Chemistry Quiz: Electron Energy Levels
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Questions and Answers

What occurs when an electron absorbs enough energy to promote itself to a higher energy level?

  • Chemical bonding
  • Electromagnetic radiation
  • Ionisation
  • Excitation (correct)
  • What is the result of ionisation in atoms?

  • The atom gains additional electrons
  • The atom's outer electron level becomes filled
  • The atom remains neutral
  • The atom loses an electron, resulting in a positive charge (correct)
  • What property controls the chemical behavior of an element?

  • Electron configuration (correct)
  • Atomic mass
  • Electromagnetic radiation frequency
  • Ionisation energy
  • What happens to an atom after it returns from an excited state to its ground state?

    <p>It emits energy in some form</p> Signup and view all the answers

    Which of the following statements about atoms with filled outer electron levels is true?

    <p>They are chemically inert</p> Signup and view all the answers

    What is considered the fundamental building block of matter?

    <p>Atom</p> Signup and view all the answers

    Which scientist is known for developing the first Atomic Theory of Matter?

    <p>John Dalton</p> Signup and view all the answers

    What did John Joseph Thomson discover in 1897?

    <p>Electrons</p> Signup and view all the answers

    What charge did Eugen Goldstein conclude that canal rays possess?

    <p>Positive charge</p> Signup and view all the answers

    Which model of the atom is commonly used to explain phenomena in radiography?

    <p>Planetary model</p> Signup and view all the answers

    What does the Greek word from which 'atom' is derived mean?

    <p>Indivisible</p> Signup and view all the answers

    What is the primary focus of atomic and subatomic structure theories?

    <p>Explaining matter composition</p> Signup and view all the answers

    What characteristic did John Dalton say all atoms of a given element share?

    <p>Same atomic weight</p> Signup and view all the answers

    What does the atomic number (Z) represent in an atom?

    <p>Number of protons in the nucleus</p> Signup and view all the answers

    What is the atomic mass number (A) of an atom?

    <p>Sum of protons and neutrons</p> Signup and view all the answers

    Which of the following statements about nuclides is true?

    <p>Isotopes of an element have the same number of protons.</p> Signup and view all the answers

    How are isotopes of carbon represented?

    <p>By changing the number of neutrons while keeping protons constant</p> Signup and view all the answers

    What charge do neutrons carry in an atomic nucleus?

    <p>Neutral</p> Signup and view all the answers

    What remains constant among all nuclides of a specific element?

    <p>Atomic number</p> Signup and view all the answers

    Which of the following statements about protons is accurate?

    <p>They carry a positive charge.</p> Signup and view all the answers

    What does a higher atomic mass number indicate about an element?

    <p>It contains more particles in the nucleus.</p> Signup and view all the answers

    What is the maximum number of electrons that can occupy the second shell (n=2)?

    <p>8</p> Signup and view all the answers

    Which statement best describes electron binding energy?

    <p>It is the energy required to remove an electron from an atom.</p> Signup and view all the answers

    According to the Pauli’s exclusion principle, what restriction is placed on electrons in an atom?

    <p>No two electrons can occupy the same quantum state simultaneously.</p> Signup and view all the answers

    Which of the following correctly explains a factor affecting electron binding energy?

    <p>Greater distance from the nucleus decreases binding energy.</p> Signup and view all the answers

    If n=3, what is the maximum number of electrons that can occupy this shell?

    <p>18</p> Signup and view all the answers

    What is the relationship between atomic number and electron binding energy?

    <p>Increased atomic number increases binding energy.</p> Signup and view all the answers

    What is the unit used to express binding energy of electrons?

    <p>Electron volts</p> Signup and view all the answers

    Which shell can have a maximum of 32 electrons?

    <p>Fourth shell</p> Signup and view all the answers

    What is the primary feature of the atom according to Rutherford's conclusions?

    <p>It has a central positively charged nucleus.</p> Signup and view all the answers

    Which statement describes the main aspect of the Bohr model?

    <p>Electrons orbit the nucleus at discrete energy levels.</p> Signup and view all the answers

    What was James Chadwick's significant discovery in 1932?

    <p>The neutron.</p> Signup and view all the answers

    What distinguishes the planetary model from the quantum model?

    <p>The planetary model describes electrons as orbiting like planets.</p> Signup and view all the answers

    How does the mass and charge of the atomic nucleus relate to its subatomic particles?

    <p>Both protons and neutrons determine the mass and charge.</p> Signup and view all the answers

    What is the approximate diameter of the outermost shell of atoms?

    <p>$1 imes 10^{-10}$ to $3 imes 10^{-10}$ metres.</p> Signup and view all the answers

    Which particle in the atomic structure has a rest mass of approximately $1.675 imes 10^{-27}$ kg?

    <p>Neutron</p> Signup and view all the answers

    What is characteristic of the atomic nucleus regarding its structure?

    <p>It is a dense structure containing protons and neutrons.</p> Signup and view all the answers

    What type of bond is formed when sodium donates an electron to chlorine?

    <p>Ionic bond</p> Signup and view all the answers

    Which of the following statements is true regarding covalent bonding?

    <p>It occurs when atoms share electrons.</p> Signup and view all the answers

    What characteristic is NOT associated with noble gases?

    <p>High reactivity</p> Signup and view all the answers

    Which of the following is an example of a crystalline compound?

    <p>Caesium iodide (CsI)</p> Signup and view all the answers

    What is one of the properties of metals?

    <p>They are lustrous and malleable.</p> Signup and view all the answers

    Which molecule is a diatomic element?

