Chemistry of Neo-abietic Acid
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Questions and Answers

Which of the following is NOT a use of abietic acid?

  • Stimulant and diuretic
  • Flavoring agent in food (correct)
  • Component of varnishes
  • Ingredient of ointments

What acid is formed from pimaric acid through the effect of heat?

  • Abietic acid (correct)
  • Neo-abietic acid
  • L-Pimaric acid
  • Turpentine acid

Which of the following substances is directly related to the test for identity of abietic acid?

  • Colophony and petroleum ether (correct)
  • L-Pimaric acid and ethanol
  • Neo-abietic acid and chloroform
  • Turpentine and water

What is the process involved in the transformation of pimaric acid into abietic acid?

<p>Distillation (D)</p> Signup and view all the answers

Which of the following uses qualifies abietic acid as a stimulant and diuretic?

<p>Medicinal ointments (B)</p> Signup and view all the answers

What is the first step in the test for combined umbelliferone?

<p>Boil 1g Asafoetida with 20 ml of HCl and water. (C)</p> Signup and view all the answers

What type of surface is tested for identity?

<p>Freshly fractured surface of the tear (D)</p> Signup and view all the answers

What color fluorescence indicates a positive test for combined umbelliferone?

<p>Blue fluorescence (D)</p> Signup and view all the answers

After boiling and filtering, into what type of solution must the filtrate be added?

<p>Strongly alkaline solution (A)</p> Signup and view all the answers

Which chemical reaction occurs in the test for combined umbelliferone?

<p>Formation of a mixture with acid and alkali (D)</p> Signup and view all the answers

What are the primary components of juices as described?

<p>Aqueous liquids with dissolved substances (B)</p> Signup and view all the answers

In which parts of plants can juices be found?

<p>In cells or cavities (A)</p> Signup and view all the answers

Which plant is cited as having juices occurring in cells?

<p>Aloes (C)</p> Signup and view all the answers

Which of the following statements about juices is NOT accurate?

<p>Juices are typically solid substances. (D)</p> Signup and view all the answers

What structural feature of juices allows them to be present in Eucalyptus?

<p>Cavities (C)</p> Signup and view all the answers

What type of action does this substance have on mucous membranes?

<p>Antiseptic and astringent (A)</p> Signup and view all the answers

Which properties are reported to be associated with the sesquiterpenes present in this substance?

<p>Antibacterial and antifungal (B)</p> Signup and view all the answers

In addition to its use in perfumes, how else can this substance be utilized?

<p>In mouth washes and gargles (C)</p> Signup and view all the answers

Which of the following statements is FALSE regarding the properties of this substance?

<p>It can be harmful to mucous membranes. (B)</p> Signup and view all the answers

What is a notable characteristic of sesquiterpenes found in this substance?

<p>They are reported to have antibacterial and antifungal properties. (A)</p> Signup and view all the answers

What is the solubility of Aloes in water?

<p>Partially soluble (A)</p> Signup and view all the answers

Which of the following solvents is Aloes insoluble in?

<p>Ether (C)</p> Signup and view all the answers

What is the primary constituent of all varieties of Aloes?

<p>Barbaloin (D)</p> Signup and view all the answers

Which of the following is an anthraquinone derived from barbaloin?

<p>Aloe-emodin (A)</p> Signup and view all the answers

Which statement is true regarding the solubility of Aloes?

<p>It is insoluble in ether but partially soluble in water. (A)</p> Signup and view all the answers

Study Notes

Formation and Uses of Acids

  • Heat transforms pimaric acid from natural turpentine into abietic acid and neo-abietic acid.
  • Abietic acid is key in varnishes, printing inks, floor coverings, and as an ingredient in ointments.
  • Neo-abietic acid is involved in similar applications.

Identity Tests

  • To test for abietic acid: Mix 0.5 g of colophony with 5 ml of petroleum ether, shake, filter, then dilute with an equal volume of deionized water.
  • Freshly fractured surfaces of the tear serve as an effective identity test for abietic acid.
  • For combined umbelliferone: Boil 1 g of Asafoetida with 20 ml of HCl and water, filter, then add to strongly alkaline water with NH4OH to observe blue fluorescence.

Applications of Umbelliferone

  • Umbelliferone has antiseptic and astringent properties suitable for use in mouthwashes and gargles.
  • Its sesquiterpenes exhibit antibacterial and antifungal qualities, enhancing its utility in healthcare products.

Dried Juices

  • Juices are aqueous plant saps containing dissolved substances, occurring in cells (e.g., Aloes) or cavities (e.g., Eucalyptus).
  • Dried juices demonstrate partial solubility in water, but are insoluble in ether, petroleum ether, or chloroform.

Constituents of Aloes

  • The primary component of all Aloe varieties is barbaloin, a yellow crystalline anthraquinone glycoside.
  • Additional constituents include resin and aloe-emodin, which is a hydrolytic decomposition product of barbaloin.

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Explore the formation and uses of neo-abietic acid in this quiz. Understand how heat and pimaric acid contribute to its properties, as well as its applications in varnishes, printing inks, and more. Test your knowledge on this fascinating topic in chemistry.

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