Chemistry Chapter 3: The Chemistry of Water

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Questions and Answers

What type of bond is primarily responsible for the unique properties of water?

  • Metallic bonds
  • Nonpolar covalent bonds
  • Ionic bonds
  • Polar covalent bonds (correct)

Water is a nonpolar molecule.

False (B)

Name one of the four emergent properties of water that contribute to Earth's suitability for life.

cohesive behavior

The ability of water to moderate temperature is due to its ________ capacity.

<p>high heat</p> Signup and view all the answers

Match the following properties of water with their descriptions:

<p>Cohesion = Attraction between water molecules Adhesion = Attraction between water and different substances Expansion upon freezing = Ice is less dense than liquid water Versatility as a solvent = Ability to dissolve many substances</p> Signup and view all the answers

Why is cohesion important for plants?

<p>It helps transport water and nutrients against gravity. (D)</p> Signup and view all the answers

Water molecules exhibit low surface tension due to hydrogen bonding.

<p>False (B)</p> Signup and view all the answers

What is the specific heat of water?

<p>1 cal/gºC (A)</p> Signup and view all the answers

What is the term for the measure of how difficult it is to stretch or break the surface of a liquid?

<p>surface tension</p> Signup and view all the answers

Water cools down rapidly and changes temperature quickly.

<p>False (B)</p> Signup and view all the answers

What is evaporative cooling?

<p>The process where a liquid transforms into gas, cooling the remaining surface.</p> Signup and view all the answers

A calorie is the amount of heat required to raise the temperature of 1 g of water by ___ºC.

<p>1</p> Signup and view all the answers

Match the terms related to heat and water:

<p>Specific Heat = Heat needed to change temperature of a substance Heat of Vaporization = Heat required to convert a liquid to gas Thermal Energy = Energy associated with atomic or molecular motion Evaporation = Transformation from liquid to gas</p> Signup and view all the answers

How does water moderate air temperature in coastal areas?

<p>By absorbing and storing heat during the day (B)</p> Signup and view all the answers

Hydrogen bonds in water help to keep its temperature stable.

<p>True (A)</p> Signup and view all the answers

What happens to water's temperature during the process of heating?

<p>Temperature changes slightly as heat is absorbed to break hydrogen bonds.</p> Signup and view all the answers

At what temperature does water reach its greatest density?

<p>4ºC (A)</p> Signup and view all the answers

Ice is denser than liquid water.

<p>False (B)</p> Signup and view all the answers

What is the term for the mixture where water is the dissolving agent?

<p>aqueous solution</p> Signup and view all the answers

A __________ substance has an affinity for water.

<p>hydrophilic</p> Signup and view all the answers

Match the following terms with their definitions:

<p>Solvent = The substance that dissolves another substance Solute = The substance that is dissolved Hydrophobic = Substances that do not have an affinity for water Hydrophilic = Substances that have an affinity for water</p> Signup and view all the answers

What effect could the sinking of ice have on bodies of water?

<p>Bodies of water could potentially freeze solid. (D)</p> Signup and view all the answers

Oil molecules are hydrophilic due to their nonpolar bonds.

<p>False (B)</p> Signup and view all the answers

What surrounds each ion when an ionic compound is dissolved in water?

<p>hydration shell</p> Signup and view all the answers

What is the definition of molarity (M)?

<p>The number of moles of solute per liter of solution (A)</p> Signup and view all the answers

Acids increase the OH- concentration of a solution.

<p>False (B)</p> Signup and view all the answers

What is the pH value of a neutral aqueous solution?

<p>7</p> Signup and view all the answers

In aqueous solutions, when an acid donates a proton, it increases the concentration of ______.

<p>H+</p> Signup and view all the answers

Match the following terms with their correct definitions:

<p>Acid = Proton donor Base = Proton acceptor Hydronium ion = H3O+ Hydroxide ion = OH–</p> Signup and view all the answers

Which of the following statements is true regarding acidic solutions?

<p>They have pH values less than 7. (A)</p> Signup and view all the answers

The concentration of H+ and OH- is equal in pure water.

<p>True (A)</p> Signup and view all the answers

What is the formula to calculate pH?

<p>pH = -log[H+]</p> Signup and view all the answers

Flashcards

Polarity of water

In a water molecule, the shared electrons spend more time near the oxygen atom, creating a slightly negative charge on the oxygen and a slightly positive charge on the hydrogens. This uneven charge distribution makes water polar, allowing it to form hydrogen bonds with other water molecules.

Hydrogen bond

A type of weak bond that occurs between a slightly positive hydrogen atom of one molecule and a slightly negative atom of another molecule, typically oxygen or nitrogen. It's a crucial force in water molecules.

Cohesion of water

The ability of water molecules to stick together due to hydrogen bonds. This leads to surface tension and plays a role in the transport of water in plants.

Adhesion of water

The attraction between water molecules and other substances due to polarity. It helps water to climb up plant stems against gravity.

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Surface tension of water

A property of water that allows it to resist breaking or stretching due to strong cohesive forces between its molecules, making it act like a thin, invisible film.

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Water's ability to moderate temperature

Water's ability to absorb and release heat energy with minimal temperature change. This helps moderate temperature fluctuations in the environment.

