Chemistry Quiz: Gas Laws and Molarity

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Questions and Answers

What is the value of Avogadro's number?

  • 6.022 x 10^24
  • 6.022 x 10^23 (correct)
  • 6.022 x 10^21
  • 6.022 x 10^22

Which equation correctly expresses the relationship between energy and frequency?

  • E = c * λ
  • E = m * v
  • E = h * c
  • E = h * f (correct)

At standard temperature and pressure (STP), what are the conditions of pressure and temperature?

  • 1 atm and 0 °C (correct)
  • 1 atm and 25 °C
  • 0.5 atm and 0 °C
  • 2 atm and 25 °C

What is the formula to calculate the molarity of a solution?

<p>M = moles of solute / liters of solution (A)</p> Signup and view all the answers

According to the relationship between changes in internal energy, which of the following expressions is correct?

<p>ΔU = q + w (D)</p> Signup and view all the answers

What is the density (in g/L) of a gas with a molar mass of 60 g/mol at 0.75 atm and 27 °C?

<p>1.09 g/L (B)</p> Signup and view all the answers

If 2.00 g of element E reacts with 10.1 g of chlorine gas to form ECl4, what is the identity of element E?

<p>Si (A)</p> Signup and view all the answers

What is the pressure of gas inside a plastic bag when 400.0 ml of gas at 5.2 atm is released into it and expands to 2.14 L?

<p>0.97 atm (C)</p> Signup and view all the answers

What will happen to the pressure of a gas if the volume is reduced to 0.4 L and the temperature is increased to 533K?

<p>Pressure will increase due to volume decrease and temperature increase. (B)</p> Signup and view all the answers

Which ion among Al+, Al2+, Al3+, and Al4+ has the greatest electron affinity?

<p>Al3+ (B)</p> Signup and view all the answers

If air in a tank is heated from 20°C to 250°C while maintaining a constant pressure of 1.0 atm, what will happen to the density of the air?

<p>Density will decrease (D)</p> Signup and view all the answers

What is the effect of reducing the volume of a gas on its pressure, according to Boyle's Law?

<p>Pressure increases with volume decrease. (B)</p> Signup and view all the answers

For a gas at an initial temperature of 298K and pressure of 1 atm, if the temperature is raised without changing the volume, what happens?

<p>Pressure will increase. (A)</p> Signup and view all the answers

What is the formula to calculate the change in enthalpy for a reaction?

<p>ΔHo = Σ np ΔHfo (products) - Σ nr ΔHfo (reactants) (C)</p> Signup and view all the answers

According to the ideal gas law, what does PV=nRT represent?

<p>The relationship between pressure, volume, number of moles, and absolute temperature. (B)</p> Signup and view all the answers

Which of the following is a correct statement regarding solubility rules?

<p>Most hydroxide salts are insoluble, except those containing alkali metals. (C)</p> Signup and view all the answers

What does Kp = Kc(RT)Δn signify?

<p>The relationship between pressure and concentration in ideal gas behavior. (A)</p> Signup and view all the answers

Which formula correctly represents the density of a substance?

<p>Density = mass/volume (C)</p> Signup and view all the answers

What does the equation KEAVE = (3/2) RT represent?

<p>The average kinetic energy of a monatomic ideal gas. (A)</p> Signup and view all the answers

In the context of van der Waals' equation, what do the variables 'a' and 'b' represent?

<p>Attractive forces between particles and volume excluded by particles, respectively. (C)</p> Signup and view all the answers

What is the standard enthalpy of formation, Hof, for ethane gas, C2H4(g)?

<p>-52.5 kJ/mol (B)</p> Signup and view all the answers

How is the relationship between rates of two reactions different based on their molar masses represented?

<p>rate 1/rate 2 = sqrt(M2/M1) (B)</p> Signup and view all the answers

Based on the percentages of elements, what is the empirical formula for a compound containing 55.2% Xenon and 44.8% chlorine?

<p>XeCl2 (D)</p> Signup and view all the answers

Which of the following factors will increase the amount of water present in the stated reaction?

