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Questions and Answers
What occurs when an electron absorbs enough energy to promote itself to a higher energy level?
What occurs when an electron absorbs enough energy to promote itself to a higher energy level?
What is the result of ionisation in atoms?
What is the result of ionisation in atoms?
What property controls the chemical behavior of an element?
What property controls the chemical behavior of an element?
What happens to an atom after it returns from an excited state to its ground state?
What happens to an atom after it returns from an excited state to its ground state?
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Which of the following statements about atoms with filled outer electron levels is true?
Which of the following statements about atoms with filled outer electron levels is true?
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What is considered the fundamental building block of matter?
What is considered the fundamental building block of matter?
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Which scientist is known for developing the first Atomic Theory of Matter?
Which scientist is known for developing the first Atomic Theory of Matter?
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What did John Joseph Thomson discover in 1897?
What did John Joseph Thomson discover in 1897?
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What charge did Eugen Goldstein conclude that canal rays possess?
What charge did Eugen Goldstein conclude that canal rays possess?
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Which model of the atom is commonly used to explain phenomena in radiography?
Which model of the atom is commonly used to explain phenomena in radiography?
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What does the Greek word from which 'atom' is derived mean?
What does the Greek word from which 'atom' is derived mean?
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What is the primary focus of atomic and subatomic structure theories?
What is the primary focus of atomic and subatomic structure theories?
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What characteristic did John Dalton say all atoms of a given element share?
What characteristic did John Dalton say all atoms of a given element share?
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What does the atomic number (Z) represent in an atom?
What does the atomic number (Z) represent in an atom?
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What is the atomic mass number (A) of an atom?
What is the atomic mass number (A) of an atom?
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Which of the following statements about nuclides is true?
Which of the following statements about nuclides is true?
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How are isotopes of carbon represented?
How are isotopes of carbon represented?
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What charge do neutrons carry in an atomic nucleus?
What charge do neutrons carry in an atomic nucleus?
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What remains constant among all nuclides of a specific element?
What remains constant among all nuclides of a specific element?
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Which of the following statements about protons is accurate?
Which of the following statements about protons is accurate?
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What does a higher atomic mass number indicate about an element?
What does a higher atomic mass number indicate about an element?
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What is the maximum number of electrons that can occupy the second shell (n=2)?
What is the maximum number of electrons that can occupy the second shell (n=2)?
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Which statement best describes electron binding energy?
Which statement best describes electron binding energy?
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According to the Pauli’s exclusion principle, what restriction is placed on electrons in an atom?
According to the Pauli’s exclusion principle, what restriction is placed on electrons in an atom?
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Which of the following correctly explains a factor affecting electron binding energy?
Which of the following correctly explains a factor affecting electron binding energy?
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If n=3, what is the maximum number of electrons that can occupy this shell?
If n=3, what is the maximum number of electrons that can occupy this shell?
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What is the relationship between atomic number and electron binding energy?
What is the relationship between atomic number and electron binding energy?
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What is the unit used to express binding energy of electrons?
What is the unit used to express binding energy of electrons?
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Which shell can have a maximum of 32 electrons?
Which shell can have a maximum of 32 electrons?
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What is the primary feature of the atom according to Rutherford's conclusions?
What is the primary feature of the atom according to Rutherford's conclusions?
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Which statement describes the main aspect of the Bohr model?
Which statement describes the main aspect of the Bohr model?
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What was James Chadwick's significant discovery in 1932?
What was James Chadwick's significant discovery in 1932?
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What distinguishes the planetary model from the quantum model?
What distinguishes the planetary model from the quantum model?
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How does the mass and charge of the atomic nucleus relate to its subatomic particles?
How does the mass and charge of the atomic nucleus relate to its subatomic particles?
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What is the approximate diameter of the outermost shell of atoms?
What is the approximate diameter of the outermost shell of atoms?
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Which particle in the atomic structure has a rest mass of approximately $1.675 imes 10^{-27}$ kg?
Which particle in the atomic structure has a rest mass of approximately $1.675 imes 10^{-27}$ kg?
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What is characteristic of the atomic nucleus regarding its structure?
What is characteristic of the atomic nucleus regarding its structure?
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What type of bond is formed when sodium donates an electron to chlorine?
What type of bond is formed when sodium donates an electron to chlorine?
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Which of the following statements is true regarding covalent bonding?
Which of the following statements is true regarding covalent bonding?
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What characteristic is NOT associated with noble gases?
What characteristic is NOT associated with noble gases?
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Which of the following is an example of a crystalline compound?
Which of the following is an example of a crystalline compound?
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What is one of the properties of metals?
What is one of the properties of metals?
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Which molecule is a diatomic element?
Which molecule is a diatomic element?
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Which of the following statements correctly describes the structure of carbon?
Which of the following statements correctly describes the structure of carbon?
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What happens during the formation of positive and negative ions?
What happens during the formation of positive and negative ions?
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Study Notes
Fundamentals of Radiation & Radiation Safety Lecture D
- Subject: Atomic Physics
- Lecturer: Ciara Mc Nally
- Topic: Fundamentals of Radiation
Atoms and Matter
- The lecture begins with a fundamental question: What is matter made of?
