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What are the main subjects covered in Chapter 13?
What are the main subjects covered in Chapter 13?
Fundamental Equilibrium Concepts, including Chemical Equilibrium, Equilibrium Constants, Shifting Equilibria: Le Châtelier's Principle, and Equilibrium Calculations.
What is the definition of Brønsted-Lowry Acid?
What is the definition of Brønsted-Lowry Acid?
A compound that donates a proton to another compound.
What types of compounds are acids? (Select all that apply)
What types of compounds are acids? (Select all that apply)
What is a conjugate acid-base pair?
What is a conjugate acid-base pair?
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What is the significance of the term "conjugate" in the context of acid-base theory?
What is the significance of the term "conjugate" in the context of acid-base theory?
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What are amphiprotic species?
What are amphiprotic species?
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Which of the following is an example of an amphiprotic species?
Which of the following is an example of an amphiprotic species?
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What is autoionization of water?
What is autoionization of water?
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What is the ion product constant for water, K_W?
What is the ion product constant for water, K_W?
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K_W is always equal to 1.0 * 10^-14.
K_W is always equal to 1.0 * 10^-14.
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Why is H₂O not included in the expression for K_W?
Why is H₂O not included in the expression for K_W?
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How are the concentrations of H₃O⁺ and OH⁻ related to each other?
How are the concentrations of H₃O⁺ and OH⁻ related to each other?
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What is the pH scale?
What is the pH scale?
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What is the relationship between pH and pOH?
What is the relationship between pH and pOH?
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What is the significance of the neutral pH value of 7?
What is the significance of the neutral pH value of 7?
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How do you calculate pH from H₃O⁺ concentration?
How do you calculate pH from H₃O⁺ concentration?
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Explain how to calculate the H₃O⁺ concentration from pH.
Explain how to calculate the H₃O⁺ concentration from pH.
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What is pOH?
What is pOH?
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What is the formula for calculating pOH from OH⁻ concentration?
What is the formula for calculating pOH from OH⁻ concentration?
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What are some examples of common substances and their associated pH ranges?
What are some examples of common substances and their associated pH ranges?
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What is an acid-base titration?
What is an acid-base titration?
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What is a buffer?
What is a buffer?
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What are polyprotic acids?
What are polyprotic acids?
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What is hydrolysis of salts?
What is hydrolysis of salts?
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What is the general chemical equation for a Brønsted-Lowry acid-base reaction?
What is the general chemical equation for a Brønsted-Lowry acid-base reaction?
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Study Notes
Chapter 13 - Fundamental Equilibrium Concepts
- Chemical Equilibrium: mA + nB ⇌ xC + yD
- Equilibrium Constants: Qc at equilibrium = Kc
- Shifting Equilibria: Le Chatelier's Principle
- Equilibrium Calculations
Chapter 10, 11, 12
- Molecular Solid
- Dissolution, electroylyte
- Equilibrium
Chapter 13 - Acid
- CO2 + H2O ⇌ H2CO3 ⇌ HCO3- + H+
Chapter 14 - Acid-Base Equilibria
- Brønsted-Lowry Acids and Bases: proton donor vs. proton acceptor.
- Kw = [H3O+][OH-] = 1.0 x 10-14 (25 °C)
- pH = -log[H3O+]
- pOH = -log[OH-] pH + pOH = 14
- Relative Strengths of Acids and Bases
- Hydrolysis of Salts
- Polyprotic Acids
- Buffers
- Acid-Base Titrations
Objectives for Chapter 14.1
- Definition of Brønsted-Lowry
- Identify acids, bases, and conjugate acid-base pairs
- Describe the acid-base behavior of amphiprotic substances
- Write equations for acid/base ionization reactions
- Calculate hydronium (H3O+) and hydroxide (OH-) concentrations
Acid and Base Definitions
- Focused on reactions between acids and bases.
- Brønsted-Lowry Acid: A compound that donates a proton to another compound.
- Brønsted-Lowry Base: A compound that accepts a proton from another compound.
What Types of Compounds are Acids?
- Molecules: H2O, HF, H2CO3, H2SO3, HNO3
- Cations containing H: H3O+, NH4+
- Anions containing H: HCO3-, HS-
What Types of Compounds are Bases?
- Ionic compounds containing -OH: HCO3-, HSO3-, H2PO4-
- Molecules: H2O, NH3
- Anions: OH-, ClO4-, HS-
- Cations: Few examples
Brønsted-Lowry Acid/Base Theory
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Conjugate acid-base pairs; removing a proton from an acid forms its conjugate base.
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Adding a proton to a base forms its conjugate acid.
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Examples of acid-base reactions H2O(l) + NH3(aq) ⇌ OH-(aq) + NH4+(aq)
Amphiprotic Species
- Species that can either accept or donate a proton (or amphoteric).
- Water can act as an acid or base.
Amphiprotic Species - Representing Acid-Base Behavior
- Separate equations for HSO3- acting as an acid with OH-: HSO3-(aq) + OH-(aq) ⇌ SO32-(aq) +H2O(l)
- React with HI as base HSO3-(aq) + HI(aq) ⇌ H2SO3(aq) + I-(aq)
The Autoionization of Water
- In pure water, water acts as both an acid and a base.
- H2O + H2O ⇌ H3O+ + OH-
- The equilibrium constant is called the ion product constant for water, Kw. Kw = [H3O+][OH-] = 1.0 x 10-14 (25 °C)
The Inverse Relation between [H3O+] and [OH-]
- [OH-] = Kw/[H3O+]
Calculation of pH from [H3O+]
- pH = -log[H3O+]
Calculation of Hydronium Ion Concentration from pH
- [H3O+] = 10-pH
Calculation of pOH
- pOH = -log[OH-]
- pH + pOH = 14
pH and pOH values of some common substances.
- pH and pOH values across a range of common substances, including acids, bases, and neutral substances at 25°C.
pH scale description
- Acidic, neutral, and basic conditions are defined according to the measured pH.
- Color-coded scale to indicate pH levels.
Figure 14.3 - Rain water is Acidic
- Acid rain is a critical environmental consideration as it results in detrimental effects on trees and structures.
- Chemical reaction involving carbonic acid and calcium carbonate, a component of limestone.
Figure 14.4 - pH Meter
- A research-grade pH meter is expensive and precise equipment for accurately measuring pH.
Figure 14.4 - pH paper
- pH paper are convenient for determining an approximate value of pH, relying on indicator dyes.
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Description
Dive into the critical concepts of acid-base equilibria in this quiz covering Chapter 14. Test your understanding of Brønsted-Lowry definitions, pH calculations, and the role of buffers and titrations. Explore the dynamics of acids and bases, alongside their conjugate pairs.