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Questions and Answers
What is the definition of molarity in terms of moles and volume?
What is the definition of molarity in terms of moles and volume?
- Molarity is the number of grams of solute per liter of solution.
- Molarity is the number of moles of solute divided by the mass of the solvent in grams.
- Molarity is the volume of solute divided by the number of moles in the solution.
- Molarity is the number of moles of solute divided by the volume of the solution in liters. (correct)
If 5g of NaOH is dissolved in 450 mL of water, what is required to calculate its molarity?
If 5g of NaOH is dissolved in 450 mL of water, what is required to calculate its molarity?
- The molar mass of NaOH. (correct)
- The total mass of the solvent.
- The boiling point of the solution.
- The density of the solution.
What would be the molarity of a solution containing 5g of NaOH in 450 mL?
What would be the molarity of a solution containing 5g of NaOH in 450 mL?
- 0.113 M
- 0.222 M
- 0.056 M
- 0.083 M (correct)
What is the unit of molality?
What is the unit of molality?
How can one describe the relationship between molarity and density?
How can one describe the relationship between molarity and density?
What is the equation that represents Henry's law in this context?
What is the equation that represents Henry's law in this context?
At what temperature is the solubility of methane in benzene being calculated?
At what temperature is the solubility of methane in benzene being calculated?
What is a solution primarily composed of?
What is a solution primarily composed of?
What is the value of the constant K_n given in the calculation?
What is the value of the constant K_n given in the calculation?
In a binary solution, how many components are present?
In a binary solution, how many components are present?
How is the solubility of methane calculated in this scenario?
How is the solubility of methane calculated in this scenario?
What is the approximate final result of the solubility calculation for methane in benzene?
What is the approximate final result of the solubility calculation for methane in benzene?
What characterizes an aqueous solution?
What characterizes an aqueous solution?
What type of solution is termed non-aqueous?
What type of solution is termed non-aqueous?
What does a ternary solution consist of?
What does a ternary solution consist of?
Mass percentage of a component in a solution is calculated by which formula?
Mass percentage of a component in a solution is calculated by which formula?
In the context of solutions, what is a solute?
In the context of solutions, what is a solute?
Which of the following describes a quaternary solution?
Which of the following describes a quaternary solution?
What is necessary for forming a saturated solution?
What is necessary for forming a saturated solution?
Which factor does NOT influence solubility according to the content?
Which factor does NOT influence solubility according to the content?
What is the relationship between molality and mass of solvent?
What is the relationship between molality and mass of solvent?
If 75g of benzene is used, what is the relevant solute-solvent relationship described?
If 75g of benzene is used, what is the relevant solute-solvent relationship described?
What is the definition of solubility?
What is the definition of solubility?
What is represented by the term 'molality' in the context of solutions?
What is represented by the term 'molality' in the context of solutions?
Which statement about the factors affecting solubility is incorrect?
Which statement about the factors affecting solubility is incorrect?
When calculating the molality of a solution, what piece of information is essential?
When calculating the molality of a solution, what piece of information is essential?
Which of the following best describes the interaction in ideal solutions?
Which of the following best describes the interaction in ideal solutions?
Which pair of substances represents a non-ideal solution due to differing interactions?
Which pair of substances represents a non-ideal solution due to differing interactions?
What effect does the difference in interaction strengths have on the vapor pressure of a solution?
What effect does the difference in interaction strengths have on the vapor pressure of a solution?
In which scenario is it likely that a solution behaves ideally?
In which scenario is it likely that a solution behaves ideally?
What is a characteristic feature of non-ideal solutions based on molecular interactions?
What is a characteristic feature of non-ideal solutions based on molecular interactions?
What characterizes an unsaturated solution?
What characterizes an unsaturated solution?
What is the process called when solid solute particles collide and separate out of a solution?
What is the process called when solid solute particles collide and separate out of a solution?
Which statement about dynamic equilibrium is true?
Which statement about dynamic equilibrium is true?
What happens during the dissolution process?
What happens during the dissolution process?
What is the primary factor that determines whether a solution is saturated or unsaturated?
What is the primary factor that determines whether a solution is saturated or unsaturated?
Which of the following statements about solute particles is correct?
Which of the following statements about solute particles is correct?
What results from a saturated solution when additional solute is added?
What results from a saturated solution when additional solute is added?
What occurs when a saturated solution reaches dynamic equilibrium?
What occurs when a saturated solution reaches dynamic equilibrium?
Flashcards
Solution
Solution
A homogeneous mixture of two or more components. The component present in lesser amount is called solute and the component present in larger amount is called solvent.
Binary Solution
Binary Solution
A solution made up of two components.
Ternary Solution
Ternary Solution
A solution made up of three components.