<p>Amount of SiO2 increases (C), Amount of SiH4 increases (D)</p> Signup and view all the answers

How many cases will not shift under the given conditions?

<p>2 (B)</p> Signup and view all the answers

What happens to the equilibrium of the reaction 2 SO2 (g) + O2 (g) ⇌ 2 SO3 (g) if the temperature is increased?

<p>Equilibrium shifts to the left (D)</p> Signup and view all the answers

What can be concluded about the K value for the dissociation of SO3 in a rigid container?

<p>K changes with temperature (C)</p> Signup and view all the answers

Which substances only exhibit dispersion forces affecting their boiling points?

<p>I, III, and V (A)</p> Signup and view all the answers

Calculate the equilibrium constant, K, for the reaction 2SO3 (g) ⇌ 2SO2 (g) + O2 (g) when 3.0 mol of SO2 is present at equilibrium.

<p>0.33 (B)</p> Signup and view all the answers

Which statement about CF2H2 and CF2Cl2 is false?

<p>CF2H2 exhibits hydrogen bonding intermolecular forces. (C)</p> Signup and view all the answers

Which orbital can hold the most electrons?

<p>3f (C)</p> Signup and view all the answers

Which statement is true regarding the effect of increasing the volume of the chamber on the reaction 2 SO2 (g) + O2 (g) ⇌ 2 SO3 (g)?

<p>Equilibrium shifts to the left (B)</p> Signup and view all the answers

If the amount of chlorine in the compound increases, what would logically happen to the empirical formula of the compound containing both Xenon and chlorine?

<p>Empirical formula will require a revised ratio (C)</p> Signup and view all the answers

How many different elements can have exactly 12 electrons in ‘s’ orbitals, 30 in ‘d’ orbitals, and two or more unpaired electrons?

<p>0 (B)</p> Signup and view all the answers

What will be the new equilibrium concentration of HI if [H2] = 0.95 M and [I2] = 0.019 M?

<p>713 (D)</p> Signup and view all the answers

Which of the following molecules has a tetrahedral shape?

<p>SiF4 (A)</p> Signup and view all the answers

Which of the following statements regarding SeF4 is correct?

<p>It is a polar molecule. (D)</p> Signup and view all the answers

What is the most likely value of ∆H for the reaction involving CS2 and Cl2?

<p>– 461.8 kJ (D)</p> Signup and view all the answers

Which metal ion is most likely to cause the formation of a white precipitate when MBr2 is reacted with Na2SO4?

<p>Ba2+ (B)</p> Signup and view all the answers

How many grams of water are produced when 25 g of C7H16 is combusted, according to the combustion reaction?

<p>63 g (D)</p> Signup and view all the answers

In which gas sample will the molecules be moving the fastest at 298 K?

<p>H2 (A)</p> Signup and view all the answers

For which reaction will Kp equal K?

<p>III and IV (C)</p> Signup and view all the answers

What is the partial pressure of methane gas if the total pressure is 756 mm Hg and the vapor pressure of water is 41 mm Hg?

<p>715 mm Hg (B)</p> Signup and view all the answers

If CH4 has an effusion rate of 9.0 mol per hour, which gas will effuse at approximately twice that rate?

<p>He (D)</p> Signup and view all the answers

Which of the following reactions involves a gas that will not affect equilibrium when liquids and solids are present?

<p>CuO(s) + H2(g) ⇌ Cu(l) + H2O(g) (A)</p> Signup and view all the answers

Flashcards

Enthalpy Change (ΔH)

A chemical reaction's enthalpy change is the heat change at constant pressure. It's the heat energy transferred between a system and its surroundings during a process at constant pressure.

Internal Energy Change (ΔU)

The energy change of a system is the sum of the heat exchanged (q) and the work done (w) on or by the system.

Specific Heat (c)

The amount of heat required to raise the temperature of 1 gram of a substance by 1 degree Celsius.

Ideal Gas Law (PV=nRT)

The relationship between the pressure, volume, moles, and temperature of an ideal gas.

