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Questions and Answers
Which process involves a substance transitioning directly from a solid state to a gaseous state?
Which process involves a substance transitioning directly from a solid state to a gaseous state?
What determines the identity of an atom and the name of its corresponding element?
What determines the identity of an atom and the name of its corresponding element?
What force binds protons and neutrons together within the nucleus of an atom?
What force binds protons and neutrons together within the nucleus of an atom?
Which statement is true regarding electrically neutral atoms?
Which statement is true regarding electrically neutral atoms?
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What are the outermost shell electrons of an atom called?
What are the outermost shell electrons of an atom called?
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What characterizes an atom with a full outermost electron shell?
What characterizes an atom with a full outermost electron shell?
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What is the correct relationship between mass number (A), atomic number (Z), and neutron number (N)?
What is the correct relationship between mass number (A), atomic number (Z), and neutron number (N)?
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If an element has an atomic number of 6 and a mass number of 14, how many neutrons does it have?
If an element has an atomic number of 6 and a mass number of 14, how many neutrons does it have?
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What characteristic primarily distinguishes representative elements from transition elements in older periodic table numbering systems?
What characteristic primarily distinguishes representative elements from transition elements in older periodic table numbering systems?
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Which of the following properties is generally associated with metals?
Which of the following properties is generally associated with metals?
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An atom that has lost electrons and carries a net positive charge is called a(n):
An atom that has lost electrons and carries a net positive charge is called a(n):
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Which subatomic particle determines whether an atom is classified as an ion or an element?
Which subatomic particle determines whether an atom is classified as an ion or an element?
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What type of chemical bond involves the sharing of outer valence electrons between atoms?
What type of chemical bond involves the sharing of outer valence electrons between atoms?
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Which type of compound is characterized by positively and negatively charged ions and lacks identifiable discrete units?
Which type of compound is characterized by positively and negatively charged ions and lacks identifiable discrete units?
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What is the initial step in a mass spectrometer's process of determining the mass of an atom or molecule?
What is the initial step in a mass spectrometer's process of determining the mass of an atom or molecule?
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What process directly leads to the formation of a molecular ion in a mass spectrometer?
What process directly leads to the formation of a molecular ion in a mass spectrometer?
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Which of the following statements accurately describes subshells and orbitals?
Which of the following statements accurately describes subshells and orbitals?
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What is a core tenet of Dalton's Atomic Theory regarding elements and atoms?
What is a core tenet of Dalton's Atomic Theory regarding elements and atoms?
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Dalton's Atomic Theory is based on which of the following laws?
Dalton's Atomic Theory is based on which of the following laws?
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Why is Dalton's Atomic Theory considered incomplete from a modern scientific perspective?
Why is Dalton's Atomic Theory considered incomplete from a modern scientific perspective?
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What is the fundamental principle behind Valence Shell Electron Pair Repulsion (VSEPR) theory?
What is the fundamental principle behind Valence Shell Electron Pair Repulsion (VSEPR) theory?
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What determines the arrangement of elements in the modern periodic table?
What determines the arrangement of elements in the modern periodic table?
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What do the rows (periods) in the periodic table represent?
What do the rows (periods) in the periodic table represent?
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According to Valence Bond Theory, how does the overlap of valence electron clouds contribute to the formation of a covalent bond?
According to Valence Bond Theory, how does the overlap of valence electron clouds contribute to the formation of a covalent bond?
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Elements within the same group (or family) of the periodic table typically share what characteristic?
Elements within the same group (or family) of the periodic table typically share what characteristic?
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What happens to the energy of a molecule as atoms approach each other to form a bond, reaching the ideal bond length?
What happens to the energy of a molecule as atoms approach each other to form a bond, reaching the ideal bond length?
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Ionic bonds are characterized by what type of interaction?
Ionic bonds are characterized by what type of interaction?
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What is the significance of the atomic weights listed on the periodic table?
What is the significance of the atomic weights listed on the periodic table?
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What is a key characteristic of ionic compounds in the solid state, as described in the text?
What is a key characteristic of ionic compounds in the solid state, as described in the text?
