L17 Bonding and Antibonding Orbitals

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10 Questions

Which type of overlapping of atomic orbitals forms a σ bond?

Head-to-head overlap

What type of combination of atomic orbitals may form a σ bond?

s-s, s-p, and p-p orbitals

Which type of molecular orbital is more stable than both antibonding molecular orbitals and parent atomic orbitals?

Bonding orbital

What is the electron density like in antibonding molecular orbitals?

Low

What is the main difference between bonding and antibonding orbitals?

Bonding orbitals contribute to the shape of the molecule, but antibonding orbitals do not.

In molecular orbital theory, what type of bond is formed when atomic orbitals intersect in a sideways positive direction perpendicular to the internuclear axis?

Pi (π) bond

How are sigma (σ) and pi (π) bonds formed in relation to each other?

Sigma bonds are formed first, followed by pi bonds

What are the characteristics of pi* (π*)-orbitals in molecular orbital theory?

Contain two nodal planes, one through the bonding axis and the other between nuclei

What is the bond order for carbon (C2) based on its molecular orbital energies?

2

What determines the stability of a resulting molecule in molecular orbital theory?

The energy differential between the lower and higher energy orbitals

Test your knowledge about bonding and antibonding orbitals in chemistry. Learn about the differences between the two types of orbitals and their roles in chemical bonding.

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