Chemistry: Molecular Shape and Electron Pair Theory

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Questions and Answers

In a trigonal planar molecule, how many atoms are typically present?

  • 3 atoms
  • 4 atoms (correct)
  • 5 atoms
  • 6 atoms

What angle is formed between atoms in a tetrahedral molecule?

  • 107 degrees
  • 109.5 degrees (correct)
  • 104.5 degrees
  • 120 degrees

Why might a molecule with polar bonds be overall classified as nonpolar?

  • The molecule has only nonbonding electron pairs
  • The molecule contains only carbon and hydrogen atoms
  • The dipoles are symmetrically arranged and cancel each other out (correct)
  • The molecule does not possess any lone pairs

What is the bond angle for a V-shaped molecule?

<p>104.5 degrees (C)</p> Signup and view all the answers

What shapes can be represented by the general formula AX₃?

<p>Trigonal Planar and Trigonal Pyramidal (B)</p> Signup and view all the answers

How many bond pairs and lone pairs are there in a V-shaped molecule?

<p>2 bond pairs, 2 lone pairs (C)</p> Signup and view all the answers

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Study Notes

Shape Determination and Electron Pair Repulsion

  • Electron pairs around a central atom arrange to maximize distance, influencing molecular shape.
  • Strength of repulsion among electron pairs follows the order: Lone pair-lone pair > Lone pair-bond pair > Bond pair-bond pair.

Charge Distribution

  • A dipole is a term for a molecule with separated centres of charge.

Molecular Geometry

  • A trigonal planar molecule typically consists of four atoms.
  • Angles in molecular shapes:
    • Tetrahedral: 109.5 degrees
    • Pyramidal: 107 degrees
    • V-shaped: 104.5 degrees
    • Linear: 180 degrees
    • Trigonal planar: 120 degrees

Covalent Bonding

  • A polar covalent bond occurs when electrons are shared unequally between atoms.
  • Polar bonds can result in a nonpolar molecule if dipoles are symmetrically arranged.

Molecular Structures and Bond Pairs

  • Pyramidal molecules contain 1 lone pair and 3 bond pairs.
  • General shapes based on formulas:
    • AX: Linear shape
    • AXâ‚‚: Linear or V-shaped planar
    • AX₃: Trigonal planar or trigonal pyramidal
    • AXâ‚„: Tetrahedral shape

Bond Pair and Lone Pair Counts

  • Linear molecules can have 1 or 2 bond pairs, depending on the number of atoms.
  • V-shaped molecules consist of 2 bond pairs and 2 lone pairs.
  • Tetrahedral molecules have 4 bond pairs and 0 lone pairs.
  • Trigonal planar molecules are characterized by 3 bond pairs and 0 lone pairs.

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