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What do lines between atoms represent in Lewis Structures?
What do lines between atoms represent in Lewis Structures?
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What are valence electrons not used for covalent bonds represented as in Lewis structures?
What are valence electrons not used for covalent bonds represented as in Lewis structures?
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What is the main purpose of Lewis Structures?
What is the main purpose of Lewis Structures?
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What is the correct way to name the compound $CH_3CH_2Cl$ using common nomenclature?
What is the correct way to name the compound $CH_3CH_2Cl$ using common nomenclature?
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Which of the following statements accurately describes alcohols?
Which of the following statements accurately describes alcohols?
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Which factor affects the water solubility of alcohols?
Which factor affects the water solubility of alcohols?
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What is the general formula of an alkyl halide?
What is the general formula of an alkyl halide?
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What is the key structural feature of an ether?
What is the key structural feature of an ether?
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Which statement is MOST accurate regarding the use of ethers in medical settings?
Which statement is MOST accurate regarding the use of ethers in medical settings?
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What is a key characteristic of amines related to their structure?
What is a key characteristic of amines related to their structure?
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What is the relationship between aromatic alcohols and phenols?
What is the relationship between aromatic alcohols and phenols?
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What characterizes ionic bonds?
What characterizes ionic bonds?
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What is the primary difference between covalent and polar covalent bonds?
What is the primary difference between covalent and polar covalent bonds?
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How does electronegativity influence bond polarity?
How does electronegativity influence bond polarity?
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Which statement is true about electrostatic bonds?
Which statement is true about electrostatic bonds?
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What is a defining feature of ion-to-ion bonds?
What is a defining feature of ion-to-ion bonds?
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What effect does the larger oxygen nucleus have in a polar covalent bond with hydrogen?
What effect does the larger oxygen nucleus have in a polar covalent bond with hydrogen?
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What property of ionic compounds like sodium chloride can be attributed to ion-to-ion bonding?
What property of ionic compounds like sodium chloride can be attributed to ion-to-ion bonding?
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What is the role of water (H2O) in ion-dipole bonding?
What is the role of water (H2O) in ion-dipole bonding?
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Flashcards
States of Matter
States of Matter
Forms of matter: solid, liquid, gas.
Melting
Melting
Conversion of a solid into a liquid.
Freezing
Freezing
Conversion of a liquid into a solid.
Vaporization
Vaporization
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Condensation
Condensation
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Atomic Number (Z)
Atomic Number (Z)
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Mass Number (A)
Mass Number (A)
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Valence Electrons
Valence Electrons
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Electron Shells
Electron Shells
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Dalton's Atomic Theory
Dalton's Atomic Theory
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Law of Conservation of Mass
Law of Conservation of Mass
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Law of Definite Proportions
Law of Definite Proportions
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Law of Multiple Proportions
Law of Multiple Proportions
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Periodic Table Organization
Periodic Table Organization
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Groups in the Periodic Table
Groups in the Periodic Table
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Average Atomic Weights
Average Atomic Weights
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Lewis Structures
Lewis Structures
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Balancing Chemical Equations
Balancing Chemical Equations
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Valence Shell Electron Pair Repulsion (VSEPR) Theory
Valence Shell Electron Pair Repulsion (VSEPR) Theory
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Valence Bond Theory
Valence Bond Theory
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Bond Length
Bond Length
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Bond Energy
Bond Energy
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Ionic Bonds
Ionic Bonds
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Covalent Bonds
Covalent Bonds
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Aryl Halides
Aryl Halides
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Alkyl Halide Formula
Alkyl Halide Formula
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Halo Groups
Halo Groups
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Hydroxyl Group
Hydroxyl Group
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Types of Alcohols
Types of Alcohols
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Solubility of Alcohols
Solubility of Alcohols
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Ethers
Ethers
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Anesthetic Ethers
Anesthetic Ethers
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Electronegativity
Electronegativity
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Polar Covalent Bond
Polar Covalent Bond
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Dipole
Dipole
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Electrostatic Bond
Electrostatic Bond
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Ion-Ion Bonding
Ion-Ion Bonding
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Ion-Dipole Bonding
Ion-Dipole Bonding
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Representative Elements
Representative Elements
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Transition Elements
Transition Elements
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Inner Transition Elements
Inner Transition Elements
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Metals
Metals
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Nonmetals
Nonmetals
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Cations
Cations
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Anions
Anions
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Mass Spectrometer
Mass Spectrometer
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Study Notes
Introduction to Chemistry
- This is an introductory chemistry course for students of anesthesia, NSG 741.
