mercury with sodium), solid in solid (e.g., copper dissolved in gold)

Methods for Expressing Concentrations

  • Mass percentage (w/w): (Mass of component / Mass of solution) x 100
  • Volume percentage (v/v): (Volume of component / Volume of solution) x 100
  • Mass by volume percentage (w/v): (Mass of solute / Volume of solution) x 100
  • Parts per million (ppm): (No. of parts of component / No. of parts in solution) x 106
  • Mole fraction (x): Ratio of moles of a component to the total moles of all components
  • Molarity (M): Number of moles of solute per liter of solution
  • Molality (m): Number of moles of solute per kilogram of solvent

Solubility

  • Solubility is the maximum amount of solute that can dissolve in a given amount of solvent at a specific temperature and pressure
  • Saturated solution: Contains the maximum amount of solute that can dissolve at a given temperature and pressure
  • Unsaturated solution: Contains less than the maximum amount of solute that can dissolve at a given temperature and pressure
  • Supersaturated solution: Contains more solute than is normally possible at a given temperature and pressure

Henry's Law

  • The solubility of a gas in a liquid is directly proportional to the partial pressure of the gas above the liquid
  • Higher partial pressure = higher solubility

Vapour Pressure of Liquid Solutions

  • Vapour pressure of a liquid is the pressure exerted by its vapours in equilibrium with the liquid
  • It depends on the nature of liquid, temperature, and concentration.
  • Raoult's Law for volatile liquids: The partial vapour pressure of each component in the solution is directly proportional to its mole fraction in the solution

Colligative Properties

  • Colligative properties depend only on the number of solute particles, not on their nature
  • Examples: Relative lowering in vapour pressure, elevation in boiling point, depression in freezing point, osmotic pressure

Elevation in Boiling Point

  • The boiling point of a solution containing a non-volatile solute is higher than the boiling point of the pure solvent
  • The difference in boiling points is termed elevation in boiling point (ΔTb)
  • ΔTb = Kb x m

Depression in Freezing Point

  • The freezing point of a solution containing a non-volatile solute is lower than the freezing point of the pure solvent
  • The difference in freezing points is termed depression in freezing point (ΔTf)
  • ΔTf = Kf x m

Osmotic Pressure

  • Osmosis is the spontaneous net movement of solvent molecules through a semipermeable membrane from a region of higher solvent concentration to a region of lower solvent concentration
  • Osmotic pressure is the pressure required to stop the flow of solvent across the semipermeable membrane
  • It is directly proportional to the molar concentration of the solution and the absolute temperature

Azeotropes

  • Azeotropes are constant boiling mixtures of two volatile liquids that have a constant composition in both the liquid and vapor phases
  • Minimum boiling azeotropes: Show a positive deviation from Raoult's law
  • Maximum boiling azeotropes: Show a negative deviation from Raoult's law

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