Chemistry Chapter on Aqueous Solutions
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Questions and Answers

What is the molarity of a solution containing 1.5 mol of NaCl dissolved in 0.500 L of solution?

  • 3.0 M NaCl (correct)
  • 2.0 M NaCl
  • 4.0 M NaCl
  • 1.0 M NaCl
  • How do you express the moles of solute when given a mass of 22.4 g of HCl?

  • 0.800 mol HCl
  • 0.125 mol HCl
  • 1.14 mol HCl
  • 0.614 mol HCl (correct)
  • What is the first step in calculating the molarity of a solution?

  • Add solvents to the solute.
  • Dilute the solution with water.
  • Measure the total volume in milliliters.
  • Convert mass of solute to moles. (correct)
  • If 42.23 g of NH4Cl is dissolved to make 500.0 mL of solution, what is necessary to calculate its molarity?

    <p>Convert 500.0 mL to liters and calculate moles of NH4Cl. (C)</p> Signup and view all the answers

    Why is the term 'aq' sometimes added after a solute in a solution?

    <p>To specify that the solvent is water. (A)</p> Signup and view all the answers

    Which conversion factor is essential for calculating the number of moles from mass for HCl?

    <p>Molar mass of HCl (D)</p> Signup and view all the answers

    If you have a solution with a molarity of 0.394 M HCl, how many moles of HCl are in 1.56 L of solution?

    <p>0.614 mol HCl (D)</p> Signup and view all the answers

    Which of the following is a common misconception about molarity calculations?

    <p>The volume of solvent is used instead of the total solution volume. (C)</p> Signup and view all the answers

    What is the molarity of a solution containing 53.50 g of NH4Cl in 0.5000 L of solution?

    <p>1.579 M NH4Cl (C)</p> Signup and view all the answers

    How many moles of NaCl are present in 0.5000 L of a 4.69 M solution?

    <p>1.045 moles (A)</p> Signup and view all the answers

    If 66.2 g of C6H12O6 is dissolved to make 235 mL of solution, what is its molarity?

    <p>1.57 M C6H12O6 (C)</p> Signup and view all the answers

    Which of the following correctly describes the relationship of concentration and stoichiometry in a chemical reaction?

    <p>Concentration provides a conversion factor between moles of solute and liters of solution. (B)</p> Signup and view all the answers

    How would you describe the process of determining the moles of solute given its concentration and volume?

    <p>Using the molarity equation. (B)</p> Signup and view all the answers

    What is the mass of solute needed to prepare 1.00 L of a 2.00 M NaCl solution?

    <p>116.88 g (B)</p> Signup and view all the answers

    If 137 g of NaCl is dissolved in 500 mL, what is the concentration in mol/L?

    <p>4.69 M NaCl (D)</p> Signup and view all the answers

    Which factor is essential when using molarity as a conversion factor?

    <p>The units must be consistent. (B)</p> Signup and view all the answers

    What is the mass of the solution when 25.0 g of sugar is dissolved in 100.0 g of water?

    <p>125.0 g (C)</p> Signup and view all the answers

    How is percent by mass calculated in a solution?

    <p>Mass of solute divided by total mass of solution times 100% (C)</p> Signup and view all the answers

    What is the mass/mass percent concentration of a saline solution with 36.5 g of NaCl in 355 g of solution?

    <p>10.3% (A)</p> Signup and view all the answers

    To prepare a 5.00% NaCl solution with a total mass of 3000.0 g, what mass of NaCl is needed?

    <p>150.0 g NaCl (A)</p> Signup and view all the answers

    In a solution prepared using 15.8 g of dextrose in a total mass of 200.0 g, what is the mass/mass percent concentration?

    <p>7.90% (B)</p> Signup and view all the answers

    If you need to express mass percent as a conversion factor, which of the following is correct?

    <p>g solute / 100 g solution (D)</p> Signup and view all the answers

    If a solution has a mass of 255 g and 25 g sugar dissolved in it, what would be the percent by mass of sugar?

    <p>10.87% (B)</p> Signup and view all the answers

    When calculating the amount of solute needed for a specific concentration, what must be known?

    <p>The mass of the solution and the desired percent concentration (A)</p> Signup and view all the answers

    Flashcards

    Mass percent concentration

    The mass of solute divided by the mass of solution, multiplied by 100%.

    Mass of solution

    The total mass of solute and solvent in a solution. Units are grams.

    Percent by mass calculation

    Calculating the percentage of a solute in a solution by dividing the mass of the solute by the mass of the solution and multiplying by 100.

    Conversion factor (mass percent)

    A ratio that relates the mass of solute to the mass of solution based on the given percent.

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    Solute

    The substance being dissolved in a solution.

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    Solvent

    The substance that dissolves the solute in a solution.

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    Mass/Mass percent concentration

    Used to express the concentration of a solution by mass.

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    Calculating solute mass

    Find the mass of solute needed for a given solution mass and concentration.

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    Molarity

    The concentration of a solution, expressed as the number of moles of solute per liter of solution.

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    Molarity units

    Molarity is expressed in moles per liter (mol/L) or M.

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    Calculating Molarity

    To calculate molarity, divide the number of moles of solute by the volume of the solution in liters.

