Chemistry Midterm Review Chapters 7, 12-14

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Questions and Answers

What is the primary focus of Chapter 14 in the upcoming midterm?

  • Liquids and Solids
  • Chemical Kinetics (correct)
  • Solutions
  • Gases

What items are explicitly allowed during the midterm exam?

  • Graphing Calculator, Notes, ID
  • Smartphone, Formula Sheet, Periodic Table
  • Laptop, Formula Sheet, Test Bank
  • Non-programmable Calculator, Pencil, Eraser, ID (correct)

How many questions will be on the exam from Chapter 7?

  • 8 questions
  • 10 questions
  • 6 questions (correct)
  • 4 questions

When is Midterm 2 scheduled to take place?

<p>November 8, 2024 (C)</p> Signup and view all the answers

How many questions will be dedicated to Chapter 12 on the exam?

<p>6 questions (C)</p> Signup and view all the answers

What should students do when they are certain of an answer on the Akindi sheet?

<p>Bubble in their answers when they are convinced (C)</p> Signup and view all the answers

Which material is provided for students during the exam?

<p>Formula Sheet and Periodic Table (D)</p> Signup and view all the answers

Where can students find their assigned exam room?

<p>Refer to their student information document (A)</p> Signup and view all the answers

How many moles of helium are found in a balloon that contains 5.5 L of helium at a pressure of 1.15 atm and a temperature of 22.0 ºC?

<p>2.6 (C)</p> Signup and view all the answers

What is the volume of O2 gas in a balloon at 1.0 atm and 305 K, after the temperature is lowered to 77 K?

<p>0.16 L (A)</p> Signup and view all the answers

Identify the gas from a 3.50 g sample in a 1.5 L container with a pressure of 2.42 atm at 355 K.

<p>N2 (A)</p> Signup and view all the answers

Which of the following gases will have the greatest average velocity at 300 K?

<p>N2 (B)</p> Signup and view all the answers

Which type of intermolecular force is considered the strongest?

<p>Ion-dipole interactions (A)</p> Signup and view all the answers

What is the preferred writing instrument on exams to allow for answer changes?

<p>Pencil (C)</p> Signup and view all the answers

How much energy is required to heat a 29.0 g sample of acetone from a solid at −94.8°C to −50.0°C?

<p>5.64 kJ (D)</p> Signup and view all the answers

What phase is present after the temperature is increased to the critical temperature at constant pressure?

<p>Gas (B)</p> Signup and view all the answers

If a certain metal forms in a FCC unit cell with an edge length of 3.52 Ã…, what is the radius of one atom?

<p>4.98 × 10–8 cm (B)</p> Signup and view all the answers

Why is chloroform, CHCl3, more soluble in water than is carbon tetrachloride, CCl4?

<p>CHCl3 is polar and has stronger solute–solvent interactions. (B)</p> Signup and view all the answers

When a room-temperature solution saturated in KCl and CO2 is heated to near boiling, what is most likely to occur?

<p>Some CO2 bubbles out of solution. (D)</p> Signup and view all the answers

What is the mass percent of a solution prepared from 15 g of NaCl in 45 g of H2O?

<p>33% (D)</p> Signup and view all the answers

What is the molar mass of lauryl alcohol if 5.00 g of it in 0.100 kg of benzene freezes at 4.1°C?

<p>270 g/mol (A)</p> Signup and view all the answers

What is the rate of disappearance of NO during the first 100 seconds?

<p>5.9 × 10–4 M/s (A)</p> Signup and view all the answers

If the rate of appearance of O2 is 0.0014 Ms–1, what is the rate of disappearance of H2O2?

<p>0.0028 Ms–1 (C)</p> Signup and view all the answers

What is the value of the rate constant, k, for the reaction given the initial rates and concentrations?

<p>4.35 × 10–3 M–1s–1 (C)</p> Signup and view all the answers

For a reaction following first order kinetics with an initial concentration of 1.5 M and rate constant 0.0294 s–1, what is the concentration after 24.5 seconds?

<p>0.29 M (D)</p> Signup and view all the answers

How long will it take for a zero order reaction with a rate constant of 0.28 to reach 30% of its original concentration of 1M?