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Water's expansion upon freezing

When water freezes, it expands due to the formation of a crystalline structure. This helps insulate aquatic life and prevents lakes from freezing solid.

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Water as a solvent

Water's ability to dissolve many substances due to its polarity. This helps transport nutrients and remove waste in living organisms.

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Calorie

The amount of heat required to raise the temperature of 1 gram of water by 1 degree Celsius.

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Thermal Energy

The energy associated with the random movement of atoms or molecules within a substance.

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Specific Heat

The amount of heat energy that must be absorbed or released to change the temperature of 1 gram of a substance by 1 degree Celsius.

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Why does water have a high specific heat?

Hydrogen bonds between water molecules require a significant amount of energy to break, resulting in water's high specific heat.

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How does water's high specific heat impact temperature?

Water's high specific heat helps moderate temperature fluctuations, preventing extreme changes in temperature.

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Evaporation

The transformation of a substance from a liquid to a gas.

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Heat of Vaporization

The amount of heat required to convert 1 gram of a liquid into a gas.

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Evaporative Cooling

The cooling effect that occurs when a liquid evaporates, taking heat away from the remaining liquid or surrounding environment.

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Why does ice float?

Water's unusual property where ice floats on liquid water due to a less dense crystalline structure.

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What is density?

A measure of how much mass is contained in a given volume. Density explains why ice floats on water.

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What is a solution?

A solution is a homogeneous mixture of substances. The solvent is the dissolving agent, and the solute is what gets dissolved. Water is the universal solvent.

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What is a polar molecule?

The uneven distribution of electrons in a water molecule creates a slightly negative charge on the oxygen and a slightly positive charge on the hydrogens. This makes water a polar molecule.

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Why is water a good solvent?

Water's ability to dissolve many substances due to its polarity. Essential for life's processes.

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What are hydrophilic substances?

Substances attracted to water, like sugar. They contain polar regions.

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What are hydrophobic substances?

Substances repelled by water, like oil. They primarily contain nonpolar regions.

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What is a hydrogen bond?

A weak bond formed between hydrogen atoms and a highly electronegative atom like oxygen. Crucial for water's properties.

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What is molecular mass?

The sum of the atomic masses of all atoms in a molecule.

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What is a mole (mol)?

A unit used to measure the amount of a substance, containing 6.02 x 10^23 molecules.

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What is Molarity (M)?

The concentration of a solute in a solution, expressed as moles of solute per liter of solution.

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What is an acid?

A substance that increases the H+ concentration of a solution, also known as a 'proton donor.'

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What is a base?

A substance that can accept H+ ions in a solution, also known as a 'proton acceptor.'

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What is pH?

The negative logarithm of the H+ concentration in a solution, measured on a scale from 0 to 14.

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What is dynamic equilibrium?

A state where the rate of a forward reaction equals the rate of the reverse reaction, in this case, the continuous dissociation and reformation of water molecules.

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What is the dissociation of water?

The process of water molecules splitting into hydrogen ions (H+) and hydroxide ions (OH-), which occurs at the same rate as their reformation.

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Study Notes

Chapter 3: The Chemistry of Water

  • Water's structure is crucial for life on Earth.
  • Polar covalent bonds in water molecules lead to hydrogen bonding.
  • Electrons spend more time near oxygen in water.
  • Water is therefore a polar molecule, with an uneven distribution of charge.
  • This polarity allows water molecules to form hydrogen bonds with each other.
  • Four emergent properties of water support life:
    • Cohesive behavior: Hydrogen bonding holds water molecules together, creating surface tension, which helps in water transport in plants. Adhesion is the attraction between water and other substances. These properties together are important in transporting water in plants.
    • Ability to moderate temperature: Water absorbs and releases a large amount of heat with minimal temperature change, keeping temperatures within a habitable range. Specific heat is the amount of heat needed to change 1g of water by 1°C.
    • Expansion upon freezing: Water expands when it freezes, making ice less dense than liquid water. This is important, as ice floats, preventing bodies of water from freezing solid.
    • Versatility as a solvent: Water's polarity allows it to dissolve many ionic and polar substances, forming aqueous solutions. Aqueous solutions are solutions where water is the solvent.
  • Water is a versatile solvent due to its polarity.
  • When an ionic compound is dissolved in water, each ion is surrounded by a sphere of water molecules called a hydration shell.
  • Water can also dissolve nonionic polar molecules and even large molecules like proteins.
  • Hydrophilic substances have an affinity for water, while hydrophobic substances do not. Oil molecules are hydrophobic due to relatively nonpolar bonds.
  • Hydrophobic molecules are important components of cell membranes.
  • Solute concentration in aqueous solutions is measured in moles. Molecular mass is the sum of atom masses in a molecule. 1 mole = 6.02 x 1023 molecules. Molarity (M) is the number of moles per liter of solution.
  • Acids increase H+ concentration in a solution; bases accept H+ ions.
  • Acidity is measured by pH, a negative logarithm of H+ concentration.
  • Pure water has a pH of 7, neutral. Biological fluids generally have pH between 6 and 8.
  • Buffers are substances that minimize changes in H+ and OH- concentrations.
  • Most buffer solutions consist of a weak acid and its corresponding base that combines with H+ reversibly. Carbon dioxide and bicarbonate are a common buffer in living organisms.

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