Chemistry Midterm III Practice Exam
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Questions and Answers

Which of the following is (2S,3R)-2,3-dihydroxybutanal?

  • Compound I and II
  • Compound II
  • Compound I
  • Compound III (correct)
  • What is the percentage composition of enantiomers in the given mixture with an observed specific rotation of +11.2?

  • 60% (R), 40% (S)
  • 40% (R), 60% (S)
  • 64% (R), 36% (S) (correct)
  • 36% (R), 64% (S)
  • What type of isomers are molecules I and II?

  • Constitutional isomers (correct)
  • Identical
  • Diastereomers
  • Enantiomers
  • Which of the following pairs are enantiomers?

    <p>B and C</p> Signup and view all the answers

    Which statements about 1,1-dicyclopentanyl ethane are correct?

    <p>It has a chiral center.</p> Signup and view all the answers

    What is the IUPAC name for the compound represented?

    <p>(3S, 4R) - 4-ethyl-3-methylheptane</p> Signup and view all the answers

    How many stereoisomers can be drawn for 3,3,5-trimethylhept-1-en-6-yne?

    <p>4</p> Signup and view all the answers

    What is the IUPAC name of the given compound?

    <p>(3R,5 R)-5-fluoro-3,5-dimethylhept-1-yne</p> Signup and view all the answers

    Which of the following compounds is a meso compound?

    <p>A compound with two or more chiral centers and an internal plane of symmetry</p> Signup and view all the answers

    Which statement about the SN1 mechanism is incorrect?

    <p>The SN1 mechanism involves a single step.</p> Signup and view all the answers

    Which feature distinguishes constitutional isomers from other types of isomers?

    <p>They have the same molecular formula but different structural formulas.</p> Signup and view all the answers

    What is necessary for a compound to be classified as enantiomers?

    <p>They must have different connectivity and be mirror images.</p> Signup and view all the answers

    What is the initial rate of the reaction given k = 2.0 x 10^-2 M^-1s^-1, [CH3Br] = 0.2 M, and [OH-] = 0.5 M?

    <p>2.0 x 10^-2 M/s</p> Signup and view all the answers

    Which of the following molecules is NOT likely to be chiral?

    <p>A symmetrical molecule with two chiral centers.</p> Signup and view all the answers

    In molecular structure representation, what designates a molecule as diastereomers?

    <p>They have multiple stereocenters and differ at one or more but not all.</p> Signup and view all the answers

    In which scenario do nucleophilicities not parallel basicities?

    <p>When nucleophilic atoms are different</p> Signup and view all the answers

    Which statement about the nucleophiles I − and F − is correct in different solvent types?

    <p>I − is stronger in protic solvents</p> Signup and view all the answers

    What is the correct order of leaving group ability in nucleophilic substitution reactions?

    <p>Br− &gt; Cl− &gt; OH− &gt; H−</p> Signup and view all the answers

    Which compound arrangement depicts the correct order of increasing SN1 reaction rates?

    <p>IV &lt; II &lt; III &lt; I</p> Signup and view all the answers

    Which solvent favors an SN1 reaction over SN2?

    <p>Polar, protic solvent</p> Signup and view all the answers

    What is the order of increasing SN2 reaction rates for the given compounds?

    <p>IV &lt; II &lt; III &lt; I</p> Signup and view all the answers

    Which solvent would likely yield the fastest reaction rate for nucleophilic substitution?

    <p>Acetone</p> Signup and view all the answers

    Which statement correctly describes the relationship between solvent type and the SN2 mechanism?

    <p>SN2 reactions are favored by polar aprotic solvents</p> Signup and view all the answers

    Study Notes

    Instructions for Practice Exam

    • Use a pen to write your name on the scantron and the exam.
    • Match the names on both.
    • Answer questions 1-18 on the scantron using a pencil.
    • Answer questions 19-23 on the exam sheet, with the indicated point values.
    • Transfer answers to the scantron in time.
    • No extra time will be given for transferring answers.
    • Plagiarism will result in a 0 grade and expulsion from the exam.
    • No pages may be removed from the exam.

    Periodic Table Information

    • A periodic table is provided, with atomic numbers, symbols, and atomic weights.
    • Separate sections for lanthanide and actinide series are included.

    Relative Strength of Acids and Conjugate Bases

    • A table of selected acids, their approximate pKa values, and their conjugate bases are listed.

    Midterm III Practice Exam Questions (Pages 2-3)

    • Question 1: I and II are constitutional isomers, enantiomers, identical, diastereomers, or not isomeric. 
    • Question 2: 1,1-dicyclopentanyl ethane does, or does not, have a chiral center. 
    • Question 3: Number of stereoisomers for 3,3,5-trimethylhept-1-en-6-yne.
    • Question 4: Determine which molecules are meso compounds.
    • Other specific questions on various organic chemistry topics including structural formulas, isomers, chiral centers, and reactions (SN1 and SN2).

    Additional Questions (Pages 4-7)

    • Question 5: Identify a specific compound (2S,3R)-2,3-dihydroxybutanal. 
    • Question 6: Determine percentages of isomers (R and S) in a mixture given specific rotation,
    • Questions 7-18: Various organic chemistry questions on molecules, reactions, and stereochemistry.
    • Questions 19-23: Additional organic chemistry problems that require reactions, formulas or structures.

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    Description

    Prepare for your Chemistry Midterm III with this practice exam! This quiz covers essential topics such as the periodic table, relative strength of acids and their conjugate bases, and various isomer classifications. Test your knowledge and boost your confidence before the big day.

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