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Questions and Answers
What is the value of Avogadro's number?
What is the value of Avogadro's number?
- 6.022 x 10^24
- 6.022 x 10^23 (correct)
- 6.022 x 10^21
- 6.022 x 10^22
Which equation correctly expresses the relationship between energy and frequency?
Which equation correctly expresses the relationship between energy and frequency?
- E = c * λ
- E = m * v
- E = h * c
- E = h * f (correct)
At standard temperature and pressure (STP), what are the conditions of pressure and temperature?
At standard temperature and pressure (STP), what are the conditions of pressure and temperature?
- 1 atm and 0 °C (correct)
- 1 atm and 25 °C
- 0.5 atm and 0 °C
- 2 atm and 25 °C
What is the formula to calculate the molarity of a solution?
What is the formula to calculate the molarity of a solution?
According to the relationship between changes in internal energy, which of the following expressions is correct?
According to the relationship between changes in internal energy, which of the following expressions is correct?
What is the density (in g/L) of a gas with a molar mass of 60 g/mol at 0.75 atm and 27 °C?
What is the density (in g/L) of a gas with a molar mass of 60 g/mol at 0.75 atm and 27 °C?
If 2.00 g of element E reacts with 10.1 g of chlorine gas to form ECl4, what is the identity of element E?
If 2.00 g of element E reacts with 10.1 g of chlorine gas to form ECl4, what is the identity of element E?
What is the pressure of gas inside a plastic bag when 400.0 ml of gas at 5.2 atm is released into it and expands to 2.14 L?
What is the pressure of gas inside a plastic bag when 400.0 ml of gas at 5.2 atm is released into it and expands to 2.14 L?
What will happen to the pressure of a gas if the volume is reduced to 0.4 L and the temperature is increased to 533K?
What will happen to the pressure of a gas if the volume is reduced to 0.4 L and the temperature is increased to 533K?
Which ion among Al+, Al2+, Al3+, and Al4+ has the greatest electron affinity?
Which ion among Al+, Al2+, Al3+, and Al4+ has the greatest electron affinity?
If air in a tank is heated from 20°C to 250°C while maintaining a constant pressure of 1.0 atm, what will happen to the density of the air?
If air in a tank is heated from 20°C to 250°C while maintaining a constant pressure of 1.0 atm, what will happen to the density of the air?
What is the effect of reducing the volume of a gas on its pressure, according to Boyle's Law?
What is the effect of reducing the volume of a gas on its pressure, according to Boyle's Law?
For a gas at an initial temperature of 298K and pressure of 1 atm, if the temperature is raised without changing the volume, what happens?
For a gas at an initial temperature of 298K and pressure of 1 atm, if the temperature is raised without changing the volume, what happens?
What is the formula to calculate the change in enthalpy for a reaction?
What is the formula to calculate the change in enthalpy for a reaction?
According to the ideal gas law, what does PV=nRT represent?
According to the ideal gas law, what does PV=nRT represent?
Which of the following is a correct statement regarding solubility rules?
Which of the following is a correct statement regarding solubility rules?
What does Kp = Kc(RT)Δn signify?
What does Kp = Kc(RT)Δn signify?
Which formula correctly represents the density of a substance?
Which formula correctly represents the density of a substance?
What does the equation KEAVE = (3/2) RT represent?
What does the equation KEAVE = (3/2) RT represent?
In the context of van der Waals' equation, what do the variables 'a' and 'b' represent?
In the context of van der Waals' equation, what do the variables 'a' and 'b' represent?
What is the standard enthalpy of formation, Hof, for ethane gas, C2H4(g)?
What is the standard enthalpy of formation, Hof, for ethane gas, C2H4(g)?
How is the relationship between rates of two reactions different based on their molar masses represented?
How is the relationship between rates of two reactions different based on their molar masses represented?
Based on the percentages of elements, what is the empirical formula for a compound containing 55.2% Xenon and 44.8% chlorine?
Based on the percentages of elements, what is the empirical formula for a compound containing 55.2% Xenon and 44.8% chlorine?
Which of the following factors will increase the amount of water present in the stated reaction?
Which of the following factors will increase the amount of water present in the stated reaction?
How many cases will not shift under the given conditions?
How many cases will not shift under the given conditions?
What happens to the equilibrium of the reaction 2 SO2 (g) + O2 (g) ⇌ 2 SO3 (g) if the temperature is increased?
What happens to the equilibrium of the reaction 2 SO2 (g) + O2 (g) ⇌ 2 SO3 (g) if the temperature is increased?