- The atom is the fundamental building block of matter, but modern atomic and subatomic theories are complex.
- Radiography phenomena are often explained using a simplified planetary model of the atom.
Atomic Theory
- 400 BC – Concept of Particles: The idea that everything is made of tiny particles originated.
- John Dalton (1766-1844): Dalton developed the first atomic theory of matter, proposing that elements are composed of tiny indestructible particles, atoms. Each element's atoms are identical and have the same atomic weight.
- John Joseph Thomson (1856-1940): Discovered the electron in 1897, following research on cathode rays.
- Eugen Goldstein (1850-1930): Experimented with cathode ray tubes. Discovered canal rays, which have the opposite charge of cathode rays.
- Ernest Rutherford (1871-1937): Proposed that the atom is mostly empty space with a tiny, positively charged nucleus. Negatively charged electrons orbit at a distance from the nucleus.
- Niels Bohr (1884-1962): Collaborated with Rutherford. Developed a model showing electrons orbiting the nucleus at specific energy levels, called shells or orbits.
- James Chadwick (1932): Discovered the neutron, a neutral subatomic particle that helps reduce proton repulsion within the nucleus.
Subatomic Particle Properties
- The atomic nucleus is small and dense, containing protons and neutrons.
- Nuclear sizes vary between 10-15 and 10-14 meters.
- Outermost electron shell diameters vary between 1 x 10-10 and 3 x 10-10 meters
- Proton properties:
- Rest mass: 1.672 x 10-27 kg, 1.007 amu
- Rest mass energy: 938 MeV
- Electric charge: +1
- Neutron properties:
- Rest mass: 1.675 x 10-27 kg, 1.009 amu
- Rest mass energy: 939 MeV
- Electric charge: 0
- Electron properties:
- Rest mass: 9.109 x 10-31 kg, 0.00055 amu
- Rest mass energy: 0.511 MeV
- Electric charge: -1
The Atomic Nucleus
- The number of protons and neutrons in the nucleus determines the atom's mass and charge, and electron orbital configuration of an element.
- Atomic mass number (A): The total number of protons and neutrons in the nucleus.
- Atomic number (Z): The number of protons in the nucleus.
Nuclides/Isotopes
- A nuclide is an atom characterized by a specific number of neutrons in the nucleus.
- Isotopes of an element share the same atomic number (number of protons) but differ in the number of neutrons.
- Examples of carbon isotopes: 12C, 13C, 14C
The Stability of the Nucleus
- The nucleus contains positively charged protons and neutral neutrons.
- Electrostatic repulsion between protons is countered by the strong nuclear force, which acts over a short range.
- The energy needed to keep the nucleus intact is called the nuclear binding energy.
Electron Orbitals
- Electrons are found in specific orbitals or shells around the nucleus.
- The number of electrons in a stable atom equals the number of protons. Atoms are neutral electrically.
- Electrons fill inner shells first, these are at lower energy levels.
- The quantum mechanical model describes electron behaviour as particles and waves and the probability of locating an electron in space.
- Cannot predict precise spatial location of an electron
Electronic Energy Levels, Electron Binding Energy and Electron Configuration
- The further away from the nucleus, the smaller the binding energy.
- An electron's energy levels are discrete.
- The number of electrons each shell can hold is given by the formula: 2n2 , where n is the shell number.
- Shell 1 (K): 2 electrons, Shell 2 (L): 8 electrons, Shell 3 (M): 18 electrons, Shell 4 (N): 32 electrons
- Increase in atomic number = increased electron binding energy
- Increase in distance between nucleus and electron = decreased electron binding energy.
The Periodic Table and Electron Excitation / Ionisation
- The periodic table organizes elements based on atomic number and recurring properties. The periodic table organizes elements by valency and physical properties, determined by electronic configuration.
- Electron excitation: An electron can gain sufficient energy to move to a higher energy level (shell).
- Ionisation: An electron can gain sufficient energy to escape from the atom completely. This leaves a net positive charge.
Chemical Bonding
- Ionic bonding: Atoms with nearly full or empty outer electron shells tend to transfer electrons to become ions (positive or negative). The oppositely charged ions attract, forming an ionic bond.
- Covalent bonding: Atoms with half-full outer shells rather share electrons (covalently) to achieve a full outer shell
- Molecular compounds: Atoms from different elements bond in fixed ratios to create a compound.
- Other matter types: Crystalline compounds (e.g., Caesium Iodide (CsI)) and single-element materials (e.g., carbon, silicon). The arrangement of atoms affects the material's properties. Noble gases have filled outer shells resulting in inert (non-reactive) behaviour. Metals have delocalized electrons and form metallic bonds. The state of matter depends on the strength of intermolecular forces (gasses, liquids, solids).
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Test your knowledge on atomic structure and electron behavior in this chemistry quiz. Explore concepts such as energy absorption, ionization, and the properties that influence chemical behavior. Understand what happens when atoms transition between excited and ground states.