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Percent Yield

The ratio of the actual yield of a reaction to the theoretical yield, expressed as a percentage.

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Standard Enthalpy of Formation (ΔHf°)

The standard enthalpy change of formation (ΔHf°) is the enthalpy change when one mole of a compound is formed from its elements in their standard states under standard conditions (298 K and 1 atm).

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Enthalpy Change of Reaction (ΔHrxn)

The enthalpy change for a reaction (ΔHrxn) can be calculated using the standard enthalpy change of formation values of the reactants and products according to Hess's Law. It's the heat change for the reaction under standard conditions.

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Mole Fraction (χ)

The mole fraction of a component in a mixture is the ratio of the number of moles of that component to the total number of moles in the mixture. It represents the relative abundance of a component.

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van der Waals Equation

The van der Waals equation is a modified version of the ideal gas law that accounts for the intermolecular forces and the finite volume of gas molecules. It provides a more realistic description of real gases.

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Concentration and Reaction Rate

The rate of a reaction is influenced by the concentration of reactants. Increasing the concentration of reactants typically increases the reaction rate.

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Temperature and Reaction Rate

The rate of a reaction is influenced by the temperature. Increasing the temperature typically increases the reaction rate due to increased kinetic energy of molecules.

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Equilibrium Constant (Kc)

The Kc equilibrium constant relates the equilibrium concentrations of reactants and products in a reaction. It indicates the relative amounts of reactants and products at equilibrium.

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Gas Density Calculation

The density of a gas can be calculated using the Ideal Gas Law (PV = nRT) rearranged to solve for density (d = PM/RT).

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Identifying Unknown Element

The identity of an element can be determined by analyzing the mass ratio of the elements in a compound and using the formula's information to calculate its molar mass.

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Pressure-Volume Relationship

Boyle's Law (P₁V₁ = P₂V₂) states that the pressure and volume of a gas are inversely proportional at constant temperature. This means that as volume decreases, pressure increases.

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Ionization Energy

The ionization energy represents the energy required to remove an electron from a gaseous atom or ion. The greater the ionization energy, the more difficult it is to remove an electron (and thus, the less likely it is to form an anion - which gains an electron).

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Electron Affinity

Electron affinity is the change in energy when an electron is added to a gaseous atom or ion. A more negative electron affinity indicates a greater tendency for an atom to gain an electron.

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Density of Gases

Density is the amount of mass per unit volume. The density of a gas is affected by temperature - when heated, density decreases, and as the gas cools, density increases.

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Carbon Tetrachloride Synthesis

The reaction of chlorine with carbon disulfide produces carbon tetrachloride and sulfur. This reaction is exothermic, meaning it releases heat energy into the surroundings.

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Ideal Gas Law

The Ideal Gas Law describes the relationship between pressure, volume, temperature, and the number of moles of an ideal gas. It can be used to predict the behavior of gases under different conditions.

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Standard Enthalpy of Reaction (ΔHrxn)

The energy change associated with a chemical reaction under standard conditions (typically 298 K and 1 atm).

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Standard Enthalpy of Combustion

The enthalpy change that occurs during the complete combustion of one mole of a substance under standard conditions.

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Sum of Oxidation Numbers

The sum of the squares of the oxidation numbers of the elements in a compound must equal zero.

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Oxidation State of an Element

The oxidation state of an element in its elemental (uncombined) form is zero.

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Oxidation State of Oxygen

The oxidation state of oxygen in most compounds is -2.

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Oxidation State of Hydrogen

The oxidation state of hydrogen in most compounds is +1.

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Hess's Law

Hess's Law states that the enthalpy change for any overall reaction is the sum of the enthalpy changes for the individual steps involved in the reaction.

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Enthalpy of Formation (∆Hf°)

The enthalpy of formation (∆Hf°) is the enthalpy change that occurs when one mole of a substance is formed from its elements in their standard states. The standard state is the most stable form of the element at 298 K and 1 atm pressure.

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Heat Capacity (C)

The heat capacity (C) is the amount of heat energy required to raise the temperature of a substance by 1°C. It is a measure of how much energy a substance can store for a given temperature change.

