Chemistry Chapter on Ionization Energy and Isotopes
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Questions and Answers

What happens to the first ionisation energy as you move across a period?

  • It remains constant
  • It decreases
  • It fluctuates unpredictably
  • It increases (correct)
  • The first ionisation energy increases down a group.

    False

    What is the effect of increasing atomic radius on first ionisation energy?

    It decreases first ionisation energy.

    The first ionisation energy __________ down groups due to increasing __________ and __________.

    <p>decreases, atomic radius, electron shielding</p> Signup and view all the answers

    Match the following factors with their effects on first ionisation energy:

    <p>Increasing nuclear charge = Increases first ionisation energy Increasing atomic radius = Decreases first ionisation energy Increasing electron shielding = Decreases first ionisation energy</p> Signup and view all the answers

    Between lithium and carbon, which will have a lower first ionisation energy?

    <p>Lithium</p> Signup and view all the answers

    Beryllium has a lower first ionisation energy than magnesium.

    <p>False</p> Signup and view all the answers

    Explain why magnesium has a lower first ionisation energy compared to beryllium.

    <p>Magnesium has a larger atomic radius and increased electron shielding compared to beryllium.</p> Signup and view all the answers

    What is the atomic number of helium isotopes?

    <p>2</p> Signup and view all the answers

    Titanium has a higher percentage abundance of the isotope 48Ti than 47Ti.

    <p>True</p> Signup and view all the answers

    What percentage of naturally occurring carbon consists of carbon-13?

    <p>1.1%</p> Signup and view all the answers

    The isotope ____Ti has the highest abundance among stable titanium isotopes.

    <p>48</p> Signup and view all the answers

    Match the following isotopes of titanium with their percentage abundance:

    <p>46Ti = 8.25% 47Ti = 7.44% 48Ti = 73.72% 49Ti = 5.41% 50Ti = 5.18%</p> Signup and view all the answers

    How do scientists utilize atomic emission spectra?

    <p>To identify the composition of stars</p> Signup and view all the answers

    Carbon-12 and carbon-13 are both isotopes of carbon that can be detected by mass spectrometry.

    <p>True</p> Signup and view all the answers

    Calculate the number of atoms of hydrogen in 16g of sulphuric acid (H2SO4).

    <p>2 moles of hydrogen atoms or 4 hydrogen atoms total.</p> Signup and view all the answers

    How many oxygen atoms are in one mole of oxygen gas?

    <p>2</p> Signup and view all the answers

    Why is the 'M+1' peak visible but the 'M+2' peak not visible in the mass spectrum of a molecule consisting of two carbon atoms?

    <p>The molecule contains only carbon-12 and not carbon-13.</p> Signup and view all the answers

    The empirical formula is the simplest whole number ratio of ______ in a compound.

    <p>elements</p> Signup and view all the answers

    The empirical formula of a compound with 23.3% magnesium, 30.7% sulphur, and 46.0% oxygen is MgSO4.

    <p>True</p> Signup and view all the answers

    What is the empirical formula of a compound containing 60.0% sulphur and 40.0% oxygen by mass?

    <p>SO2</p> Signup and view all the answers

    Match the following compounds with their empirical formulas:

    <p>Ethene = CH2 Sulphuric Acid (H2SO4) = H2SO4 Magnesium Oxide = MgO Carbon Dioxide = CO2</p> Signup and view all the answers

    What is the molar mass of sulphuric acid (H2SO4)?

    <p>98 g/mol</p> Signup and view all the answers

    The empirical formula of a compound can be the same as its molecular formula.

    <p>True</p> Signup and view all the answers

    What primarily contributes to the high melting points of metallic structures?

    <p>Strong metallic bonds</p> Signup and view all the answers

    Metallic structures are poor conductors of electricity.

    <p>False</p> Signup and view all the answers

    What term describes the attraction between positively charged metal ions and delocalised electrons?

    <p>metallic bonds</p> Signup and view all the answers

    A high amount of ___________________ is required to break the bonds in metallic structures.

    <p>energy</p> Signup and view all the answers

    Match the property of metallic structures with its explanation:

    <p>High melting points = Strong attraction between metal ions and delocalised electrons Good electrical conductivity = Movement of delocalised electrons Strength = No individual bonds to break Bond strength = Depends on the charge and size of the ion</p> Signup and view all the answers

    What happens to the strength of a metallic bond as the charge of the metal ion increases?