    <p>Oxygen (O2)</p> Signup and view all the answers

    Which of the following statements correctly describes the structure of carbon?

    <p>Carbon can form extensive covalently bound structures.</p> Signup and view all the answers

    What happens during the formation of positive and negative ions?

    <p>Atoms either donate or accept electrons.</p> Signup and view all the answers

    Study Notes

    Fundamentals of Radiation & Radiation Safety Lecture D

    • Subject: Atomic Physics
    • Lecturer: Ciara Mc Nally
    • Topic: Fundamentals of Radiation

    Atoms and Matter

    • The lecture begins with a fundamental question: What is matter made of?
    • The atom is the fundamental building block of matter, but modern atomic and subatomic theories are complex.
    • Radiography phenomena are often explained using a simplified planetary model of the atom.

    Atomic Theory

    • 400 BC – Concept of Particles: The idea that everything is made of tiny particles originated.
    • John Dalton (1766-1844): Dalton developed the first atomic theory of matter, proposing that elements are composed of tiny indestructible particles, atoms. Each element's atoms are identical and have the same atomic weight.
    • John Joseph Thomson (1856-1940): Discovered the electron in 1897, following research on cathode rays.
    • Eugen Goldstein (1850-1930): Experimented with cathode ray tubes. Discovered canal rays, which have the opposite charge of cathode rays.
    • Ernest Rutherford (1871-1937): Proposed that the atom is mostly empty space with a tiny, positively charged nucleus. Negatively charged electrons orbit at a distance from the nucleus.
    • Niels Bohr (1884-1962): Collaborated with Rutherford. Developed a model showing electrons orbiting the nucleus at specific energy levels, called shells or orbits.
    • James Chadwick (1932): Discovered the neutron, a neutral subatomic particle that helps reduce proton repulsion within the nucleus.

    Subatomic Particle Properties

    • The atomic nucleus is small and dense, containing protons and neutrons.
      • Nuclear sizes vary between 10-15 and 10-14 meters.
      • Outermost electron shell diameters vary between 1 x 10-10 and 3 x 10-10 meters
    • Proton properties:
      • Rest mass: 1.672 x 10-27 kg, 1.007 amu
      • Rest mass energy: 938 MeV
      • Electric charge: +1
    • Neutron properties:
      • Rest mass: 1.675 x 10-27 kg, 1.009 amu
      • Rest mass energy: 939 MeV
      • Electric charge: 0
    • Electron properties:
      • Rest mass: 9.109 x 10-31 kg, 0.00055 amu
      • Rest mass energy: 0.511 MeV
      • Electric charge: -1

    The Atomic Nucleus

    • The number of protons and neutrons in the nucleus determines the atom's mass and charge, and electron orbital configuration of an element.
    • Atomic mass number (A): The total number of protons and neutrons in the nucleus.
    • Atomic number (Z): The number of protons in the nucleus.

    Nuclides/Isotopes

    • A nuclide is an atom characterized by a specific number of neutrons in the nucleus.
    • Isotopes of an element share the same atomic number (number of protons) but differ in the number of neutrons.
    • Examples of carbon isotopes: 12C, 13C, 14C

    The Stability of the Nucleus

    • The nucleus contains positively charged protons and neutral neutrons.
    • Electrostatic repulsion between protons is countered by the strong nuclear force, which acts over a short range.
    • The energy needed to keep the nucleus intact is called the nuclear binding energy.

    Electron Orbitals

    • Electrons are found in specific orbitals or shells around the nucleus.
    • The number of electrons in a stable atom equals the number of protons. Atoms are neutral electrically.
    • Electrons fill inner shells first, these are at lower energy levels.
    • The quantum mechanical model describes electron behaviour as particles and waves and the probability of locating an electron in space.
    • Cannot predict precise spatial location of an electron

    Electronic Energy Levels, Electron Binding Energy and Electron Configuration

    • The further away from the nucleus, the smaller the binding energy.
    • An electron's energy levels are discrete.
    • The number of electrons each shell can hold is given by the formula: 2n2 , where n is the shell number.
      • Shell 1 (K): 2 electrons, Shell 2 (L): 8 electrons, Shell 3 (M): 18 electrons, Shell 4 (N): 32 electrons
    • Increase in atomic number = increased electron binding energy
    • Increase in distance between nucleus and electron = decreased electron binding energy.

    The Periodic Table and Electron Excitation / Ionisation

    • The periodic table organizes elements based on atomic number and recurring properties. The periodic table organizes elements by valency and physical properties, determined by electronic configuration.
    • Electron excitation: An electron can gain sufficient energy to move to a higher energy level (shell).
    • Ionisation: An electron can gain sufficient energy to escape from the atom completely. This leaves a net positive charge.

    Chemical Bonding

    • Ionic bonding: Atoms with nearly full or empty outer electron shells tend to transfer electrons to become ions (positive or negative). The oppositely charged ions attract, forming an ionic bond.
    • Covalent bonding: Atoms with half-full outer shells rather share electrons (covalently) to achieve a full outer shell
    • Molecular compounds: Atoms from different elements bond in fixed ratios to create a compound.
    • Other matter types: Crystalline compounds (e.g., Caesium Iodide (CsI)) and single-element materials (e.g., carbon, silicon). The arrangement of atoms affects the material's properties. Noble gases have filled outer shells resulting in inert (non-reactive) behaviour. Metals have delocalized electrons and form metallic bonds. The state of matter depends on the strength of intermolecular forces (gasses, liquids, solids).

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