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    Converting mass to moles

    If solute amount is in grams, use the molar mass to convert to moles.

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    Solution volume

    The total volume of the solution, including the solute's volume.

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    Volume of solution (in calculation)

    Total volume of solution in L.

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    Molarity (M)

    A unit of concentration, representing the number of moles of solute per liter of solution.

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    Moles of solute

    The amount of a substance in a solution, measured in moles.

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    Volume of solution

    The total volume of the solution, expressed in liters.

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    Concentration as Conversion Factor

    Concentration (like molarity) can be used to convert between amount and volume, and vice-versa.

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    Stoichiometry and Concentration

    Concentration units (like Molarity) can be instrumental in stoichiometry problems. That means conversion using ratios and proportions.

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    Solving for moles in a solution

    To find the number of moles from a given volume and concentration of a particular solution, multiply the volume of the solution (in Liters) by the concentration (in Molarity).

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    Significant Figures in Calculations

    When solving calculations like Molarity (or moles) be mindful of the number of significant figures when presenting final answer.

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    Study Notes

    Chapter Overview

    • Solutions are crucial in various chemical, biological, and industrial applications.
    • Aqueous solutions (where substances dissolve in water) are a focus of this chapter.
    • Solutions can involve all states (gas-gas, solid-solid, liquid-solid, liquid-liquid).
    • This chapter primarily concentrates on aqueous solutions.

    Tragedy in Cameroon - Lake Nyos

    • In 1986, a gas cloud from Lake Nyos (Cameroon) killed over 1,700 people.
    • The gas was primarily carbon dioxide, released after a lake overturn.
    • The carbon dioxide was dissolved in the water and released into the atmosphere.
    • The incident prompted investigations into other African lakes, specifically Lake Kivu.

    Solutions - Homogeneous Mixtures

    • The major component of a solution is the solvent.
    • The minor component of a solution is the solute.
    • The overall phase of a solution is identical to the solvent's phase.
    • Examples:
      • Salt water: solid NaCl in liquid water
      • Air: gaseous O2 in gaseous N2
    • Table 13.2.1 demonstrates various solution types with illustrations.

    Like Dissolves Like

    • Polar compounds dissolve polar compounds.
    • Nonpolar compounds dissolve nonpolar compounds.
    • Polar compounds do not dissolve in nonpolar compounds, and vice versa.
    • This principle is summarized in Table 13.2.2.
    • Intermolecular forces (London dispersion forces, dipole-dipole interactions, hydrogen bonding) determine solubility.

    Solutions of Solids Dissolved in Water

    • Solubility is the maximum amount of solute that can dissolve in a given amount of solvent at a specific temperature.
    • A saturated solution is one where the maximum amount of solute is dissolved.
    • These solutions are saturated or unsaturated.
    • The solubility of solids typically increases with temperature.
    • Supersaturated solutions can hold more solute than their saturated counterparts.
    • Table 13.3.1 lists the solubility of specific ionic compounds.

    Electrolyte Solutions

    • Electrolytes are compounds that yield ions in solution.
    • Strong electrolytes dissociate nearly completely in solution.
    • Weak electrolytes dissociate partially.
    • Nonelectrolytes do not dissociate.
    • Conductivity measurements can distinguish these types of solutions.
    • Table 13.3.2 displays conductivity examples.

    Solutions of Gases in Water

    • Gas solubility typically decreases with increasing temperature.
    • Gas solubility increases with increased pressure.
    • Thermal pollution (e.g., hot water discharge from industries) can decrease the amount of dissolved oxygen in water, impacting aquatic life.
    • This is described by Henry's law and Figure 13.4.1.

    Specifying Solution Concentration - Mass Percent

    • Mass percent (%m/m) = (mass of solute / mass of solution) * 100%
    • Quantitative expressions for solution concentration.
    • Allows measuring ratios of solute to solution.

    Specifying Solution Concentration - Molarity

    • Molarity (M) = (moles of solute / liters of solution).
    • A crucial concentration expression for chemical calculations.

    Solution Dilution

    • M1V1 = M2V2.
    • M1 & M2 represent initial and final concentrations, while V1 & V2 represent initial and final volumes.
    • Diluting a solution involves adding more solvent without altering the amount of solute.

    Solution Stoichiometry

    • Using concentration to calculate reactant/product amounts in solution-based reactions.

    Freezing Point Depression and Boiling Point Elevation

    • Colligative properties depend on solute concentration.
    • Freezing point of solutions is lower than the pure solvent.
    • Boiling point of solutions is higher than the pure solvent.
    • Formulas for freezing point depression and boiling point elevation involve molality and van't Hoff factor.

    Osmosis

    • Osmosis is the solvent's movement across a semipermeable membrane from a lower to a higher concentration of solute
    • Osmotic pressure is directly related to solute concentration and is crucial in biological systems.
    • Osmosis explains why IV fluids must be isotonic to prevent cell damage.

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    Description

    Explore the crucial role of solutions in chemical, biological, and industrial applications with a focus on aqueous solutions. This chapter delves into the composition of solutions, the impact of a historical tragedy in Cameroon due to gas release, and the fundamental concepts of homogeneous mixtures.

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