Chemistry Exam Review 2018/19
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Boiling Point

The temperature at which a liquid boils and turns into gas. The boiling point temperature may vary, depending on the element. Vapour pressure of liquid = external pressure.

Freezing Point

The temperature at which a liquid solidifies when solid and liquid are in equilibrium.

Ionization Energy

The amount of energy required to completely remove the most loosely held electron from the gaseous atom.

Electron Affinity

The amount of energy released when an atom gains an electron

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Covalent Bond

A chemical bond that involves the sharing of electron pairs between atoms.

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Oxidation

The loss of an electron in a chemical reaction.

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Reduction

The gain of an electron in a chemical reaction.

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Brønsted Acids and Bases

Bronsted acids are proton donors. Bronsted bases are proton acceptors.

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Buffer Solution

A solution that resists changes in pH when small amounts of an acid or a base are added to it.

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Acid-Base Indicator

A substance that changes color with changes in pH

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Osmotic Pressure

The pressure that needs to be applied to a solution to prevent the inward flow of water across a semipermeable membrane.

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Electrolysis

The process by which electric current is passed through a substance to effect a chemical change.

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Solubility

The process by which a substance dissolves in a solvent. This is a measure of the maximum amount of solute that can dissolve in a given amount of solvent.

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Azeotrope

A mixture of two or more liquids whose proportions cannot be altered by simple distillation.

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Colloid

A substance that is dispersed throughout another substance, creating a mixture with particles that are invisible in an optical microscope (about 1-100 nm in size).

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Suspension

Particles suspended in a medium that are larger than colloids and will settle out over time.

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Emulsion

A mixture of two or more liquids that are normally immiscible (don't mix) but are dispersed throughout each other.

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Rate Constant

The rate constant for a chemical reaction at a specific temperature. It's the rate of the reaction when the concentration of reactants is 1 mol/dm³.

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Critical Pressure of Gases

The minimum pressure needed to liquify a gas at its critical temperature.

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Ionization Potential

A measure of the tendency of a substance to lose electrons. It's the energy needed to remove one electron from an atom or ion.

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Molecule

A molecule containing more than one atom, particularly involving the interaction of two or more atoms through the sharing of electrons.

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Half-life

The half-life of a chemical reaction is the time required for the reactant concentration to decrease to half of its initial value.

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Exothermic Reaction

A chemical reaction that releases energy to the surrounding environment, often in the form of heat or light.

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Endothermic Reaction

A chemical reaction that absorbs heat or energy from the surrounding environment.

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Autocatalysis

A type of chemical reaction in which the product of the reaction itself acts as a catalyst.

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Catalyst

A substance that speeds up a chemical reaction without being consumed in the process.

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Inhibitor

A substance that slows down or inhibits a chemical reaction without being consumed in the process.

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Hybridization

The mixing of at least two non-equivalent atomic orbitals to form new hybrid orbitals.

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Chemical Bond

A chemical bond that's formed between two atoms which involve the sharing of electrons.

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Redox Reaction

A chemical reaction that involves the transfer of electrons between atoms. This results in a change in oxidation states.

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Enthalpy

The thermodynamic property that describes the measure of the amount of work done during a process carried out at constant pressure.

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Entropy

The thermodynamic property that describes the amount of disorder or randomness within a system.

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Gibbs Free Energy

The thermodynamic property that describes the amount of energy available to do useful work.

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Study Notes

Chemistry Exam Review - 2018/19

  • Orbital Filling (Hydrogen Atom): The ground state hydrogen atom fills the 1s orbital.
  • Oxidation: A process involving loss of electrons. An example is Zn → Zn²⁺ + 2e⁻.
  • Maximum Electrons (L shell): The maximum number of electrons that can occupy the L shell is 8.
  • Primary Bond Types: Ionic, covalent, and metallic bonds are the primary bond types.
  • Brønsted Bases: Proton acceptors.
  • Brønsted Acids: Proton donors.
  • Lewis Acids: Electron-pair acceptors.
  • Lewis Bases: Electron-pair donors.
  • pH Comparison (Solutions A & B): If solution A has a pH of 1, and solution B has a pH of 2, solution B has 10 times the concentration of H⁺ ions as solution A.
  • Boiling Point Definition: The temperature at which a liquid changes to a gas when the vapour pressure equals the external pressure.
  • Density: A measure of mass per unit volume; an intensive property (g/dm³).
  • Gibbs Free Energy Formula: $\Delta G$ = $\Delta H$ - T$\Delta S$, where G= Gibbs free energy, H= enthalpy, T= temperature (K), S = entropy.
  • Gibbs Free Energy Definition: The thermodynamic quantity representing energy available to do useful work in a system or process.
  • Micelle Definition: An aggregation of surfactant molecules in a liquid colloid, consisting of a hydrophilic head and a hydrophobic tail. Common example is soap.
  • Ligand Definition (Complexometry): An ion or molecule attached to a metal atom by coordinate bonding. Common examples include NH₃, Cl⁻, and H₂O.
  • Ideal Gas Law Formula: PV=nRT (Pressure x Volume = number of moles x gas constant x Temperature)
  • Exothermic vs. Endothermic Reactions: Exothermic reactions release energy, and endothermic reactions absorb energy.
  • Isotopes Definition: Atoms with the same atomic number but different mass numbers.
  • Colligative Properties: Properties of solutions that depend on the concentration of solute, not its identity e.g., osmotic pressure, boiling point elevation, freezing point depression.
  • Ionization Energy: The energy to remove an electron from a gaseous atom; higher from right to left on periodic table.
  • Galvanic Cell vs. Electrolysis: Galvanic cells use electrochemical energy to produce electrical current, while electrolysis uses electrical energy to force chemical reactions.
  • Bond Order Definition: Half the difference between bonding electrons and antibonding electrons in a molecule. O₂ bond order is 2.
  • Arsenic Detection: Arsenic (III) ions can be detected by Griess-Ilosvay reagent.
  • Hydrogen Bonding: Hydrogen bonding can occur with molecules containing H directly bonded to highly electronegative atoms such as N, O, and F.
  • Substances Existing Only in Solid State at Standard Conditions: The substance CaCO₃ is solid at standard conditions; other possible answers are KMnO₄, I₂ , Br₂ and S.
  • Hydrogen Halides (HX): Generally, from HF to HI, the ionic character of the H-X bond increases, and so does the bond energy.
  • Solubility: The ability of a substance, (the solute), to dissolve in a solvent.
  • Buffer Solution Definition (Example): A solution that resists changes to pH when small amounts of acid or base are added. Examples include CH₃COOH/CH₃COO⁻ and NH₃/NH₄⁺.
  • Autocatalysis: Involves a reaction that has one of its products acting as a catalyst.

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Prepare for your chemistry exam with this comprehensive review quiz from the 2018/19 academic year. The quiz covers essential topics including orbital filling, oxidation, bond types, and the concepts of acidity and pH. Test your knowledge on key chemistry principles to enhance your understanding and performance.

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