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Combustion Reaction

A combustion reaction is a chemical reaction involving the rapid reaction between a substance with an oxidant, usually oxygen, to produce heat and light.

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Molar Mass

Molar mass is the mass of one mole of a substance. It is usually expressed in units of g/mol.

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Partial Pressure

The partial pressure of a gas in a mixture is the pressure that the gas would exert if it were the only gas present in the container.

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Graham's Law of Effusion

Graham's law states that the rate of effusion of a gas is inversely proportional to the square root of its molar mass. The lighter the gas, the faster it will effuse.

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Equilibrium

The condition where the forward and reverse reaction rates are equal, resulting in no net change in concentrations of reactants and products.

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Reaction Rate

The change in concentration of a reactant or product over a specific unit of time, describing how fast a reaction proceeds.

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Activation Energy (Ea)

The minimum energy required for a reaction to occur. Raising the temperature increases the number of molecules with enough energy to react.

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Catalyst

A substance that speeds up a reaction without being consumed in the process. It lowers the activation energy.

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Order of a Reaction

The sum of the exponents of the concentration terms in the rate law. Reflects the number of molecules that collide in the rate-determining step.

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Rate-Determining Step

A reaction that occurs in multiple steps with the slowest step determining the overall rate of the reaction.

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Study Notes

Equations and Constants

  • Avogadro's number (NA): 6.022 x 1023
  • Speed of light (c): 2.998 x 108 m/s
  • Planck's constant (h): 6.626 x 10-34 Js
  • Energy (E) = hν
  • Wavelength (λ) = h/mv
  • Speed (c) = λν
  • ΔE = -2.178 x 10-18 J
  • Rydberg constant (RH): 2.178 x 10-18 J
  • Energy level (En) = -RH(1/n2)

Density

  • Density = mass/volume
  • 1 J = 1 kg m2/s2

Percentage Yield

  • % yield = (actual yield/theoretical yield) x 100

Molarity

  • Molarity (M) = moles of solute/liters of solution

Heat Transfer

  • qrxn = qsolution
  • q = cmΔT
  • c = specific heat capacity
  • ΔT = change in temperature

Enthalpy Changes

  • ΔU = q + w
  • w = -PextΔV
  • ΔH = ΔU + PΔV (at constant P)
  • ΔHrxn = ΣnpΔHf°(products) – ΣnrΔHf°(reactants)

Rate Laws

  • rate1/rate2= (M1/M2)3RT
  • time1/time2 = (M1/M2)3RT

Ideal Gas Law

  • PV = nRT
  • R = 0.08206 L·atm/mol·K (8.314 J/mol·K)

Other Constants

  • STP conditions: 1 atm and 0°C
  • Ptotal = P1+P2 + P3+...
  • Xi = (ni/Ntotal)

Other Equations

  • Density = mass/volume
  • PM=dRT (M=molar mass, d=density)
  • KEave =(3/2) RT
  • (P1V1/T1) = (P2V2/T2)

Solubility Rules

  • Most nitrate (NO3-), acetate (CH3COO-), chlorate (ClO3-), and bicarbonate (HCO3-) salts are soluble.
  • Most salts of alkali metals (group 1) and ammonium (NH4+) cations are soluble.
  • Most chloride (Cl-), bromide (Br-), and iodide (I-) salts are soluble. Exceptions: salts containing Ag+, Pb2+, and Hg22+ ions are insoluble.
  • Most sulfate (SO42-) salts are soluble. Exceptions: salts containing Ca2+, Sr2+, Ba2+, Pb2+, Hg22+, and Ag+ ions are insoluble.
  • Most hydroxide (OH-) salts are insoluble. Exceptions: hydroxides containing alkali metals (group 1), ammonium (NH4+), Ba2+, Sr2+, and Ca2+ ions are soluble.
  • Most sulfide (S2-), carbonate (CO32-), chromate (CrO42-), and phosphate (PO43-) salts are insoluble. Exceptions: salts of alkali metals (group 1) and ammonium (NH4+) cations are soluble.

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