    <p>It increases</p> Signup and view all the answers

    Metallic structures can conduct electricity when the ions are fixed in a lattice.

    <p>False</p> Signup and view all the answers

    What is required for metallic structures to conduct electricity?

    <p>Free moving electrons</p> Signup and view all the answers

    What is the resulting compound when tin (Sn) reacts with iodine (I2)?

    <p>SnI4</p> Signup and view all the answers

    When 5.00 g of hydrated tin (II) chloride are heated, the mass of the anhydrous compound formed is greater than 5.00 g.

    <p>False</p> Signup and view all the answers

    If 4.20 g of anhydrous tin (II) chloride is formed, how much water was lost during the heating of 5.00 g of hydrated tin (II) chloride?

    <p>0.80 g</p> Signup and view all the answers

    The formula for the hydrated tin (II) chloride is SnCl2.xH2O, where x represents the number of molecules of ______.

    <p>water</p> Signup and view all the answers

    To calculate the percentage composition of carbon in a compound, which of the following must be known?

    <p>Mass of the compound and mass of carbon</p> Signup and view all the answers

    Match the following compounds with their components:

    <p>SnI4 = Tin and iodine SnCl2 = Tin and chlorine H2O = Hydrogen and oxygen C6H12O6 = Carbon, hydrogen, and oxygen</p> Signup and view all the answers

    What is the total percentage mass of oxygen in a compound containing 2.20 g of hydrogen, 7.20 g of carbon, and 17.6 g of oxygen?

    <p>65.2%</p> Signup and view all the answers

    The molar mass of SnCl2 is ______ g/mol.

    <p>189.2</p> Signup and view all the answers

    What is the formula to calculate percentage yield?

    <p>Actual Yield / Theoretical Yield x 100</p> Signup and view all the answers

    The combustion of carbon disulfide produces only carbon dioxide as a product.

    <p>False</p> Signup and view all the answers

    What are the products of burning carbon disulfide in the presence of oxygen?

    <p>Sulfur dioxide and carbon dioxide</p> Signup and view all the answers

    The percent yield of a reaction can be calculated using the formula: __________.

    <p>percentage yield = (actual yield / theoretical yield) x 100</p> Signup and view all the answers

    Match the compounds with their yields in the reaction of carbon disulfide combustion:

    <p>Carbon Dioxide = Varies based on supplied reactants Sulfur Dioxide = Depends on actual yield of the reaction</p> Signup and view all the answers

    If 25.0 g of carbon disulfide is burned and produces 40.5 g of sulfur dioxide, what contributes to the percent yield being less than 100%?

    <p>Incomplete reaction or loss during transfer</p> Signup and view all the answers

    The theoretical yield of a reaction can always be achieved in practice.

    <p>False</p> Signup and view all the answers

    Calculate the percentage yield if the actual yield of chlorobenzene is 63.7 g and the theoretical yield is 70 g.

    <p>91.0%</p> Signup and view all the answers

    Study Notes

    A Level OCR B Salters H033 Chemistry Booklet: Elements of Life Pt1

    • Table of Contents: Provides a detailed outline of the topics covered in the booklet, with page numbers for each. Includes learning sequences, powerful knowledge sections, and practice exercises.

    Data Sheet

    • General Information: Includes key constants like Avogadro's constant, molar gas volume, specific heat capacity of water, Planck constant and more.
    • Amino Acid Codons: Lists the triplet base codes (codons) for various amino acids used in mRNA.

    Common lons

    • Ion Formulae and Names: Provides a table listing common ion formulae alongside their respective names. (e.g., NO₃⁻-Nitrate, SO₄²⁻-Sulphate, CO₃²⁻-Carbonate, etc.)

    Learning Sequence 1: Formulae and Equations

    • Outcomes: Students will describe atomic structure and isotopes, explain mass spectrometry, and apply Avogadro's number to chemical calculations.
    • Powerful Knowledge: Atomic Structure: Atoms consist of protons, neutrons and electrons located in different parts of the atom, with unique masses and charges. The nucleus holds protons and neutrons, while the electron cloud surrounds the nucleus.
    • Atomic Number: The atomic number represents the number of protons in an atom of an element.
    • Mass Number (Relative Atomic Mass): The sum of protons and neutrons in an atom.
    • Isotopes: Atoms of the same element (same number of protons) that have different numbers of neutrons.
    • Mass Spectrometry: Used to determine the abundance of isotopes.