- Chemistry and physics are fundamental to anesthesia practice.
Why Chemistry and Physics?
- Anesthesia practice is based on chemical and physical sciences.
- Chemistry studies the composition, properties, and structure of matter at atomic and molecular levels, and how it reacts with other matter.
- Physics describes the motion, mechanics, force, and energy of matter, and how it behaves through space and time.
- These concepts are intertwined with the delivery of anesthetics.
- Understanding these laws and theories is crucial for clinical anesthesia interventions to optimize patient care.
General Chemistry
- The universe consists of matter and energy.
- Energy is studied in physics.
- Matter exists as solid, liquid, gas, or plasma.
- Solids maintain a fixed shape and volume.
- Liquids maintain a fixed volume but adapt to the container's shape.
- Liquids are compressible to some extent.
- Liquids change volume with changes in pressure and temperature.
So, What is Chemistry?
- Chemistry is the study of matter and its changes.
- Physical chemists develop models to understand chemical systems.
- Inorganic chemists study substances derived from all elements except carbon.
- Organic chemists study carbon-based compounds.
- Biochemists study chemistry in living systems.
- Chemical changes result in the formation of a different substance.
- Physical changes do NOT change substances.
States of Matter
- Common states of matter include solids, liquids, and gases.
- Solids have a definite shape and volume.
- Liquids have a definite volume and an indefinite shape.
- Gases have an indefinite shape and volume.
- Transitions between states include melting, freezing, vaporization, condensation, and deposition.
The Atom
- Atoms are the fundamental building blocks of matter, composed of protons, neutrons, and electrons.
- Protons have a positive charge and a mass of approximately 1 amu.
- Neutrons have no charge and a mass of approximately 1 amu.
- Electrons have a negative charge and much smaller mass than protons and neutrons.
- Atomic number (Z) defines an element's identity and equals the number of protons.
- Neutron number (N) is the number of neutrons.
- Mass number (A) is the sum of protons and neutrons.
- Atomic weight is the average mass of all isotopes of an element in amu.
- Protons and neutrons are tightly bound in the nucleus, which is much smaller than the atom itself.
- Electrons orbit the nucleus in shells, and each shell needs to be filled before the next shell.
Dalton's Atomic Theory
- Elements are composed of tiny, indivisible particles called atoms.
- All atoms of a given element are identical and are unique to that element.
- Compounds are formed by bonding different atoms together in a fixed ratio.
- Chemical reactions do not create, destroy, or change atoms; they merely rearrange them.
- Dalton's theory relied on conservation of mass and definite proportions.
- Dalton's theory is incomplete from a modern perspective because it didn't consider isotopes.
The Periodic Table of the Elements
- The periodic table organizes elements by increasing atomic number (number of protons).
- Each element has a chemical symbol.
- Each element's average atomic mass is listed.
- Rows are called periods, reflecting the filling of electron shells.
- Columns are called groups, reflecting similar chemical and physical properties.
- Group 8A (or 18) contains the noble gases, which are relatively unreactive.
- Elements can be classified as representative, transition, or inner transition elements.
Average Atomic Weights & Classifications
- Atomic weights on the periodic table are weighted averages of naturally occurring isotopes.
- Classify elements as representative, transition, or inner transition.
- In the older periodic table, groups numbered with an A are representative, and groups with a B are transition.
- Elements below the main portion of the periodic table are inner transition elements.
Metals vs Nonmetals
- Metals are typically shiny, solid, malleable, ductile, and conductive.
- Metals tend to lose electrons during chemical reactions.
- Nonmetals are typically solids, liquids, or gases.