What can be concluded about the K value for the dissociation of SO3 in a rigid container?
What can be concluded about the K value for the dissociation of SO3 in a rigid container?
Which substances only exhibit dispersion forces affecting their boiling points?
Which substances only exhibit dispersion forces affecting their boiling points?
Calculate the equilibrium constant, K, for the reaction 2SO3 (g) ⇌ 2SO2 (g) + O2 (g) when 3.0 mol of SO2 is present at equilibrium.
Calculate the equilibrium constant, K, for the reaction 2SO3 (g) ⇌ 2SO2 (g) + O2 (g) when 3.0 mol of SO2 is present at equilibrium.
Which statement about CF2H2 and CF2Cl2 is false?
Which statement about CF2H2 and CF2Cl2 is false?
Which orbital can hold the most electrons?
Which orbital can hold the most electrons?
Which statement is true regarding the effect of increasing the volume of the chamber on the reaction 2 SO2 (g) + O2 (g) ⇌ 2 SO3 (g)?
Which statement is true regarding the effect of increasing the volume of the chamber on the reaction 2 SO2 (g) + O2 (g) ⇌ 2 SO3 (g)?
If the amount of chlorine in the compound increases, what would logically happen to the empirical formula of the compound containing both Xenon and chlorine?
If the amount of chlorine in the compound increases, what would logically happen to the empirical formula of the compound containing both Xenon and chlorine?
How many different elements can have exactly 12 electrons in ‘s’ orbitals, 30 in ‘d’ orbitals, and two or more unpaired electrons?
How many different elements can have exactly 12 electrons in ‘s’ orbitals, 30 in ‘d’ orbitals, and two or more unpaired electrons?
What will be the new equilibrium concentration of HI if [H2] = 0.95 M and [I2] = 0.019 M?
What will be the new equilibrium concentration of HI if [H2] = 0.95 M and [I2] = 0.019 M?
Which of the following molecules has a tetrahedral shape?
Which of the following molecules has a tetrahedral shape?
Which of the following statements regarding SeF4 is correct?
Which of the following statements regarding SeF4 is correct?
What is the most likely value of ∆H for the reaction involving CS2 and Cl2?
What is the most likely value of ∆H for the reaction involving CS2 and Cl2?
Which metal ion is most likely to cause the formation of a white precipitate when MBr2 is reacted with Na2SO4?
Which metal ion is most likely to cause the formation of a white precipitate when MBr2 is reacted with Na2SO4?
How many grams of water are produced when 25 g of C7H16 is combusted, according to the combustion reaction?
How many grams of water are produced when 25 g of C7H16 is combusted, according to the combustion reaction?
In which gas sample will the molecules be moving the fastest at 298 K?
In which gas sample will the molecules be moving the fastest at 298 K?
For which reaction will Kp equal K?
For which reaction will Kp equal K?
What is the partial pressure of methane gas if the total pressure is 756 mm Hg and the vapor pressure of water is 41 mm Hg?
What is the partial pressure of methane gas if the total pressure is 756 mm Hg and the vapor pressure of water is 41 mm Hg?
If CH4 has an effusion rate of 9.0 mol per hour, which gas will effuse at approximately twice that rate?
If CH4 has an effusion rate of 9.0 mol per hour, which gas will effuse at approximately twice that rate?
Which of the following reactions involves a gas that will not affect equilibrium when liquids and solids are present?
Which of the following reactions involves a gas that will not affect equilibrium when liquids and solids are present?
Flashcards
Enthalpy Change (ΔH)
Enthalpy Change (ΔH)
A chemical reaction's enthalpy change is the heat change at constant pressure. It's the heat energy transferred between a system and its surroundings during a process at constant pressure.
Internal Energy Change (ΔU)
Internal Energy Change (ΔU)
The energy change of a system is the sum of the heat exchanged (q) and the work done (w) on or by the system.
Specific Heat (c)
Specific Heat (c)
The amount of heat required to raise the temperature of 1 gram of a substance by 1 degree Celsius.