    Powerful knowledge: Isotopes

    • Isotope Definition: Atoms of the same element with different numbers of neutrons, hence, different mass numbers. Their chemical behavior is the same due to identical electron numbers.

    • Calculating isotopic elements: Various exercises to calculate relative atomic mass from isotopic data.

    • Example: Carbon (C) has isotopes 12C, 13C and 14C all having the same number of protons but different numbers of neutrons.

    • Powerful knowledge: Mass spectroscopy Explains how mass spectrometers work by vaporizing, ionizing, accelerating, deflecting, and detecting ions to determine the mass-to-charge ratio (m/z) and abundance of each isotope.

    Powerful knowledge: Calculating Average Atomic Mass of Isotopes

    • Method: Weighted average based on isotopic masses and natural abundances.
    • Formula: Utilizes the formula to calculate average atomic mass from isotopic masses and abundances.

    Learning Sequence 3: Bonding and Structure

    • Outcomes: Students describe covalent and dative bonding in molecules, describe ionic and metallic bonding using ideas about ions, and describe the properties of simple molecular, massive covalent, ionic lattice and metallic structures.

    Powerful knowledge: Covalent Bonding

    • Definition: Atoms share one or more pairs of electrons to reach a stable electron configuration, usually observed between nonmetals.

    Dative Covalent Bonds

    • Definition: One atom provides both electrons to be shared in the covalent bond, typically with one atom having a lone pair electron and the other having an empty orbital.

    Powerful knowledge: Ionic Bonding

    • Definition: Electrons are transferred or shared creating ions for achieving stability. Characteristic of metals binding with nonmetals.

    Powerful knowledge: Metallic Bonding

    • Definition: Lattice formed by positive ions in a sea of delocalized electrons.

    Powerful knowledge: Structure and Properties of Simple Molecular Structures

    • Structures and Properties: Simple molecular structures have low melting and boiling points and poor conductivity due to weak intermolecular forces holding the molecules together. They generally consist of non-metallic elements.

    Powerful knowledge: Structure and Properties of Giant Covalent Structures

    • Structure and Properties: Examples like diamond and graphite are good examples of such structures characterized by extremely strong covalent bonds, which lead to high melting and boiling points. They may or may not conduct electricity, depending on the structure.

    Powerful knowledge: Structure and Properties of Ionic Compounds

    • Structure and Properties: Giant ionic lattices are formed between metallic and nonmetallic elements with ions forming a crystal lattice structure causing high melting and boiling points due to strong electrostatic interactions. Generally poor conductors of electricity in their solid state but can conduct in molten or dissolved form.

    Powerful knowledge: Structure and Properties of Metallic Structures

    • Structure and Properties: Consist of metallic ions surrounded by a sea of delocalized electrons. Metallic structures have high melting and boiling points and are good conductors of both electricity and heat. The ability to conduct is caused by the mobility of electrons.

    Learning Sequence 4: Amount of Substances and Chemical Calculations

    • Outcomes: Students define the mole, calculate moles in mass, calculate reacting masses, and perform percentage yield and composition calculations.
    • Powerful knowledge: Number of Moles: One mole of any substance contains Avogadro's number of entities (atoms, molecules, etc.).
    • Molar Calculations: Calculates reacting mass, amount of product formed, or needed reactants. Utilize stoichiometric ratios from balanced chemical equations.
    • Percentage yield: Compares actual yield (amount experimentally obtained) to theoretical yield (calculated yield). Provides an insight into the efficiency of a reaction.

    Powerful knowledge: Percentage Composition

    • Definition: Percentage composition describes the percentage of each element by mass in a compound. Using molar mass and the percentage composition enables calculation of the empirical formula

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    Test your understanding of first ionisation energy trends and isotopic abundance in this quiz. Explore how atomic radius and group positioning affect ionisation energy, along with the significance of atomic emission spectra. This quiz covers essential concepts in chemistry.

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