- Nonmetals tend to gain electrons during chemical reactions.
Ions & Elements
- Ions are atoms or groups of atoms with a net electrical charge due to electron addition or loss.
- Cations are positively charged ions.
- Anions are negatively charged ions.
- Ionization energy is the energy needed to remove the most loosely bound electron from an atom.
- Elements contain only one type of atom.
Compounds
- Two or more elements combine to form compounds.
- Compounds are bonded by covalent or electrostatic forces.
- Covalent bonds involve electron sharing.
- Electrostatic bonds involve attraction between oppositely charged ions.
Mass Spectrometer
- A mass spectrometer measures the mass of atoms or molecules.
- Samples are injected through a high-temperature/low-pressure port.
- The sample is bombarded with high-energy electrons.
- The resulting molecular ions are deflected by magnets.
- Magnetic strength changes to analyze the atomic/molecular mass.
Moles
- A mole is 6.02 x 10^23 particles of a substance, containing the same number as in 12 grams of carbon-12.
- Avogadro's number is a conversion factor between particles and moles.
Molar Mass (Molecular Weight)
- Molar mass is the mass of one mole of a substance in grams.
- For an element, molar mass equals the atomic mass in amu.
- For molecules, molar mass is the sum of the atomic masses of the component atoms.
- Molar mass provides conversion factors between grams and moles.
Isotopes
- Isotopes are atoms of the same element that have the same number of protons but different numbers of neutrons.
- Different isotopes have distinct mass numbers.
Isomers
- Isomers are molecules with the same chemical formula but different structures.
- Structural isomers have the same molecular formula but different arrangements of atoms.
- Stereoisomers have similar structures but different arrangements in three-dimensional space.
- Enantiomers are mirror images of each other.
- Diastereomers are not mirror images of each other.
Physical and Chemical Properties and Changes
- Physical properties can be observed without changing the substance's makeup (e.g., color, melting point).
- Extensive properties depend on the sample size (e.g., mass, volume).
- Intensive properties do not depend on the sample size (e.g., density, temperature).
- Chemical properties describe how a substance changes into different substances (e.g., flammability, reactivity).
- Chemical changes involve the making or breaking of chemical bonds.
Chemistry Concepts
- Pure substances cannot be physically separated into simpler components.
- Mixtures are combinations of two or more pure substances that can be physically separated.
- Homogeneous mixtures are uniform in their composition and properties.
- Heterogeneous mixtures exhibit distinct phases.
Intermolecular Forces
- Intermolecular forces are attractive forces between molecules, influenced by chemical bonds.
- These forces affect macroscopic properties (e.g., state of matter, boiling points, interactions).
- Electrostatic in nature due to attractions of oppositely charged particles.
- Intermolecular forces affect the properties of molecules and dictate interactions between molecules and other compounds.
Lewis Structures
- Lewis structures are diagrams that represent the bonding arrangement in a molecule.
- Atoms are represented by their chemical symbols, and shared electron pairs (bonds) are shown as lines.
- Lone pairs of electrons are shown as dots.
Balancing Chemical Equations
- Chemical equations represent chemical reactions.
- Balancing equations ensures that the total number of atoms of each element is equal on both sides of the equation.
Valence Shell Electron Pair Repulsion (VSEPR) Theory
- VSEPR theory explains molecular geometry by repulsion between electron pairs in a molecule.
- Electron pairs arrange themselves to maximize distance, resulting in a particular three-dimensional shape for a molecule.
- Various shapes are possible.
Valence Bond Theory
- Covalent bonds form when the electron wave functions of two atoms overlap.
- The shared pair of electrons is distributed between nuclei, reducing electrostatic repulsions and stabilizing the molecule.
Bond Length and Bond Energy
- Bond length is the distance between the nuclei of two bonded atoms.
- Bond energy is the energy required to break a bond.
- Ideally, bond length and energy are at a minimum and maximum, respectively, for a stable molecule.
Ionic Bonds
- Ionic bonds result from the electrostatic attraction between oppositely charged ions (cations and anions).
- In ionic solids, these ions arrange in a highly ordered crystalline lattice.