<p>20 s (A)</p> Signup and view all the answers

What is the activation energy (Ea) of the process that correlates chirping rates of crickets to temperature?

<p>6.16 kJ/mol (A)</p> Signup and view all the answers

What is the incorrect assumption to make when determining the rate of a reaction?

<p>Reaction rates are constant over time. (C)</p> Signup and view all the answers

In a first order reaction, what is the relationship between concentration and time?

<p>Concentration decreases exponentially with time. (C)</p> Signup and view all the answers

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Study Notes

Midterm Information

  • Midterm Date: Friday, November 8th, 2024
  • Midterm Time: 6:30 PM (EST) – 8:30 PM (EST)
  • Exam Location: See Announcement on D2L for Exam Rooms
  • Format: 25 Multiple Choice Questions
  • Chapters covered: Chapters 7, 12-14
  • Allowed tools: Non-programmable Calculator, Pencil, Eraser, ID
  • Materials provided: Formula Sheet and Periodic Table

Exam Breakdown

  • Chapter 7 - Gases: 6 Questions
  • Chapter 12 - Liquids and Solids: 6 Questions
  • Chapter 13 – Solutions: 6 Questions
  • Chapter 14 – Chemical Kinetics: 7 Questions

Study Resources

  • D2L Interactive Examples: short videos on essential skills
  • D2L Video Tutorials
  • Textbook Questions (odd-numbered)
  • Adaptive Assignments on Achieve
  • Past Exams (available for practice)

Important Notes

  • Check D2L for your assignment to a specific exam room in Kerr Hall East
  • Fill out an Akindi Sheet by bubbling in your Student Number and Version Number correctly
  • Use a pencil on the Akindi Sheet so you can erase mistakes
  • No Student Number or Version Number on the Akindi Sheet results in a score of 0

Study Tips

  • Don’t make new notes; focus on summarizing already existing notes
  • Quiz yourself using existing notes and practice problems
  • Practice questions are key to success
  • Bounce between different topics closer to the exam date
  • Take care of yourself - eat well, take breaks, and get a good night's sleep!

Concept Review

  • Gas Laws:
    • Ideal Gas Law: PV = nRT
    • Boyle's Law: P1V1 = P2V2
    • Charles's Law: V1/T1 = V2/T2
    • Avogadro's Law: V1/n1 = V2/n2
    • Dalton's Law of Partial Pressures: Ptotal = P1 + P2 + ...
  • Kinetic Molecular Theory:
    • Gases are composed of particles constantly in random motion with negligible volume
    • Average kinetic energy is proportional to absolute temperature (KE = (1/2)mv^2)
  • Intermolecular Forces:
    • Dispersion Forces: Weakest forces, present between all molecules; increase with increasing molecular size
    • Dipole-Dipole Forces: Between polar molecules with permanent dipoles
    • Hydrogen Bonding: Strongest dipole-dipole interaction; involves hydrogen bonded to highly electronegative elements (N, O, F)
    • Ion-Dipole Forces: Between ions and polar molecules
  • Liquids and Solids:
    • Properties of liquids: fluidity, viscosity, surface tension, and vapor pressure
    • Types of solids: crystalline and amorphous
    • Crystalline solids have a regular, repeating arrangement of atoms or molecules: ionic, covalent, metallic, and molecular solids
  • Solutions:
    • Concentration units: molarity, molality
    • Solute-Solvent Interactions: "like dissolves like"
    • Factors affecting solubility: temperature, pressure, and nature of solvent and solute
    • Colligative properties: vapor pressure lowering, freezing point depression, boiling point elevation, and osmotic pressure
  • Chemical Kinetics:
    • Factors affecting reaction rate: concentration, temperature, and surface area
    • Rate Law: expresses the relationship between the rate of a reaction and the concentration of reactants
    • Reaction order: determined by the exponents in the rate law
    • Integrated rate laws: used to determine the concentration of reactants or products at any given time
    • Activation energy: minimum amount of energy required for a reaction to occur
    • Catalysts: substances that increase the rate of a reaction without being consumed

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