Aqueous Solutions and Chemical Equilibria
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Questions and Answers

What type of materials are soluble in water but do not dissociate?

  • Conjugate acids
  • Weak electrolytes
  • Strong electrolytes
  • Non-electrolytes (correct)
  • According to the Arrhenius theory, which is considered a base?

  • NH3
  • HCl
  • NaOH (correct)
  • BF3
  • Which species have both acidic and basic properties?

  • Conjugate bases
  • Non-electrolytes
  • Amphiprotic species (correct)
  • Strong electrolytes
  • In the Brønsted-Lowry theory, what is formed when an acid loses a proton?

    <p>A conjugate base</p> Signup and view all the answers

    What type of electrolytes ionize almost completely when dissolved in water?

    <p>Strong electrolytes</p> Signup and view all the answers

    Which of the following is an example of a non-electrolyte?

    <p>$C_{12}H_{22}O_{11}$</p> Signup and view all the answers

    According to the Lewis theory, which is considered an acid?

    <p>$\text{BF}_3$</p> Signup and view all the answers

    What role does a base play in the Lewis theory?

    <p>$\text{NH}_3$</p> Signup and view all the answers

    What is autoprotolysis in the context of solvents?

    <p>A spontaneous reaction to form a pair of ionic species</p> Signup and view all the answers

    Which of the following can be considered as an example of acid-base behavior?

    <p>Autoprotolysis</p> Signup and view all the answers

    What does Kw represent in the context of aqueous solutions?

    <p>Ion-product constant for water</p> Signup and view all the answers

    What is the value of Kw at room temperature?

    <p>1.00×10^-14</p> Signup and view all the answers

    Why can the concentration of water be considered constant in dilute aqueous solutions?

    <p>Its concentration is significantly higher than other ions</p> Signup and view all the answers

    Which statement correctly describes chemical equilibrium?

    <p>A state where the ratio of reactants and products concentrations is constant</p> Signup and view all the answers

    What relationship can be discovered by taking the negative logarithm of Kw equation?

    <p>Useful relationship for finding hydronium and hydroxide ion concentrations</p> Signup and view all the answers

    Study Notes

    Solubility and Dissociation

    • Soluble materials that do not dissociate in water include sugar and alcohols that dissolve without breaking into ions.
    • Non-dissociating solutes retain their molecular structure when in solution.

    Arrhenius Theory

    • According to the Arrhenius theory, bases are substances that yield hydroxide ions (OH⁻) when dissolved in water.

    Amphovert Properties

    • Amphoteric species can behave as either acids or bases, depending on the circumstances; examples include water (H₂O) and bicarbonate (HCO₃⁻).

    Brønsted-Lowry Theory

    • In the Brønsted-Lowry framework, an acid, upon losing a proton (H⁺), forms a conjugate base.

    Electrolytes

    • Strong electrolytes are substances that ionize almost completely in solution, such as sodium chloride (NaCl) and hydrochloric acid (HCl).

    Non-Electrolytes

    • Non-electrolytes are substances that do not conduct electricity when dissolved, with examples like glucose and ethanol.

    Lewis Theory

    • In the Lewis acid-base theory, acids are defined as electron pair acceptors, while bases are electron pair donors.

    Autoprotolysis

    • Autoprotolysis refers to the self-ionization of solvents, such as water, where two molecules interact to form hydronium (H₃O⁺) and hydroxide (OH⁻) ions.

    Acid-Base Behavior

    • Acid-base behavior can be exemplified by the reaction between an acid and a base, resulting in the formation of water and a salt.

    Ion Product of Water

    • Kw represents the ion product of water at a specific temperature, symbolizing the equilibrium constant for the autoprotolysis of water.

    Value of Kw

    • At room temperature (25°C), the value of Kw is 1.0 × 10⁻¹⁴.

    Concentration of Water

    • The concentration of water in dilute aqueous solutions remains effectively constant due to its high concentration relative to solutes.

    Chemical Equilibrium

    • Chemical equilibrium is a state where the concentrations of reactants and products remain constant over time, indicating a balance in chemical reactions.

    Logarithmic Relationship

    • Taking the negative logarithm of the Kw equation reveals the relationship to pH, illustrating how concentration of H⁺ and OH⁻ ions affect acidity and basicity.

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    Description

    Learn about the chemical composition of aqueous solutions and the classification of electrolytes. Understand the difference between strong electrolytes, weak electrolytes, and non-electrolytes. Explore how water serves as a versatile solvent in chemical analyses.

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