- Ionic bonds tend to be strong, leading to high melting and boiling points.
- Bonds involve complete electron transfer from one atom to another.
Covalent Bonds
- Covalent bonds result from the sharing of one or more pairs of electrons between atoms.
- Electron sharing enables each atom to reach a stable electron configuration (often 8 valence electrons).
- Orbitals overlap, contributing to bonding.
- Single, double, or triple bonds are possible, depending on the number of electron pairs shared.
Electronegativity & Polar Covalent Bonds
- Electronegativity measures an atom's ability to attract electrons in a chemical bond.
- Polar covalent bonds occur when atoms with different electronegativities share electrons unevenly.
- The electron distribution is not symmetrical, with the more electronegative atom having a partial negative charge.
- Polar covalent bonds determine how molecules behave and interact in various environments.
Polar Covalent Bonds
- Electrons in a polar covalent bond tend to be attracted more strongly to one atom than the other.
- This results in a partial positive charge on one atom and a partial negative charge on the other, creating a dipole.
- Water is a highly polar molecule, influencing its tendency to dissolve other substances with similar polarities.
- Intermolecular forces influence how molecules arrange themselves and their properties.
Electrostatic Bonds
- Electrostatic bonds result from the attraction of opposite charges.
- Electrostatic forces influence the arrangement of molecules in various environments (e.g., polar solvents).
Ion-Ion Bonding
- Ion-ion bonds result from the electrostatic attraction between oppositely charged ions.
- These bonds are the strongest electrostatic forces.
- These bonds occur between any two oppositely charged atoms.
- The strong force leads to higher melting points and boiling points for ionic compounds.
Ion-Dipole Bonding
- Ion-dipole bonds arise from the attraction between ions and polar molecules.
- Polar molecules have partial charges.
- These bonds are instrumental in dissolving ionic compounds in polar solvents like water.
Hydrogen Bonding
- Hydrogen bonds are a strong type of dipole-dipole interaction.
- Hydrogen bonds are crucial for stabilization and shape of molecules or compounds.
- Hydrogen bonding results from electrostatic attraction between molecules with partial positive and partial negative charges.
- Hydrogen bonding impacts many biological phenomena.
Van der Waals Forces
- London dispersion forces are the weakest intermolecular forces.
- They still allow low-temperature gases like oxygen and nitrogen to become liquids.
- They result from temporary fluctuations in electron distribution, creating temporary dipoles.
Molecular Bond Strength
- Generally, covalent bonds are stronger than ionic bonds.
- However, in biological systems, the presence of water necessitates considering factors like the nature of the solutes and the water's role.
- Biological systems rely on various interactions to stabilize molecules.
Bond Breaking
- Bond energy is the energy needed to break a chemical bond.
- If a bond is formed energy is released that equals the energy consumed to break the bond.
- Bond energies are related to enthalpy changes.
Enthalpy
- Enthalpy is the total energy of a system.
- Includes kinetic and potential energy.
- Accounts for energy's relation to height, bonds, particles.
- Change measurement is done by enthalpy change (ΔH).
Electrolytes
- Electrolytes are substances that dissolve in water to form solutions that can conduct electricity.
- Ionic compounds that dissolve readily in water are often electrolytes due to the separation into free-moving ions.
- Molecular compounds do not act as electrolytes unless they exhibit acid or base properties.
- Tap water conducts electricity since it contains dissolved ions.
Functional Groups
- Functional groups are sets of atoms bonded together in a specific configuration.
- Functional groups dictate the chemical and physical behavior of organic molecules.
- Functional groups on organic molecules determine chemical reactivity and impact how molecules interact or function.
Hydrocarbon Functional Group
Hydrocarbons
- Hydrocarbons consist of carbon and hydrogen atoms.
- The hydrocarbon backbone serves as the basis for various other molecules including functional groups.
- These are the simplest organic compounds.
Alkyl Groups
- Alkyl groups are formed by removing a hydrogen atom from a hydrocarbon chain.
- They are very reactive, and alkyl groups become more so as the size/bulk increases.