Ideal Gas Law (PV=nRT)
Ideal Gas Law (PV=nRT)
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Percent Yield
Percent Yield
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Standard Enthalpy of Formation (ΔHf°)
Standard Enthalpy of Formation (ΔHf°)
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Enthalpy Change of Reaction (ΔHrxn)
Enthalpy Change of Reaction (ΔHrxn)
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Mole Fraction (χ)
Mole Fraction (χ)
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van der Waals Equation
van der Waals Equation
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Concentration and Reaction Rate
Concentration and Reaction Rate
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Temperature and Reaction Rate
Temperature and Reaction Rate
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Equilibrium Constant (Kc)
Equilibrium Constant (Kc)
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Gas Density Calculation
Gas Density Calculation
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Identifying Unknown Element
Identifying Unknown Element
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Pressure-Volume Relationship
Pressure-Volume Relationship
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Ionization Energy
Ionization Energy
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Electron Affinity
Electron Affinity
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Density of Gases
Density of Gases
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Carbon Tetrachloride Synthesis
Carbon Tetrachloride Synthesis
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Ideal Gas Law
Ideal Gas Law
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Standard Enthalpy of Reaction (ΔHrxn)
Standard Enthalpy of Reaction (ΔHrxn)
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Standard Enthalpy of Combustion
Standard Enthalpy of Combustion
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Sum of Oxidation Numbers
Sum of Oxidation Numbers
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Oxidation State of an Element
Oxidation State of an Element
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Oxidation State of Oxygen
Oxidation State of Oxygen
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Oxidation State of Hydrogen
Oxidation State of Hydrogen
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Hess's Law
Hess's Law
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Enthalpy of Formation (∆Hf°)
Enthalpy of Formation (∆Hf°)
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Heat Capacity (C)
Heat Capacity (C)
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Combustion Reaction
Combustion Reaction
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Molar Mass
Molar Mass
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Partial Pressure
Partial Pressure
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Graham's Law of Effusion
Graham's Law of Effusion
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Equilibrium
Equilibrium
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Reaction Rate
Reaction Rate
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Activation Energy (Ea)
Activation Energy (Ea)
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Catalyst
Catalyst
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Order of a Reaction
Order of a Reaction
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Rate-Determining Step
Rate-Determining Step
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Study Notes
Equations and Constants
- Avogadro's number (NA): 6.022 x 1023
- Speed of light (c): 2.998 x 108 m/s
- Planck's constant (h): 6.626 x 10-34 Js
- Energy (E) = hν
- Wavelength (λ) = h/mv
- Speed (c) = λν
- ΔE = -2.178 x 10-18 J
- Rydberg constant (RH): 2.178 x 10-18 J
- Energy level (En) = -RH(1/n2)
Density
- Density = mass/volume
- 1 J = 1 kg m2/s2
Percentage Yield
- % yield = (actual yield/theoretical yield) x 100
Molarity
- Molarity (M) = moles of solute/liters of solution
Heat Transfer
- qrxn = qsolution
- q = cmΔT
- c = specific heat capacity
- ΔT = change in temperature
Enthalpy Changes
- ΔU = q + w
- w = -PextΔV
- ΔH = ΔU + PΔV (at constant P)
- ΔHrxn = ΣnpΔHf°(products) – ΣnrΔHf°(reactants)
Rate Laws
- rate1/rate2= (M1/M2)3RT
- time1/time2 = (M1/M2)3RT
Ideal Gas Law
- PV = nRT
- R = 0.08206 L·atm/mol·K (8.314 J/mol·K)
Other Constants
- STP conditions: 1 atm and 0°C
- Ptotal = P1+P2 + P3+...
- Xi = (ni/Ntotal)
Other Equations
- Density = mass/volume
- PM=dRT (M=molar mass, d=density)
- KEave =(3/2) RT
- (P1V1/T1) = (P2V2/T2)
Solubility Rules
- Most nitrate (NO3-), acetate (CH3COO-), chlorate (ClO3-), and bicarbonate (HCO3-) salts are soluble.
- Most salts of alkali metals (group 1) and ammonium (NH4+) cations are soluble.
- Most chloride (Cl-), bromide (Br-), and iodide (I-) salts are soluble. Exceptions: salts containing Ag+, Pb2+, and Hg22+ ions are insoluble.
- Most sulfate (SO42-) salts are soluble. Exceptions: salts containing Ca2+, Sr2+, Ba2+, Pb2+, Hg22+, and Ag+ ions are insoluble.
- Most hydroxide (OH-) salts are insoluble. Exceptions: hydroxides containing alkali metals (group 1), ammonium (NH4+), Ba2+, Sr2+, and Ca2+ ions are soluble.
- Most sulfide (S2-), carbonate (CO32-), chromate (CrO42-), and phosphate (PO43-) salts are insoluble. Exceptions: salts of alkali metals (group 1) and ammonium (NH4+) cations are soluble.
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