Quaternary Solution
Quaternary Solution
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Aqueous Solution
Aqueous Solution
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Non-Aqueous Solution
Non-Aqueous Solution
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Mass Percentage
Mass Percentage
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Concentration
Concentration
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Molality (m)
Molality (m)
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Density (d)
Density (d)
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Molarity (M)
Molarity (M)
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Molar Mass (MM)
Molar Mass (MM)
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Volume Conversion
Volume Conversion
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Saturated Solution
Saturated Solution
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Unsaturated Solution
Unsaturated Solution
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Dissolution
Dissolution
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Crystallization
Crystallization
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Dynamic Equilibrium
Dynamic Equilibrium
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Solubility
Solubility
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Solubility (mass/mass)
Solubility (mass/mass)
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Solubility (mass/volume)
Solubility (mass/volume)
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Molality
Molality
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Mole
Mole
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Molar Mass
Molar Mass
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Henry's Law
Henry's Law
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Henry's Law Constant (Kn)
Henry's Law Constant (Kn)
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Partial Pressure and Mole Fraction
Partial Pressure and Mole Fraction
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Gas Dissolution
Gas Dissolution
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Raoult's Law
Raoult's Law
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Ideal vs. Non-ideal Solutions
Ideal vs. Non-ideal Solutions
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Mole Fraction
Mole Fraction
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Vapor Pressure of Ideal Solutions
Vapor Pressure of Ideal Solutions
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Deviations from Raoult's Law
Deviations from Raoult's Law
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Study Notes
Solutions
- Solutions are homogeneous mixtures of two or more components
- Solute is the component present in lesser amount
- Solvent is the component present in larger amount
- Binary solution has two components
- Ternary solution has three components
- Quaternary solution has four components
- Aqueous solution: Water is the solvent
- Non-aqueous solution: Water is not the solvent
Types of Solutions
- Gaseous solutions: Gas in gas (e.g., mixture of oxygen and nitrogen gases)
- Liquid solutions: Gas in liquid (e.g., oxygen dissolved in water), liquid in liquid (e.g., ethanol dissolved in water), solid in liquid (e.g., glucose dissolved in water)
- Solid solutions: Gas in solid (e.g., hydrogen in palladium), liquid in solid (e.g., amalgam of mercury with sodium), solid in solid (e.g., copper dissolved in gold)
Methods for Expressing Concentrations
- Mass percentage (w/w): (Mass of component / Mass of solution) x 100
- Volume percentage (v/v): (Volume of component / Volume of solution) x 100
- Mass by volume percentage (w/v): (Mass of solute / Volume of solution) x 100
- Parts per million (ppm): (No. of parts of component / No. of parts in solution) x 106
- Mole fraction (x): Ratio of moles of a component to the total moles of all components
- Molarity (M): Number of moles of solute per liter of solution
- Molality (m): Number of moles of solute per kilogram of solvent
Solubility
- Solubility is the maximum amount of solute that can dissolve in a given amount of solvent at a specific temperature and pressure
- Saturated solution: Contains the maximum amount of solute that can dissolve at a given temperature and pressure
- Unsaturated solution: Contains less than the maximum amount of solute that can dissolve at a given temperature and pressure
- Supersaturated solution: Contains more solute than is normally possible at a given temperature and pressure
Henry's Law
- The solubility of a gas in a liquid is directly proportional to the partial pressure of the gas above the liquid
- Higher partial pressure = higher solubility
Vapour Pressure of Liquid Solutions
- Vapour pressure of a liquid is the pressure exerted by its vapours in equilibrium with the liquid
- It depends on the nature of liquid, temperature, and concentration.
- Raoult's Law for volatile liquids: The partial vapour pressure of each component in the solution is directly proportional to its mole fraction in the solution
Colligative Properties
- Colligative properties depend only on the number of solute particles, not on their nature
- Examples: Relative lowering in vapour pressure, elevation in boiling point, depression in freezing point, osmotic pressure
Elevation in Boiling Point
- The boiling point of a solution containing a non-volatile solute is higher than the boiling point of the pure solvent
- The difference in boiling points is termed elevation in boiling point (ΔTb)
- ΔTb = Kb x m
Depression in Freezing Point
- The freezing point of a solution containing a non-volatile solute is lower than the freezing point of the pure solvent
- The difference in freezing points is termed depression in freezing point (ΔTf)
- ΔTf = Kf x m
Osmotic Pressure
- Osmosis is the spontaneous net movement of solvent molecules through a semipermeable membrane from a region of higher solvent concentration to a region of lower solvent concentration
- Osmotic pressure is the pressure required to stop the flow of solvent across the semipermeable membrane
- It is directly proportional to the molar concentration of the solution and the absolute temperature
Azeotropes
- Azeotropes are constant boiling mixtures of two volatile liquids that have a constant composition in both the liquid and vapor phases
- Minimum boiling azeotropes: Show a positive deviation from Raoult's law
- Maximum boiling azeotropes: Show a negative deviation from Raoult's law
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