- By their reaction characteristics alkyl groups dictate how other molecules are formed, and thus, their functions, or reactions.
Cycloalkanes & Saturation
- Cycloalkanes are cyclic hydrocarbons containing only single bonds between carbons.
- Saturation refers to the maximum number of hydrogen atoms for a certain number of carbons.
- Unsaturated compounds contain double or triple bonds, which reduce the number of hydrogen atoms.
- The number of hydrogen atoms impacts physical characteristics and chemical reactivity.
Alkenes (C=C)
- Alkenes are hydrocarbons with at least one carbon-carbon double bond, also called olefins.
- Alkenes have trigonal planar geometry.
Alkenes Reactions
- Hydrogenation of alkenes involves addition of hydrogen atoms to a double bond to convert into an alkane.
- This is often facilitated by using a metal catalyst.
- Polymerization uses alkene monomers to form polymers.
Alkynes (C≡C)
- Alkynes are hydrocarbons containing a carbon-carbon triple bond.
- They are less common than alkanes and alkenes.
Aromatics
- Common elements with benzene rings that form many vital compounds and medications.
Organohalogen Compounds
- Organohalogen compounds contain halogen atoms like fluorine, chlorine, bromine, and iodine.
- Halogens attach to various hydrocarbon chains.
- Name structure via IUPAC using prefixes to indicate halogen substituents (fluoro, chloro,..etc.).
Functional Groups Based on Water: Alcohol
- Alcohols have hydroxyl (-OH) groups.
- Alcohols can form hydrogen bonds, which influences solubility and reactivity in water-based systems.
- Solubility decreases as alkyl groups increase in size.
- Aromatic alcohols have very similar properties to regular alcohols with some differences in reactivities.
Functional Groups Based on Water: Ether
- Ethers contain an oxygen atom bonded to two alkyl groups.
- Ethers are typically less reactive than various other functional groups.
- Many ethers are used as solvents.
Functional Groups Based on Water: Amines
- Amines are nitrogen-based functional groups with various reactivities.
- Amines are often used as basic compounds.
- Most are commonly given as salts which improve their solubility in water.
Carbonyl Functional Groups
- Carbonyl groups contain a carbon atom double-bonded to an oxygen atom.
- The carbonyl group's characteristics affect reactivity and properties.
Aldehydes
- Aldehydes have a carbonyl group, with one alkyl group and one hydrogen atom attached to it.
- They are important naturally-occurring compounds and can be easily oxidized.
- The IUPAC name for an aldehyde ends with the suffix "al".
Ketones
- Ketones have a carbonyl group with two alkyl groups attached.
- They are prevalent in nature and in medications.
- Ketones' IUPAC name uses the suffix "one".
Reactions of Aldehydes and Ketones
- Oxidation and reduction reactions involve electron transfer.
- Oxidations increase bonds to oxygen and release energy.
- Reductions decrease oxygen bonds, increase hydrogen bonds, and consume energy.
Formation of Acetals and Ketals
- Aldehydes and ketones react with alcohols to form acetal or ketal products.
- These reactions are examples of condensation reactions and form stable cyclic structures under mild conditions.
Carboxylic Acids
- Carboxylic acids contain a carboxyl (-COOH) functional group.
- They act as organic acids, donating a proton (H+).
- The naming convention uses the suffix "oic acid."
- Carboxylic acids are frequently found in many molecules and compounds, and in numerous biological processes.
Esters
- Esters are formed through the condensation reaction between carboxylic acids and alcohols.
- Many esters exhibit pleasant, fruit-like odors.
- Esters (the triglyceride's composition) are important energy storage molecules and components of many lipids.
Amides
- Amides are formed from the condensation reaction between carboxylic acids and amines.
- Proteins are composed of amino acid units linked by amide bonds (also called peptide bonds).
- Amides can be hydrolyzed back into carboxylic acids and amines under the right conditions.
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Test your knowledge on atomic structure with this quiz that covers key concepts such as the states of matter, atomic identity, and subatomic particles. Challenge yourself with questions about the properties of elements and their arrangement in the periodic table. Perfect for students studying chemistry at all levels.